@article {2289,
	title = {Capturing aqueous [F-18]-fluoride with an arylboronic ester for PET: Synthesis and aqueous stability of a fluorescent [F-18]-labeled aryltrifluoroborate},
	journal = {Journal of Fluorine Chemistry},
	volume = {129},
	number = {5},
	year = {2008},
	note = {ISI Document Delivery No.: 302SWTimes Cited: 5Cited Reference Count: 12Ting, Richard Lo, Justin Adam, Michael J. Ruth, Thomas J. Perrin, David M.},
	month = {May},
	pages = {349-358},
	type = {Article},
	abstract = {The aqueous stability of aryltrifluoroborates is of importance to their use in transition metal mediated coupling reactions as well as their potential use in [F-18]-labeled aryltrifluoroborate PET imaging agents. Nevertheless, few studies have fully characterized the solvolysis of fluoride from an aryltrifluoroborate in water. Using [F-19] NMR, fluorescence and [F-18]-labeling techniques, we disclose the composition of an aryltrifluoroborate of exceptional kinetic stability with respect to solvolytic defluoridation. This work not only highlights the potential of using [F-18]-labeled aryltrifluoroborates for PET tracers, but provides a chemical platform and a general approach for evaluating the stability of other aryltrifluoroborates. (c) 2008 Elsevier B.V. All rights reserved.},
	keywords = {ACIDS, aryltrifluoroborate, CROSS-COUPLING REACTIONS, KINETICS, PET, SYNTHESIS, [F-18]-labeling},
	isbn = {0022-1139},
	url = {<Go to ISI>://000255990600005},
	author = {Ting, R. and Lo, J. and Adam,Michael J. and Ruth, T. J. and Perrin,David M.}
}
@article {2289,
	title = {Capturing aqueous [F-18]-fluoride with an arylboronic ester for PET: Synthesis and aqueous stability of a fluorescent [F-18]-labeled aryltrifluoroborate},
	journal = {Journal of Fluorine Chemistry},
	volume = {129},
	number = {5},
	year = {2008},
	note = {ISI Document Delivery No.: 302SWTimes Cited: 5Cited Reference Count: 12Ting, Richard Lo, Justin Adam, Michael J. Ruth, Thomas J. Perrin, David M.},
	month = {May},
	pages = {349-358},
	type = {Article},
	abstract = {The aqueous stability of aryltrifluoroborates is of importance to their use in transition metal mediated coupling reactions as well as their potential use in [F-18]-labeled aryltrifluoroborate PET imaging agents. Nevertheless, few studies have fully characterized the solvolysis of fluoride from an aryltrifluoroborate in water. Using [F-19] NMR, fluorescence and [F-18]-labeling techniques, we disclose the composition of an aryltrifluoroborate of exceptional kinetic stability with respect to solvolytic defluoridation. This work not only highlights the potential of using [F-18]-labeled aryltrifluoroborates for PET tracers, but provides a chemical platform and a general approach for evaluating the stability of other aryltrifluoroborates. (c) 2008 Elsevier B.V. All rights reserved.},
	keywords = {ACIDS, aryltrifluoroborate, CROSS-COUPLING REACTIONS, KINETICS, PET, SYNTHESIS, [F-18]-labeling},
	isbn = {0022-1139},
	url = {<Go to ISI>://000255990600005},
	author = {Ting, R. and Lo, J. and Adam,Michael J. and Ruth, T. J. and Perrin,David M.}
}
@article {ISI:000251974000023,
	title = {An electronic rationale for observed initiation rates in ruthenium-mediated olefin metathesis: charge donation in phosphine and N-heterocyclic carbene ligands.},
	journal = {J. Am. Chem. Soc.},
	volume = {129},
	number = {51},
	year = {2007},
	month = {dec},
	pages = {15774{\textendash}6},
	chapter = {15774},
	abstract = {Ru K-edge XAS data indicate that second generation ruthenium-based olefin metathesis precatalysts (L = N-heterocyclic carbene) possess a more electron-deficient metal center than in the corresponding first generation species (L = tricyclohexylphosphine). This surprising effect is also observed from DFT calculations and provides a simple rationale for the slow phosphine dissociation kinetics previously noted for second-generation metathesis precatalysts.},
	keywords = {ALKENES, Alkenes: chemistry, BOND, carbenes, CATALYSTS, CL, DFT, ELECTRONS, Heterocyclic Compounds, Heterocyclic Compounds: chemistry, HYDROCARBONS, Hydrocarbons: chemistry, KINETICS, LIGANDS, MECHANISM, METHANE, Methane: analogs \& derivatives, Methane: chemistry, MOIETY, NHC LIGANDS, OLEFIN METATHESIS, phosphines, Phosphines: chemistry, RAY-ABSORPTION SPECTROSCOPY, ruthenium, Ruthenium: chemistry, TRANSITION-METAL-COMPLEXES, XAS},
