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Total Synthesis of (+)-3-Demethoxyerythratidinone and (+)-Erysotramidine via the Oxidative Amidation of a Phenol

TitleTotal Synthesis of (+)-3-Demethoxyerythratidinone and (+)-Erysotramidine via the Oxidative Amidation of a Phenol
Publication TypeJournal Article
Year of Publication2015
AuthorsPaladino, M, Zaifman, J, Ciufolini, MA
JournalORGANIC LETTERS
Volume17
Pagination3422-3425
Date PublishedJUL 17
ISSN1523-7060
Abstract

Oxidative amidation chemistry provides a unified route to aromatic Erythrina alkaloids through a sequence that illustrates new principles and improved conditions to effect a crucial eliminative Curtius-Schmidt rearrangement.

DOI10.1021/acs.orglett.5b01423