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Asymmetric induction in organic photochemistry via the solid-state ionic chiral auxiliary approach

TitleAsymmetric induction in organic photochemistry via the solid-state ionic chiral auxiliary approach
Publication TypeBook Chapter
Year of Publication2005
AuthorsScheffer, JR, Xia, WJ
Book TitleOrganic Solid State Reactions
Series TitleTopics in Current Chemistry
Volume254
Pagination233-262
PublisherSpringer-Verlag Berlin
CityBerlin
ISBN Number0340-1022
KeywordsABSOLUTE-CONFIGURATION, ACHIRAL, AMMONIUM CARBOXYLATE SALTS, ASYMMETRIC INDUCTION, auxiliaries, crystal structure-reactivity correlations, CRYSTALLINE STATE, di-pi-methane, ionic chiral, MODIFIED ZEOLITES, MOLECULES, organic photochemistry, PHOTOCYCLIZATION, SINGLE-CRYSTALS, solid state, STRUCTURE-REACTIVITY RELATIONSHIPS, TROPOLONE ETHER
Abstract

After a brief introduction and summary of various methods of asymmetric induction in organic photochemistry, the main part of the review covers the solid-state ionic chiral auxiliary approach to asymmetric photochemical synthesis. Application of this technique to the Norrish type II reaction, as well as to the di-Ti-methane and oxa-di-pi-methane photorearrangements, and the Cis, trans-photoisomerization of diarylcyclopropane derivatives is presented and discussed.

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