	isbn = {0002-7863},
	issn = {1520-5126},
	doi = {10.1021/ja0747674},
	url = {<Go to ISI>://000251974000023 http://www.ncbi.nlm.nih.gov/pubmed/18047332},
	author = {Getty, Kendra and Delgado-Jaime, Mario Ulises and Kennepohl, Pierre}
}
@article {1439,
	title = {Does atmospheric processing of saturated hydrocarbon surfaces by NO3 lead to volatilization?},
	journal = {Geophysical Research Letters},
	volume = {33},
	number = {17},
	year = {2006},
	note = {ISI Document Delivery No.: 085ZJTimes Cited: 23Cited Reference Count: 28Knopf, D. A. Mak, J. Gross, S. Bertram, A. K.},
	month = {Sep},
	pages = {5},
	type = {Article},
	abstract = {The heterogeneous oxidation of a saturated hydrocarbon monolayer by NO3 was studied. A flow tube reactor coupled to chemical ionization mass spectrometry was used to determine the reactive uptake coefficient of NO3 on these surfaces, and X-ray photoelectron spectroscopy (XPS) was used to investigate surface oxidation and to determine if exposure to NO3 leads to volatilization of the organic substrate. The uptake coefficient of NO3 by an alkane monolayer is about (8.8 +/- 2.5) x 10(-4), which may lead to competitive oxidation compared with OH, due to the higher atmospheric abundance of NO3 under certain conditions. The XPS results are consistent with the formation of 1) C-O groups, 2) ketones or aldehydes, and 3) carboxylic groups. The XPS results also suggest that NO3 does not rapidly volatilize the organic surface: even under extremely polluted conditions, maximum 10\% of the organic layer is volatilized.},
	keywords = {FILMS, GAS-PHASE PRODUCTS, HETEROGENEOUS REACTION, KINETICS, LIQUID, OLEIC-ACID, ORGANIC AEROSOLS, ozone, PARTICLES, REACTIVE UPTAKE},
	isbn = {0094-8276},
	url = {<Go to ISI>://000240642600004},
	author = {Knopf, D. A. and Mak, J. and Gross, S. and Bertram, A. K.}
}
@article {1157,
	title = {Reactive uptake of O-3 by multicomponent and multiphase mixtures containing oleic acid},
	journal = {Journal of Physical Chemistry A},
	volume = {109},
	number = {25},
	year = {2005},
	note = {ISI Document Delivery No.: 940CZTimes Cited: 55Cited Reference Count: 80},
	month = {Jun},
	pages = {5579-5589},
	type = {Article},
	abstract = {The heterogeneous reaction of O-3 with lauric acid/oleic acid (LA/OA) mixtures and myristic acid/oleic acid (MA/OA) mixtures were studied as a function of con position, physical state, and microstructure at 298 K. Lauric acid and myristic acid are both alkanoic acids whereas oleic acid is an alkenoic acid. Additionally, we investigated the uptake of O-3 by multicomponent mixtures that closely represent the composition of meat-cooking, aerosols. These measurements were performed with a rotating-wall flow-tube reactor coupled to a chemical ionization mass spectrometer. The reactive uptake coefficients (gamma) of O-3 on liquid LA/OA and MA/OA solutions range from 4 x 10(-4) to 7.2 x 10(-4) The gamma values measured for solid-liquid LA/OA and MA/OA mixtures (which consist of solid LA or solid MA. in equilibrium with a liquid) range from 2 x 10(-5) to 1.7 x 10(-4). These experiments show that only 79\% solid by mass in the solid-liquid mixture can decrease gamma by an order of magnitude compared to the liquid mixtures. The gamma values for solid-liquid mixtures that closely represent the composition of meat-cooking aerosols range from 1.6 x 10(-5) to 6.9 x 10(-5). We found that gamma of solid-liquid mixtures depends on the microstructure of the mixtures, which in turn depends on the method of preparing the films. Furthermore, experiments employing solid-liquid mixtures show an increase in gamma with increasing film age. This can be explained either by the formation of a nonequilibrium phase followed by its relaxation to the stable phase or by Ostwald{\textquoteright}s ripening, which refers to a change in the solid microstructure due to a tendency to minimize the total surface free energy of the solid. We used the obtained gamma values to estimate OA lifetimes for polluted atmospheric conditions. For liquid solutions, the lifetimes were on the order of a few minutes. The lifetimes derived for solid-liquid mixtures are up to 75 min, significantly longer than for liquid solutions. Our study emphasizes the effect of the physical state and microstructure of multicomponent mixtures on the heterogeneous chemistry.},
