@article {736,
	title = {Molecules that can{\textquoteright}t resist templation},
	journal = {Chemical Communications},
	number = {14},
	year = {2003},
	note = {ISI Document Delivery No.: 696EETimes Cited: 26Cited Reference Count: 47},
	pages = {1617-1623},
	type = {Article},
	abstract = {The encapsulation of molecules or ions has captured the interest of a variety of researches, including those using zeolites, fullerenes, micelles, clathrates, and metal coordination complexes. Multiple hemispherical units have been used to create organic cages that can bind guests reversibly or irreversibly. Often such cages will only form in the presence of a guest, which acts as a template. This article summarizes some of the work in this field.},
	keywords = {CAPSULES, CARCEPLEXES, CAVITANDS, CONTAINER COMPOUNDS, CRYSTAL-STRUCTURE, HEMICARCEPLEXES, HOST-GUEST COMPLEXATION, PHASE, REVERSIBLE ENCAPSULATION, SHELL CLOSURE},
	isbn = {1359-7345},
	url = {<Go to ISI>://000183872700002},
	author = {Sherman, J.}
}
@article {462,
	title = {Synthesis and characterization of a disulfide-linked C-5-symmetric [5]carceplex},
	journal = {Journal of the American Chemical Society},
	volume = {124},
	number = {1},
	year = {2002},
	note = {ISI Document Delivery No.: 510QCTimes Cited: 23Cited Reference Count: 17},
	month = {Jan},
	pages = {16-17},
	type = {Article},
	keywords = {CARCEPLEXES, CAVITANDS, HOST GUEST COMPLEXATION},
	isbn = {0002-7863},
	url = {<Go to ISI>://000173217900008},
	author = {Naumann, C. and Place, S. and Sherman, J. C.}
}
@article {461,
	title = {Synthesis and conformational dynamics of ortho-xylyl-bridged-[4]cavitands},
	journal = {Tetrahedron},
	volume = {58},
	number = {4},
	year = {2002},
	note = {ISI Document Delivery No.: 515QLTimes Cited: 10Cited Reference Count: 24},
	month = {Jan},
	pages = {787-798},
	type = {Article},
	abstract = {ortho-Xylyl-[4]cavitands 2 to 6 were synthesized from bromoresorcin[4] arenes 1. Cavitands 2 to 6 show C-4nu symmetry in their H-1 NMR spectra at higher temperatures. Dynamic H-1 NMR studies of 2 to 6 indicate the C-4nu symmetry is due to fast interconversion of rectangular C-2nu isomers. This is supported by the crystal structure of 2a, which shows a C-2nu rectangular structure. The activation energy barriers for 2a and 2b were measured by quantitative 1D NOESY (EXSY) experiments. The results were analyzed by the initial rate approximation and matrix calculations. The activation energy barrier was found to depend strongly on the size of the upper rim group (Br, H, OH, CN). In addition, replacing the phenolic proton of tetrol derivatives 4a and 4b with metal ions raises the energy barrier further, likely via bridging metal cations. The two tetrabromo compounds (2a and 2b) reveal a sensitivity of the activation barrier to the feet of the cavitands. Cavitand 6 may act as a hub for radially expanded cavitands. The advantages of the 1D NOESY experiments over the more commonly used two-dimensional experiments are discussed. (C) 2002 Elsevier Science Ltd. All rights reserved.},
	keywords = {1D NOESY (EXSY), CARCEPLEXES, CAVITANDS, CHEMICAL-EXCHANGE, DEEP-CAVITY CAVITANDS, dynamic H-1 NMR, EXCHANGE, HEMICARCEPLEXES, KINETICS, MAGNETIC-RESONANCE SPECTROSCOPY, NMR},
	isbn = {0040-4020},
	url = {<Go to ISI>://000173506800019},
	author = {Naumann, C. and Patrick, B. O. and Sherman, J. C.}
}
@article {4771,
	title = {Bis-capsules: Cooperative reversible encapsulation of two molecules in adjacent separate chambers},
	journal = {Angewandte Chemie-International Edition},
	volume = {39},
	number = {1},
	year = {2000},
	note = {ISI Document Delivery No.: 273GWTimes Cited: 31Cited Reference Count: 27},
