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STEREOSELECTIVE PREPARATION OF A RIGID TRIMETHYLENEMETHANE COMPLEX BY REACTION OF ALLENE WITH AN IRIDIUM METHYLIDENE DERIVATIVE - X-RAY CRYSTAL-STRUCTURE OF FAC-IR[ETA-4-C(CH2)3][N(SIME2CH2PPH2)2]

TitleSTEREOSELECTIVE PREPARATION OF A RIGID TRIMETHYLENEMETHANE COMPLEX BY REACTION OF ALLENE WITH AN IRIDIUM METHYLIDENE DERIVATIVE - X-RAY CRYSTAL-STRUCTURE OF FAC-IR[ETA-4-C(CH2)3][N(SIME2CH2PPH2)2]
Publication TypeJournal Article
Year of Publication1991
AuthorsFryzuk, MD, Joshi, K, Rettig, SJ
JournalOrganometallics
Volume10
Pagination1642-1644
Date PublishedMay
Type of ArticleNote
ISBN Number0276-7333
Keywords3+2 CYCLO-ADDITION, CARBENE COMPLEXES, LIGAND, ORGANIC SYNTHESES, TRANSITION-METAL COMPLEXES
Abstract

The trimethylenemethane complex fac-Ir[eta-4-C(CH2)3][N(SiMe2CH2PPh2)2] was prepared from the reaction of the methylidene derivative Ir = CH2[N(SiMe2CH2PPh2)2] with allene.

URL<Go to ISI>://A1991FM14600072