@article {2491,
	title = {The Direct Synthesis of Unsymmetrical Vicinal Diamines from Terminal Alkynes: A Tandem Sequential Approach for the Synthesis of Imidazolidinones},
	journal = {Synthesis-Stuttgart},
	number = {1},
	year = {2009},
	note = {ISI Document Delivery No.: 395LSTimes Cited: 6Cited Reference Count: 84Lee, Alison V. Sajitz, Melanie Schafer, Laurel L.Sp. Iss. SI},
	month = {Jan},
	pages = {97-104},
	type = {Article},
	abstract = {The combination of titanium-catalyzed anti-Markovnikov hydroamination of terminal alkynes with the Strecker reaction is used in the synthesis of unsymmetrical vicinal diamines via the one-pot synthesis of alpha-cyanoamines. This methodology is Further applied to the efficient synthesis of imidazolidinones. An easy-to-use bis(amidate)titanium precatalyst permits efficient approaches to heterocyclic chemistry from terminal alkynes.},
	keywords = {AMINES, ANTI-MARKOVNIKOV, ASYMMETRIC-SYNTHESIS, CATALYZED INTERMOLECULAR HYDROAMINATION, HETEROCYCLES, HYDROAMINATION, IMIDO COMPLEXES, INTRAMOLECULAR HYDROAMINATION, LIGANDS, SCOPE, tandem reactions, TITANIUM, TITANIUM PRECATALYST, VINYLARENES},
	isbn = {0039-7881},
	url = {<Go to ISI>://000262526200012},
	author = {Lee, A. V. and Sajitz, M. and Schafer, L. L.}
}
@article {1060,
	title = {Intramolecular hydroamination of unactived olefins with Ti(NMe2)(4) as a precatalyst},
	journal = {Organic Letters},
	volume = {7},
	number = {10},
	year = {2005},
	note = {ISI Document Delivery No.: 924NCTimes Cited: 104Cited Reference Count: 59},
	month = {May},
	pages = {1959-1962},
	type = {Article},
	abstract = {[GRAPHICS] Commercially available Ti(NMe2)(4) has been used effectively as a precatalyst in a facile protocol for the intramolecular hydroamination of aminoalkenes to yield pyrrolidine and piperidine heterocyclic products with isolated yields up to 92\%. Germinally substituted substrates display the highest reactivity. This precatalyst is also effective for the hydroamination of activated internal alkenes, providing access to more complex heterocyclic target molecules.},
	keywords = {ALKENE HYDROAMINATION, ALKYNE, AMIDO COMPLEXES, ANTI-MARKOVNIKOV, CATALYZED INTERMOLECULAR HYDROAMINATION, GROUP-3 METALS, HYDROAMINATION, IMIDO COMPLEXES, REACTIVITY, TITANIUM, ZIRCONIUM},
	isbn = {1523-7060},
	url = {<Go to ISI>://000228984500019},
	author = {Bexrud, J. A. and Beard, J. D. and Leitch, D. C. and Schafer, L. L.}
}
@article {667,
	title = {Amidate complexes of titanium and zirconium: a new class of tunable precatalysts for the hydroamination of alkynes},
	journal = {Chemical Communications},
	number = {19},
	year = {2003},
	note = {ISI Document Delivery No.: 733YYTimes Cited: 71Cited Reference Count: 25},
	month = {Oct},
	pages = {2462-2463},
	type = {Article},
	abstract = {A series of bis(amidate)group 4-bis(amido) complexes have been prepared, characterized and have been shown to be highly tunable precatalysts for both the intra- and intermolecular hydroamination of alkynes.},
	keywords = {AMIDES, ANILINES, CATALYZED INTERMOLECULAR HYDROAMINATION, COORDINATION, INTRAMOLECULAR HYDROAMINATION/CYCLIZATION, LIGAND, TERMINAL ALKYNES},
	isbn = {1359-7345},
	url = {<Go to ISI>://000186029500034},
	author = {Li, C. Y. and Thomson, R. K. and Gillon, B. and Patrick, B. O. and Schafer, L. L.}
}