	keywords = {AIR-POLLUTION, ATMOSPHERIC PARTICLES, CLOUD MICROPHYSICS, FINE ORGANIC AEROSOL, HETEROGENEOUS REACTION, KINETICS, METAL-ALLOYS, ozone, PARTICULATE MATTER, UNSATURATED FATTY-ACIDS},
	isbn = {1089-5639},
	url = {<Go to ISI>://000230122600007},
	author = {Knopf, D. A. and Anthony, L. M. and Bertram, A. K.}
}
@article {461,
	title = {Synthesis and conformational dynamics of ortho-xylyl-bridged-[4]cavitands},
	journal = {Tetrahedron},
	volume = {58},
	number = {4},
	year = {2002},
	note = {ISI Document Delivery No.: 515QLTimes Cited: 10Cited Reference Count: 24},
	month = {Jan},
	pages = {787-798},
	type = {Article},
	abstract = {ortho-Xylyl-[4]cavitands 2 to 6 were synthesized from bromoresorcin[4] arenes 1. Cavitands 2 to 6 show C-4nu symmetry in their H-1 NMR spectra at higher temperatures. Dynamic H-1 NMR studies of 2 to 6 indicate the C-4nu symmetry is due to fast interconversion of rectangular C-2nu isomers. This is supported by the crystal structure of 2a, which shows a C-2nu rectangular structure. The activation energy barriers for 2a and 2b were measured by quantitative 1D NOESY (EXSY) experiments. The results were analyzed by the initial rate approximation and matrix calculations. The activation energy barrier was found to depend strongly on the size of the upper rim group (Br, H, OH, CN). In addition, replacing the phenolic proton of tetrol derivatives 4a and 4b with metal ions raises the energy barrier further, likely via bridging metal cations. The two tetrabromo compounds (2a and 2b) reveal a sensitivity of the activation barrier to the feet of the cavitands. Cavitand 6 may act as a hub for radially expanded cavitands. The advantages of the 1D NOESY experiments over the more commonly used two-dimensional experiments are discussed. (C) 2002 Elsevier Science Ltd. All rights reserved.},
	keywords = {1D NOESY (EXSY), CARCEPLEXES, CAVITANDS, CHEMICAL-EXCHANGE, DEEP-CAVITY CAVITANDS, dynamic H-1 NMR, EXCHANGE, HEMICARCEPLEXES, KINETICS, MAGNETIC-RESONANCE SPECTROSCOPY, NMR},
	isbn = {0040-4020},
	url = {<Go to ISI>://000173506800019},
	author = {Naumann, C. and Patrick, B. O. and Sherman, J. C.}
}
@article {5154,
	title = {Expanding cavitand chemistry: The preparation and characterization of [n]cavitands with n >= 4},
	journal = {Chemistry-a European Journal},
	volume = {7},
	number = {8},
	year = {2001},
	note = {ISI Document Delivery No.: 426VFTimes Cited: 21Cited Reference Count: 26},
	month = {Apr},
	pages = {1637-1645},
	type = {Article},
	abstract = {{The preparation of cavitands composed of 4, 5, 6, and 7 aromatic subunits ([n]cavitands},
	keywords = {CAVITANDS, chemical exchange, CHEMICAL-EXCHANGE, CHEMISTRY, HOST GUEST COMPLEXATION, host-guest chemistry, KINETICS, NMR, supramolecular},
	isbn = {0947-6539},
	url = {<Go to ISI>://000168368500009},
	author = {Naumann, C. and Roman, E. and Peinador, C. and Ren, T. and Patrick, B. O. and Kaifer, A. E. and Sherman, J. C.}
}
@inbook {5198,
	title = {Hot oxygen in the exosphere of Venus},
	booktitle = {Rarefied Gas Dynamics},
	series = {Aip Conference Proceedings},
	volume = {585},
	year = {2001},
	note = {ISI Document Delivery No.: BT38RTimes Cited: 1Cited Reference Count: 35Proceedings Paper22nd International Symposium on Rarefied Gas DynamicsJUL 09-14, 2000SYDNEY, AUSTRALIASandia Natl Labs, AFOSR/AOARD, ONR IFO Asia, Far E, DLR, USA Res Off, GAB Consulting Pty Ltd, Telstra2 HUNTINGTON QUADRANGLE, STE 1NO1, MELVILLE, NY 11747-4501 USA},
	pages = {119-126},
	publisher = {Amer Inst Physics},
	organization = {Amer Inst Physics},
	address = {Melville},
	abstract = {It has now been firmly established from both theoretical calculations and observations, that the exospheres of the terrestrial planets have extended coronas of translational energetic oxygen atoms. The current model generally accepted as the source of these hot atoms is the dissociative recombination of OZ, that is, O-2(+) + e(-) {\textendash}> O* + O* where the product O* atoms are translationally energetic. The determination of the extent of this population of superthermal atoms is an important endeavor. The present paper considers a simple model based on the Boltzmann equation for the energy and altitude dependence of the oxygen atom distribution function. The density and temperature distributions are determined with this distribution.},
