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  3. OXIDATIVE ADDITION OF DICHLOROMETHANE TO [(DPPE)RH]2(MU-CL)2 (DPPE = PH2PCH2CH2PPH2) - X-RAY STRUCTURE OF [(DPPE)RHCL]2(MU-CL)2(MU-CH2)

OXIDATIVE ADDITION OF DICHLOROMETHANE TO [(DPPE)RH]2(MU-CL)2 (DPPE = PH2PCH2CH2PPH2) - X-RAY STRUCTURE OF [(DPPE)RHCL]2(MU-CL)2(MU-CH2)

TitleOXIDATIVE ADDITION OF DICHLOROMETHANE TO [(DPPE)RH]2(MU-CL)2 (DPPE = PH2PCH2CH2PPH2) - X-RAY STRUCTURE OF [(DPPE)RHCL]2(MU-CL)2(MU-CH2)
Publication TypeJournal Article
Year of Publication1991
AuthorsBall, GE, Cullen, WR, Fryzuk, MD, James, BR, Rettig, SJ
JournalOrganometallics
Volume10
Pagination3767-3769
Date PublishedOct
Type of ArticleNote
ISBN Number0276-7333
KeywordsCOMPLEXES, CONVERSION, HYDROGENATIONS, imines
Abstract

Dichloromethane reacts with the rhodium chloride-bridged dimer [(dppe)Rh]2(mu-Cl)2, where dppe = Ph2PCH2CH2PPh2, to generate the bridging-methylene derivative [(dppe)RhCl]2(mu-Cl)2(mu-CH2).
URL<Go to ISI>://A1991GK14300058