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BIS(DIPHENYLPHOSPHINO)METHANE COMPLEXES OF PALLADIUM AS CATALYSTS FOR HYDROSILYLATION OF OLEFINS BY TRICHLOROSILANE

TitleBIS(DIPHENYLPHOSPHINO)METHANE COMPLEXES OF PALLADIUM AS CATALYSTS FOR HYDROSILYLATION OF OLEFINS BY TRICHLOROSILANE
Publication TypeJournal Article
Year of Publication1992
AuthorsGulinski, J, James, BR
JournalJournal of Molecular Catalysis
Volume72
Pagination167-171
Date PublishedMar
Type of ArticleArticle
ISBN Number0304-5102
KeywordsBOND, CRYSTAL, HYDROGEN-SULFIDE, INSERTION, metal complexes, Pd(I), PHOSPHINE COMPLEXES
Abstract

Mononuclear Pd(II), and dinuclear Pd(O) and Pd(I) complexes containing bis(diphenylphosphino)methane catalyze the addition of trichlorosilane to the olefinic bond of hexene-1, styrene and vinyltrichlorosilane. Activity relationships for limited data at 80 and 120-degrees-C suggest that in each case mononuclear Pd(O) species might act as a catalyst precursor.

URL<Go to ISI>://A1992HT94000006