| Title | Bis(mercapto) and hydrido(thiolate) complexes of Ru(II)-dppm (dppm = Ph2PCH2PPh2) |
| Publication Type | Journal Article |
| Year of Publication | 2001 |
| Authors | Khorasani-Motlagh, M, Safari, N, Pamplin, CB, Patrick, BO, James, BR |
| Journal | Inorganica Chimica Acta |
| Volume | 320 |
| Pagination | 184-189 |
| Date Published | Aug |
| Type of Article | Article |
| ISBN Number | 0020-1693 |
| Keywords | CHEMISTRY, COMPLEXES, crystal structures, CRYSTAL-STRUCTURE, DERIVATIVES, DINUCLEAR RHODIUM COMPLEXES, hydrido complexes, HYDROFORMYLATION, MECHANISMS, MERCAPTO, PHOSPHINE COMPLEXES, ruthenium complexes, RUTHENIUM(II), THIOLATO, WATER |
| Abstract | From a mixture of cis- and trans-Ru(SH)(2)(dppm)(2) (4), formed from reaction of H2S with trans-Ru(H)Cl(dppm)(2) (2), a crystal of cis-4 has been isolated and its structure determined by X-ray analysis. The mercapto protons are located within the centrosymmetric structure, although the S-atoms are partially disordered (S - H similar to 1.06 Angstrom). The thiolate complexes, trans-Ru(H)SR(dppm)(2) (R = Ph, 5a; C6F5, 5b), have been isolated from reaction of trans-2 with 1 equiv. of RSH. trans-Ru(H)SH(dppm)(2) (3) has been isolated from reaction of H2S with a mixture of cis- and trans-Ru(H)(2)(dppm)(2) (1). An improved synthetic route for 1 is presented. (C) 2001 Elsevier Science B.V. All rights reserved. |
| URL | <Go to ISI>://000170965000025 |
