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Catalytic synthesis of amines and N-containing heterocycles: amidate complexes for selective C-N and C-C bond-forming reactions.

TitleCatalytic synthesis of amines and N-containing heterocycles: amidate complexes for selective C-N and C-C bond-forming reactions.
Publication TypeJournal Article
Year of Publication2010
AuthorsEisenberger, P, Schafer, LL
JournalPure and Applied Chemistry
Volume82
Pagination1503 - 1515
Date Published2010///
ISBN Number0033-4545
Abstract

The direct, 100 % atom-economic, and selective synthesis of amines is a challenging task that can be achieved, making use of early transition-metal catalysts. Here we report the synthesis and application of group 4 and 5 high-oxidn.-state metal amidate complexes in catalytic C-N (hydroamination) and C-C (hydroaminoalkylation) bond-forming reactions to access substituted amines. [on SciFinder(R)]