Title | 3-Rhoda-1,2-diazacyclopentanes: A Series of Novel Metallacycle Complexes Derived From CN Functionalization of Ethylene} |
Publication Type | Journal Article |
Year of Publication | 2014 |
Authors | Drover, MW, Beh, DW, Kennepohl, P, Love, JA |
Journal | Chemistry |
Date Published | Aug |
Abstract | {Rh-containing metallacycles, [(TPA)Rh(III) (κ(2) -(C,N)-CH2 CH2 (NR)2 -]Cl; TPA=N,N,N,N-tris(2-pyridylmethyl)amine have been accessed through treatment of the Rh(I) ethylene complex, [(TPA)Rh(η(2) -CH2 CH2 )]Cl ([1]Cl) with substituted diazenes. We show this methodology to be tolerant of electron-deficient azo compounds including azo diesters (RCO2 NNCO2 R; R=Et [3]Cl |