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Oxidation State Dependent Coordination Modes: Accessing an Amidate-Supported Nickel( I) delta-bis(C-H) Agostic Complex

TitleOxidation State Dependent Coordination Modes: Accessing an Amidate-Supported Nickel( I) delta-bis(C-H) Agostic Complex
Publication TypeJournal Article
Year of Publication2016
AuthorsD. Beattie, D, Bowes, EG, Drover, MW, Love, JA, Schafer, LL
JournalANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume55
Pagination13290-13295
Date PublishedOCT 10
ISSN1433-7851
Abstract

Amidate-supported two-and three-coordinate Ni-I complexes were synthesized by reduction of the corresponding Ni-II precursors. A dramatic change in binding mode is observed upon reduction from Ni-II to Ni-I. The Ni-I derivatives include an unprecedented NiI bis(C-H) agostic complex and a two-coordinate Ni-I complex.

DOI10.1002/anie.201607243