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Dehydrogenation of cyclic amines by a coordinatively unsaturated Cp*Ir(III) phosphoramidate complex

TitleDehydrogenation of cyclic amines by a coordinatively unsaturated Cp*Ir(III) phosphoramidate complex
Publication TypeJournal Article
Year of Publication2017
AuthorsDrover, MW, Schafer, LL, Love, JA
JournalDALTON TRANSACTIONS
Volume46
Pagination8621-8625
Date PublishedJUL 14
ISSN1477-9226
Abstract

The reaction of a Cp{*}Ir(III) phosphoramidate complex with secondary amines gives amine, imine-bound Cp{*}Ir(III) hydride complexes resulting from amine dehydrogenation. These well-characterized species could serve as models of relevant intermediates that have been proposed in catalytic amine dehydrogenation using related N, O-chelated Cp{*}Ir(III) pyridonate complexes.

DOI10.1039/c7dt01499f