@article {3758, title = {2,3-Pyrazinedicarboxylates of cobalt(II), nickel(II), and copper(II); Magnetic properties and crystal structures}, journal = {Canadian Journal of Chemistry-Revue Canadienne De Chimie}, volume = {74}, number = {3}, year = {1996}, note = {ISI Document Delivery No.: UF848Times Cited: 30Cited Reference Count: 28}, month = {Mar}, pages = {433-444}, type = {Article}, abstract = {{Complexes of singly and doubly deprotonated 2,3-pyrazinedicarboxylic acid (pyzdcH(2)) have been prepared and studied. Crystal data: [Ni(pyzdcH)(2)(H2O)(2)], 1, monoclinic, P2(1)/n}, keywords = {3-pyrazinedicarboxylates, ANTIFERROMAGNETISM, COMPLEXES, metal 2, SUPEREXCHANGE MECHANISM, SYNTHESIS, X-ray structure}, isbn = {0008-4042}, url = {://A1996UF84800017}, author = {Mao, L. and Rettig, S. J. and Thompson, R. C. and Trotter, J. and Xia, S. H.} } @article {3758, title = {2,3-Pyrazinedicarboxylates of cobalt(II), nickel(II), and copper(II); Magnetic properties and crystal structures}, journal = {Canadian Journal of Chemistry-Revue Canadienne De Chimie}, volume = {74}, number = {3}, year = {1996}, note = {ISI Document Delivery No.: UF848Times Cited: 30Cited Reference Count: 28}, month = {Mar}, pages = {433-444}, type = {Article}, abstract = {{Complexes of singly and doubly deprotonated 2,3-pyrazinedicarboxylic acid (pyzdcH(2)) have been prepared and studied. Crystal data: [Ni(pyzdcH)(2)(H2O)(2)], 1, monoclinic, P2(1)/n}, keywords = {3-pyrazinedicarboxylates, ANTIFERROMAGNETISM, COMPLEXES, metal 2, SUPEREXCHANGE MECHANISM, SYNTHESIS, X-ray structure}, isbn = {0008-4042}, url = {://A1996UF84800017}, author = {Mao, L. and Rettig, S. J. and Thompson, R. C. and Trotter, J. and Xia, S. H.} } @article {3470, title = {ANTIFERROMAGNETISM AND METAMAGNETISM IN 1,4-DIAZINE AND PYRIDINE COMPLEXES OF NICKEL(II)}, journal = {Canadian Journal of Chemistry-Revue Canadienne De Chimie}, volume = {73}, number = {2}, year = {1995}, note = {ISI Document Delivery No.: QQ128Times Cited: 9Cited Reference Count: 54}, month = {Feb}, pages = {275-283}, type = {Article}, abstract = {Several nickel(II) complexes containing pyridine (py), pyrazine (pyz) or methylpyrazine (mepyz) have been synthesized and characterized by vibrational and electronic spectroscopy, differential scanning calorimetry, and magnetic susceptibility studies to cryogenic temperatures. A comparison of the magnetic properties of the polymeric diazine-bridged complexes, Ni(pyz)(2)X(2) (X = Cl or NO3), Ni(pyz)(p-CH3C6H4SO3)(2), Ni(mepyz)(NO3)(2), and Ni(pyz)(3)(CH3SO3)(2).CH3OH with those of the related monometallic systems, Ni(py)(4)X(2) (X = Cl, p-CH3C6H4SO3 or CH3SO3) and Ni(mepyz)(4)(NO3)(2).H2O provides evidence for weak antiferromagnetic coupling between metal centers mediated by bridging diazine ligands in the former group of compounds. The magnetic properties were analyzed employing a model for S = 1 which takes into account zero-field splitting and employs a molecular field term to account for weak magnetic exchange. The compounds Ni(pyz)Cl-2 and Ni(py)Cl-2, show metamagnetic behaviour with critical fields of 13 and 2 kOe, respectively, at 2 K. In these compounds nickel ions, linked in chains by bridging chlorides, exhibit intrachain ferromagnetic and interchain antiferromagnetic exchange. In Ni(pyz)Cl-2, bridging pyrazine ligands are considered to provide the pathway for the antiferromagnetic coupling resulting in a high critical field.}, keywords = {ANTIFERROMAGNETISM, BRIDGED COPPER(II) COMPLEXES, CHAIN, COMPLEXES, CRYSTAL-STRUCTURE, MAGNETIC EXCHANGE, METAMAGNETISM, MOLECULAR-STRUCTURES, NICKEL(II), polymer, Pyrazine, PYRIDINE, SUPEREXCHANGE MECHANISM, SUSCEPTIBILITY}, isbn = {0008-4042}, url = {://A1995QQ12800015}, author = {Otieno, T. and Thompson, R. C.} }