	keywords = {ESCAPE, FRACTIONATION, GEOCORONA, HYDROGEN, KINETICS, MARS, MODEL, NITROGEN-ATOMS, O(P-3) ATOMS, UPPER-ATMOSPHERE},
	isbn = {0094-243X0-7354-0025-3},
	url = {<Go to ISI>://000172834300017},
	author = {Shizgal, B. D.},
	editor = {Bartel, T. J. and Gallis, M. A.}
}
@article {4339,
	title = {The co-crystallization of Ru((R)-binap)(eta(3)-Me-allyl)(2) and binap dioxide, and synthesis of Ru(Ph2P(CH2)(4)PPh2)(eta(3)-Me-allyl)(2)},
	journal = {Journal of Organometallic Chemistry},
	volume = {557},
	number = {2},
	year = {1998},
	note = {ISI Document Delivery No.: ZQ872Times Cited: 8Cited Reference Count: 30},
	month = {Apr},
	pages = {213-219},
	type = {Article},
	abstract = {{The molecular structure of the 2-methylallyl species Ru((R)-binap)(eta(3)-Me-allyl)(2) (3) was established by X-ray crystallography of a crystal of 3a, the asymmetric unit of which is composed of half of a molecule of 3 and half of a (R)-(+)-2,2{\textquoteright}-bis(-diphenylphosphinoyl)-1,1{\textquoteright}-binaphthyl(binap dioxide) molecule, co-crystallized with two disordered deuterobenzenes; crystals of 3a are tetragonal, space group I422, with Z = 8},
	keywords = {allyl, ASYMMETRIC HYDROGENATION, BINAP, CATALYSTS, COMPLEXES, ENANTIOSELECTIVE HYDROGENATION, GENERAL-SYNTHESIS, KINETICS, rhodium, ruthenium, RUTHENIUM(II) COMPLEXES, X-ray crystal structure},
	isbn = {0022-328X},
	url = {<Go to ISI>://000073911500007},
	author = {Macfarlane, K. S. and Rettig, S. J. and Liu, Z. Q. and James, Brian R.}
}
@article {4346,
	title = {Equations describing passive transport through vesicular membranes},
	journal = {Biophysical Chemistry},
	volume = {70},
	number = {1},
	year = {1998},
	note = {ISI Document Delivery No.: YU539Times Cited: 4Cited Reference Count: 26},
	month = {Jan},
	pages = {65-74},
	type = {Article},
	abstract = {A theoretical description of the kinetics of the passive transport of both lipophobic and lipophilic nonelectrolytes, weak acids, and weak bases through membranes of large unilamellar vesicles is discussed. Equations are derived which may be used to obtain permeability coefficients and predict the extent of LW entrapment of permeant molecules. Theoretical curves are generated to illustrate the difference between lipophobic and lipophilic permeation. By applying a diffusional approach rather than a simple first order kinetic approach to the problem of passive transport, some of the inconsistencies observed in other works are corrected. (C) 1998 Elsevier Science B.V.},
	keywords = {accumulation, DIFFUSION, FATTY-ACIDS, IONS, KINETICS, LARGE UNILAMELLAR VESICLES, lipid bilayer, LIPID BILAYER-MEMBRANES, LIPOSOMES, PARTITION-COEFFICIENTS, passive, permeability, PROCEDURE, RAPID EXTRUSION, TRANSMEMBRANE PH GRADIENTS, TRANSPORT},
	isbn = {0301-4622},
	url = {<Go to ISI>://000071728000007},
	author = {Males, R. G. and Phillips, P. S. and Herring, F. G.}
}
@article {4263,
	title = {One-electron transformations of paramagnetic cobalt complexes. Synthesis and structure of cobalt(II) amidodiphosphine halide and alkyl complexes and their reaction with alkyl halides},
	journal = {Journal of the American Chemical Society},
	volume = {120},
	number = {39},
	year = {1998},
	note = {ISI Document Delivery No.: 127ZPTimes Cited: 33Cited Reference Count: 106},
	month = {Oct},
	pages = {10126-10135},
	type = {Review},