	pages = {194-+},
	type = {Article},
	keywords = {CALIXARENES, CARCEPLEXES, CAVITANDS, COMPLEXES, GUESTS, host-guest chemistry, HOSTS, HYDROGEN-BONDS, molecular recognition, NONCOVALENT INTERACTIONS, TEMPLATION},
	isbn = {1433-7851},
	url = {<Go to ISI>://000084700400026},
	author = {Chopra, N. and Naumann, C. and Sherman, J. C.}
}
@article {4874,
	title = {Template effects in the formation of a tetramethylene-bridged hemicarceplex},
	journal = {Journal of the American Chemical Society},
	volume = {122},
	number = {7},
	year = {2000},
	note = {ISI Document Delivery No.: 289TZTimes Cited: 20Cited Reference Count: 57},
	month = {Feb},
	pages = {1337-1342},
	type = {Article},
	abstract = {We report a study of the template effect in the formation of tetramethylene-bridged hemicarceplex 7.guest. Two tetrol cavitands were bridged with 1,4-dibromobutane in the presence of suitable template (guest) molecules in N-formylpiperidine as solvent. Selectivity was observed when competing templates were present during the reaction: the relative templating abilities (template ratios) of 30 different guest molecules range by 3600-fold, and manifest a significant preference for para-disubstituted benzenes. Twenty-one of the 30 hemicarceplexes used in this templation study are new. The trend in guest selectivity is markedly different from previous studies in which smaller cavities (e.g., carceplex 2.guest) are formed. In such studies, capsule 3.guest was a good transition state model, whereas this is not the case in the present work.},
	keywords = {2 BOWLS, BINDING-PROPERTIES, CARCEPLEXES, CONTAINER, CRYSTAL-STRUCTURE, ENCAPSULATION, METAL-ION, O-BENZYNE, REVERSIBLE MOLECULAR CAPSULES, zeolites},
	isbn = {0002-7863},
	url = {<Go to ISI>://000085639200011},
	author = {Makeiff, D. A. and Pope, D. J. and Sherman, J. C.}
}
@article {4503,
	title = {Elucidation of "twistomers" in container compounds},
	journal = {Journal of the American Chemical Society},
	volume = {121},
	number = {9},
	year = {1999},
	note = {ISI Document Delivery No.: 176GRTimes Cited: 28Cited Reference Count: 18},
	month = {Mar},
	pages = {1962-1963},
	type = {Article},
	keywords = {CARCEPLEXES, CRYSTAL-STRUCTURE, HOST-GUEST COMPLEXATION, LANTHANIDE SHIFT-REAGENTS},
	isbn = {0002-7863},
	url = {<Go to ISI>://000079143700029},
	author = {Chapman, R. G. and Sherman, J. C.}
}
@article {4510,
	title = {A giant carceplex permanently entraps three organic molecules},
	journal = {Angewandte Chemie-International Edition},
	volume = {38},
	number = {13-14},
	year = {1999},
	note = {ISI Document Delivery No.: 217RCTimes Cited: 52Cited Reference Count: 26},
	pages = {1955-1957},
	type = {Article},
	keywords = {CAPSULES, CARCEPLEXES, CAVITANDS, CRYSTAL-STRUCTURE, HOST GUEST COMPLEXATION, host-guest chemistry, inclusion compounds, SHELL CLOSURE, TEMPLATE SYNTHESIS},
	isbn = {1433-7851},
	url = {<Go to ISI>://000081511900022},
	author = {Chopra, N. and Sherman, J. C.}
}
@article {3935,
	title = {A bis(carceplex) from a cyclic tetramer of cavitands},
	journal = {Angewandte Chemie-International Edition in English},
	volume = {36},
	number = {16},
	year = {1997},
	note = {ISI Document Delivery No.: XX181Times Cited: 36Cited Reference Count: 35},
	month = {Sep},
	pages = {1727-1729},
	type = {Article},
	keywords = {CALIX<4>ARENE, CARCEPLEXES, CAVITANDS, CHANNELS, CHEMISTRY, COMPLEXES, ENCAPSULATION, HOST, host-guest chemistry, INCLUSION, MOLECULES, self-assembly, supramolecular chemistry, THERMODYNAMICS},
	isbn = {0570-0833},
	url = {<Go to ISI>://A1997XX18100014},
	author = {Chopra, N. and Sherman, J. C.}
}
