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Lewis adducts of the side-on end-on dinitrogen-bridged complex [(NPN)Ta(2)(mu-H)(2)(mu-eta(1):eta(2)-N-2)] with AlMe3, GaMe3, and B(C6F5)(3): Synthesis, structure, and spectroscopic properties

TitleLewis adducts of the side-on end-on dinitrogen-bridged complex [(NPN)Ta(2)(mu-H)(2)(mu-eta(1):eta(2)-N-2)] with AlMe3, GaMe3, and B(C6F5)(3): Synthesis, structure, and spectroscopic properties
Publication TypeJournal Article
Year of Publication2005
AuthorsStudt, F, MacKay, BA, Johnson, SA, Patrick, BO, Fryzuk, MD, Tuczek, F
JournalChemistry-a European Journal
Volume11
Pagination604-618
Date PublishedJan
Type of ArticleArticle
ISBN Number0947-6539
KeywordsCHEMISTRY, CLEAVAGE, COORDINATED, density functional calculations, DINITROGEN, DINITROGEN COMPLEXES, DINUCLEAR TANTALUM COMPLEX, EFFECTIVE CORE POTENTIALS, FIXATION, MOLECULAR CALCULATIONS, MOLYBDENUM CENTER, N-2 LIGAND, NITROGEN, Raman spectroscopy, REACTIVITY, tantalum, TRIS(PENTAFLUOROPHENYL)BORANE
Abstract

{Reaction of the side-on end-on dinitrogen complex [{(NPN)Ta}(2)(mu- H)(2)(mu-eta(1):eta(2)-N-2)] (1; in which NPN= (PhNSiMe2CH2)(2)PPh), with the Lewis acids XR3 results in the adducts [{(NPN)Ta}(2)(mu-H)(2)(mu-eta(1):eta(2)-NNXR3)]

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