	abstract = {Complexes of the type CoX[N(SiMe2CH2PPh2)(2)], where X = Cl, Br, or I, can be prepared via reaction of CoX2 with LiN(SiMe2CH2PPh2)(2); these derivatives are tetrahedral high-spin d(7) systems. Reaction of these halide complexes with organolithium, sodium, or potassium reagents generates square-planar, low-spin hydrocarbyl complexes of the formula CoR[N(SiMe2CH2PPh2)(2)] (R = Me, CH2Ph, CH2SiMe3, C5H5). One-electron oxidations have been carried out; only the product of halide abstraction is observed. For example, addition of PhCH2X to the halide derivatives CoX[N(SiMe2CH2PPh2)(2)] generates trivalent, paramagnetic complexes, CoX2[N(SiMe2CH2PPh2)(2)]; these derivatives show variable-temperature magnetic susceptibility data that are consistent with zero-field splitting of the S = 1 state. Addition of methyl bromide or methyl iodide to low-spin CoMe[N(SiMe2CH2PPh2)(2)] results in the formation of the Co(II) halide derivatives CoX[N(SiMe2CH2PPh2)(2)] along with methane and bibenzyl. It is proposed that the Co(III) methyl halide complex CoMe(X) [N(SiMe2CH2PPh2)(2)] is unstable and loses methyl radical homolytically to generate the Co(II) halide derivative; the methyl subsequently reacts with the toluene solvent to produce methane and bibenzyl. Addition of excess benzyl halides has also been found to generate the Co(II) halide complexes initially, followed by a one-electron oxidation to the Co(II) dihalide derivatives. In much of the one-electron chemistry of the Co(II) derivatives incorporating the amidodiphosphine ligand, the decomposition of the putative but unstable Cs(III) alkyl halide derivative CoRX[N(SiMe2CH2PPh2)(2)] is proposed as a recurring event.},
	keywords = {17-ELECTRON, BOND-DISSOCIATION ENERGIES, COORDINATION CHEMISTRY, D6 ML5 COMPLEXES, DERIVATIVES, HIGHER OXIDATION-STATES, KINETICS, LIGAND, ORGANIC HALIDES, RADICAL REACTIONS},
	isbn = {0002-7863},
	url = {<Go to ISI>://000076381000017},
	author = {Fryzuk,Michael D. and Leznoff, D. B. and Thompson, R. C. and Rettig, S. J.}
}
@article {3743,
	title = {Monitoring of the formation and removal of bulk, surface, and interfacial carrier traps on silicon(100)},
	journal = {Canadian Journal of Physics},
	volume = {74},
	year = {1996},
	note = {ISI Document Delivery No.: WU206Times Cited: 8Cited Reference Count: 177th Canadian Semiconductor Technology ConferenceAUG 14-18, 1995OTTAWA, CANADANatl Res Council CanadaSuppl. 1},
	pages = {S233-S238},
	type = {Proceedings Paper},
	abstract = {An RF probe was used to monitor the steady-state photo-generated carrier concentration in silicon with and without an oxide layer. The changes in this steady-state concentration during exposure to gaseous molecular and atomic species such as He, H-2, O-2, H, and O at temperatures between 25 and 450 degrees C are interpreted in terms of changes in the bulk silicon, interface, and exposed surface. The initial experiments established the relationship between the carrier concentration and the RF-probe signal, and distinguished between changes in the bulk, and on silicon surfaces and interfaces. It was found that in the case of hydrogen, bulk passivation and depassivation by H-2 can be observed only at elevated temperatures, with or without an oxide layer. H-atom depassivation can be observed at all temperatures and is irreversible at room temperature. The formation of an oxide layer by exposure to O atoms at 25 and 450 degrees C was followed, and the oxides formed were then treated in an attempt to create an SiO2/Si interface with an acceptable density of interfacial states.},
	keywords = {111 SI-SIO2 INTERFACE, ATOMIC-HYDROGEN, H-2, KINETICS, PASSIVATION, PB CENTERS, SI/SIO2 INTERFACE, STATES, TEMPERATURE},
	isbn = {0008-4204},
	url = {<Go to ISI>://A1996WU20600047},
	author = {Li, H. J. and Ogryzlo, E. A.}
}
@article {3283,
	title = {CHARACTERIZATION OF A RADIOFREQUENCY DISCHARGE USED FOR DOWNSTREAM PLASMA OXIDATION OF SI},
	journal = {Journal of Applied Physics},
	volume = {77},
	number = {4},
	year = {1995},
	note = {ISI Document Delivery No.: QG500Times Cited: 4Cited Reference Count: 26},
	month = {Feb},
	pages = {1690-1695},
	type = {Article},
	keywords = {CHEMICAL-VAPOR-DEPOSITION, GROWTH, KINETICS, SILICON DIOXIDE},
	isbn = {0021-8979},
	url = {<Go to ISI>://A1995QG50000053},
	author = {Cook, J. G. and Lebrun, L. and Li, Z. M. and Ogryzlo, E. A.}
}
@article {3560,
	title = {EVIDENCE FOR REVERSIBLE DISSOCIATIVE ADSORPTION IN THE REACTION OF MOLECULAR CHLORINE WITH GALLIUM-ARSENIDE},
	journal = {Canadian Journal of Chemistry-Revue Canadienne De Chimie},
	volume = {73},
	number = {5},
	year = {1995},
	note = {ISI Document Delivery No.: RG959Times Cited: 2Cited Reference Count: 9},
	month = {May},
