| Title | Catalytic synthesis of amines and N-containing heterocycles: amidate complexes for selective C-N and C-C bond-forming reactions. |
| Publication Type | Journal Article |
| Year of Publication | 2010 |
| Authors | Eisenberger, P, Schafer, LL |
| Journal | Pure and Applied Chemistry |
| Volume | 82 |
| Pagination | 1503 - 1515 |
| Date Published | 2010/// |
| ISBN Number | 0033-4545 |
| Abstract | The direct, 100 % atom-economic, and selective synthesis of amines is a challenging task that can be achieved, making use of early transition-metal catalysts. Here we report the synthesis and application of group 4 and 5 high-oxidn.-state metal amidate complexes in catalytic C-N (hydroamination) and C-C (hydroaminoalkylation) bond-forming reactions to access substituted amines. [on SciFinder(R)] |