	pages = {735-739},
	type = {Article},
	abstract = {The reaction of molecular chlorine with the (100) face of a gallium arsenide crystal has been studied at pressures of Cl-2 between 0.10 and 9.0 Torr and in the temperature range from 90 to 110 degrees C. In contrast to an earlier report, the etch rate was found to be half order with respect to Cl-2. The similarity of these results to those obtained for the reaction of molecular chlorine and bromine with silicon points to a mechanism in which the gaseous halogen molecule is first physisorbed on the semiconductor surface and then dissociates into chemisorbed atoms. The data indicate that both steps occur reversibly at higher pressures, where the composite half-order rate constant can be represented by the Arrhenius equation: k(1/2) = 10(13.6+/-2.6) mu m min(-1) Torr(-1/2) e(-(100+/-19kJ) (mol-1/RT)) At low pressures the first-order rate constant is given by the equation: k(1) = 10(10.4+/-2.3) mu m min(-1) Torr(-1) e(-(76+/-16kJ) (mol-1/RT)},
	keywords = {bromine, DOPED POLYCRYSTALLINE SILICON, ETCHING, GALLIUM ARSENIDE, IODINE, KINETICS, MOLECULAR CHLORINE, RATE CONSTANTS},
	isbn = {0008-4042},
	url = {<Go to ISI>://A1995RG95900014},
	author = {Wong, K. C. and Ogryzlo, E. A.}
}
@article {3390,
	title = {High-resolution Fourier transform infrared study of the out-of-plane bending fundamentals of HCOCl and DCOCl},
	journal = {Journal of Molecular Spectroscopy},
	volume = {174},
	number = {2},
	year = {1995},
	note = {ISI Document Delivery No.: TN850Times Cited: 4Cited Reference Count: 32},
	month = {Dec},
	pages = {353-364},
	type = {Article},
	abstract = {High-resolution infrared spectra of the out-of-plane bending (upsilon(6)) fundamentals of the transient molecules HCOCl and DCOCl are reported. The HCOCl band consists of a C-type component due to the out-of-plane transition moment from the ground state and a Coriolis-induced parallel component which derives its intensity from mixing of the 4(1) and 6(1) vibrational states. In DCOCl, the C-type component is absent, so that all of the band intensity comes from Coriolis-induced borrowing from upsilon(4). The DCOCl upsilon(4) and upsilon(6) bands have been fitted simultaneously to account for the strong first-order and weaker second-order a-axis Coriolis interactions between the fundamentals. In HCOCl the upsilon(6) band is only weakly perturbed by upsilon(4) but is more strongly affected by local interactions with the 5(2) vibrational level, which have been explicitly included in the analysis. Ab initio predictions of the relative intensities of the upsilon(6) fundamentals show that the change in dipole moment is much smaller for DCOCl, accounting for the absence of the C-type component. (C) 1995 Academic Press, Inc.},
	keywords = {CH3CL, CL ATOM, FORMYL CHLORIDE, FTIR, GAS-PHASE REACTIONS, KINETICS, MECHANISMS, MICROWAVE-SPECTRUM, OXIDATION},
	isbn = {0022-2852},
	url = {<Go to ISI>://A1995TN85000007},
	author = {Joo, D. L. and Clouthier, D. J. and Merer, A. J.}
}
@article {3391,
	title = {A HIGH-RESOLUTION FOURIER-TRANSFORM INFRARED STUDY OF THE NU(3)-BAND, NU(4)-BAND, AND NU(5)-BAND OF DEUTERATED FORMYL CHLORIDE (DCOCL)},
	journal = {Journal of Molecular Spectroscopy},
	volume = {170},
	number = {2},
	year = {1995},
	note = {ISI Document Delivery No.: QT231Times Cited: 8Cited Reference Count: 21},
	month = {Apr},
	pages = {346-355},
	type = {Article},
	abstract = {High-resolution infrared spectra of the low-lying nu(3), nu(4), and nu(5) fundamentals of the transient molecule DCOCl are reported. These type-A/B hybrid bands have been analyzed in detail, providing extensive rotational assignments for the (DCOCl)-Cl-35 and (DCOCl)-Cl-37 isotopomers. The ground state constants have been refined by a simultaneous fit of the available microwave data and FTIR combination differences from the three bands. The excited state constants have been determined by fitting assignments over a wide range of J and K-a values. A small perturbation was found at high K-a values in the nu(4) band and determined to be due to a Delta K-d = -2 interaction with the rotational levels of the 6(1) vibrational state. (C) 1995 Academic Press, Inc.},
	keywords = {CL ATOM, FTIR, GAS-PHASE REACTIONS, KINETICS, MICROWAVE-SPECTRUM, OXIDATION},
	isbn = {0022-2852},
	url = {<Go to ISI>://A1995QT23100005},
	author = {Joo, D. L. and Laboy, J. and Kolomeisky, A. and Zhuo, Q. and Clouthier, D. J. and Chan, C. P. and Merer, A. J. and Judge, R. H.}
}
@article {3392,
	title = {KINETICS AND MECHANISM OF H-2-HYDROGENATION OF STYRENE CATALYZED BY [RUCL(DPPB)(MU-CL)](2) (DPPB=1,4-BIS(DIPHENYLPHOSPHINO)BUTANE) - EVIDENCE FOR HYDROGEN-TRANSFER FROM A DINUCLEAR MOLECULAR-HYDROGEN SPECIES},
	journal = {Journal of Organometallic Chemistry},
	volume = {488},
	number = {1-2},
	year = {1995},
	note = {ISI Document Delivery No.: QG254Times Cited: 32Cited Reference Count: 31},
	month = {Feb},
	pages = {161-167},
	type = {Article},
	abstract = {Kinetic studies on the H-2-hydrogenation of styrene catalyzed by [RuCl(dppb)(mu-Cl)](2) (dppb = Ph(2)P(CH2)(4)PPh(2)) in N,N-dimethylacetamide solution, near ambient conditions have revealed a first-order dependence on Ru, and dependences on H-2 and on styrene that are first-order at lower concentrations and decrease with increasing concentration. Considered along with NMR and tensiometric data, the findings are interpreted in terms of a basic hydride route in which an initially formed, dinuclear, molecular hydrogen complex (eta(2)-H-2)Ru(dppb)(mu-Cl)(3)RuCl(dppb) transfers both hydrogens to the styrene.},
	keywords = {ASYMMETRIC HYDROGENATION, BINAP, CATALYSIS, COMPLEXES, DIHYDROGEN, dihydrogen complexes, HYDROGENATION, KINETICS, LIGANDS, phosphine, ruthenium, RUTHENIUM(II) COMPLEXES, SELECTIVE, STYRENE, UNSATURATED CARBOXYLIC-ACIDS},
	isbn = {0022-328X},
	url = {<Go to ISI>://A1995QG25400022},
	author = {Joshi, A. M. and Macfarlane, K. S. and James, Brian R.}
}
@article {3321,
	title = {ROUTES TO DICATIONIC RUTHENIUM(II) NITRILE COMPLEXES CONTAINING CHELATING DIPHOSPHINE LIGANDS - X-RAY ANALYSES OF RU(DPPB)(MECN)(4)(2+)2PF(6)- (DPPB=PH(2)P(CH2)(4)PPH(2)) AND TRANS-RUCL2(MECN)(4)},
	journal = {Canadian Journal of Chemistry-Revue Canadienne De Chimie},
	volume = {73},
	number = {7},
	year = {1995},
	note = {ISI Document Delivery No.: RT503Times Cited: 13Cited Reference Count: 27},
	month = {Jul},
	pages = {1084-1091},
	type = {Article},
	abstract = {{Routes to the Ru(PP)(RCN)(4)(2+)2PF(6)(-) complexes (PP = Ph(2)P(CH2)(4)PPh(2), dppb; R = Me, Ph) from the Ru(II) precursors Ru2Cl4(PP)(2) and RuCl2(PP)(PPh(3)) have been established. The X-ray crystal structure of the dppb-MeCN derivative (3) is described, and the steric effect of the diphosphine ligand is examined by comparison with the crystal structure of trans-RuCl2(MeCN)(4) (5), which is also presented. Crystals of 3 are triclinic},
	keywords = {ACETONITRILE, CRYSTAL, DIPHOSPHINE LIGANDS, EXCHANGE, HYDROGENATION, KINETICS, NITRILES, ruthenium},
	isbn = {0008-4042},
	url = {<Go to ISI>://A1995RT50300023},
	author = {Fogg, D. E. and Rettig, S. J. and James, Brian R.}
}
@article {3143,
	title = {CATALYTIC OXYGEN BLEACHING OF WOOD PULP WITH METAL PORPHYRIN AND PHTHALOCYANINE COMPLEXES},
	journal = {Tappi Journal},
	volume = {77},
	number = {11},
	year = {1994},
	note = {ISI Document Delivery No.: PQ091Times Cited: 11Cited Reference Count: 10},
	month = {Nov},
	pages = {119-125},
	type = {Article},
	abstract = {A series of porphyrin and phthalocyanine complexes of Co, Fe, and Mn is screened for catalytic activity in the oxygen bleaching of unbleached softwood kraft pulp in 1 M KOH at 25 and 100 degrees C under 0.8 MPa oxygen pressure. The Mn(III) complex of meso(tetrasulfonatophenyl) porphyrin, isolated as Na3Mn(TSPP).4H(2)O and abbreviated as Mn(TSPP), is shown to promote delignification and suppress cellulose degradation in oxygen bleaching. The influence of bleaching time, pH, temperature, oxygen pressure, and Mn(TSPP) charge on catalytic activity is assessed by factorial and parametric experiments. The Mn(TSPP) is effective at a minimum concentration of about 0.025 g/L (0.023 x 10(-3) M) and is most beneficial for bleaching rate and selectivity in 1 M KOH at high temperature and oxygen pressure (100 degrees C, 0.8 MPa O-2).},
	keywords = {CATALYSTS, KINETICS, OXYGEN BLEACHING, SELECTIVITY, transition metals},
	isbn = {0734-1415},
	url = {<Go to ISI>://A1994PQ09100013},
	author = {Perng, Y. S. and Oloman, C. W. and Watson, P. A. and James, Brian R.}
}
@article {3204,
	title = {INSERTION REACTION OF DIMETHYLACETYLENEDICARBOXYLATE WITH THE HEAD-TO-TAIL ISOMER OF PT2I2(MU-PPY3)2 PPY3=TRIS(2-PYRIDYL)PHOSPHINE},
	journal = {Inorganica Chimica Acta},
	volume = {217},
	number = {1-2},
	year = {1994},
	note = {ISI Document Delivery No.: NA902Times Cited: 9Cited Reference Count: 15},
	month = {Mar},
	pages = {209-212},
	type = {Note},
	abstract = {The head-to-tail (HT) isomer of Pt2I2(mu-Ppy3)2 (3), where py=2-pyridyl, is made by reaction of NaI with the chloro analogue (2), which it itself synthesized via a conproportionation reaction of a Pt(0) complex and cis-PtCl2(mu-PPY3)2 (1). Complex 1 is formed by reacting appropriate Pt(II) precursors with Ppy3. Dimethylacetylenedicarboxylate (DMAD) inserts into the Pt-Pt bond of 3 to give the A-frame species HT-Pt2I2(mu-PpY3)2(mu-DMAD) (4); the reaction is kinetically first-order in both [3] and [DMAD], and the activation parameters (DELTAH(not-equal) = 38 kJ mol-1, DELTAS(not-equal) = -138 J mol-1 K-1) are consistent with a concerted process involving a four-centre transition state. Complexes 1-4 are characterized by elemental analyses and (P{H})P-31-H-1 and (Pt{H})-Pt-195-H-1 NMR spectroscopy.},
	keywords = {ALKYNE COMPLEXES, bis(diphenylphosphino)methane, COMPLEXES, DIMERS, DINUCLEAR, INSERTION REACTION, KINETICS, LIGANDS, PLATINUM COMPLEXES},
	isbn = {0020-1693},
	url = {<Go to ISI>://A1994NA90200032},
	author = {Xie, L. Y. and James, Brian R.}
}
@article {2813,
	title = {THE ETCHING OF GALLIUM-ARSENIDE WITH IODINE MONOCHLORIDE},
	journal = {Journal of the Electrochemical Society},
	volume = {140},
	number = {1},
	year = {1993},
	note = {ISI Document Delivery No.: KF885Times Cited: 2Cited Reference Count: 7},
	month = {Jan},
	pages = {226-229},
	type = {Article},
	abstract = {The reaction of GaAs(100) with iodine monochloride has been studied at ICl pressures between 0.10 and 0.80 Torr and in the temperature range from 100 to 300-degrees-C. At low temperatures the etch rate is first order in ICl, and decreases as the temperature increases, dropping to a minimum at about 140-degrees-C. Above this temperature the order of the reaction drops below 1, and the etch rate increases with increasing temperature. This complex behavior is analyzed in terms of two distinct mechanisms. At low temperatures the negative temperature dependence is explained by a physisorption controlled mechanism and is characterized by the rate law Etch rate = 10(-5.8+/-0.2) mum min-1 Torr-1 e+(47+/-1 kJ mol-1/RT)P(ICl) At higher temperatures the data is consistent with a mechanism in which the ICl is dissociatively adsorbed on the GaAs. At low pressures the rate law is given by Etch rate = 10(5.6+/-1.7) mum min-1 Torr-1 e-(39+/-17 kJ mol-1/RT)P(ICl) At higher pressures the dissociative adsorption becomes reversible, the order of the reaction becomes one-half, and the rate law takes the form Etch rate = 10(4.4+/-0.1) mum min-1 Torr-1/2 e-(33+/-1 kJ mol-1/RT) square-root P(ICl)},
	keywords = {bromine, KINETICS, MOLECULAR CHLORINE, SILICON},
	isbn = {0013-4651},
	url = {<Go to ISI>://A1993KF88500047},
	author = {Hahn, L. L. and Wong, K. C. and Ogryzlo, E. A.}
}
@article {7265,
	title = {COORDINATION CHEMISTRY OF 2-(2{\textquoteright}-HYDROXYPHENYL)-2-OXAZOLINES WITH ALUMINUM, GALLIUM, AND INDIUM - 1ST TRIS(LIGAND)METAL(III) COMPLEXES OF THIS NATURALLY-OCCURRING BINDING GROUP},
	journal = {Inorganic Chemistry},
	volume = {31},
	number = {26},
	year = {1992},
	note = {ISI Document Delivery No.: KE754Times Cited: 62Cited Reference Count: 44},
	month = {Dec},
	pages = {5408-5416},
	type = {Article},
	abstract = {{A series of tris(ligand)metal(III) complexes of group 13 metals (Al, Ga, In) with 2-(2{\textquoteright}-hydroxyphenyl)-2-oxazoline (Hoz), 2-(5{\textquoteright}-bromo-2{\textquoteright}-hydroxyphenyl)-2-oxazoline (HBroz), 2-(2{\textquoteright}-hydroxy-3{\textquoteright}-methylphenyl)-2-oxazoline(Hmoz), 2-(2{\textquoteright}-hydroxy-3{\textquoteright}-allylphenyl)-2-oxazoline (Haloz) have been prepared. These compounds have been studied by a variety of techniques including variable-temperature NMR (H-1 and Al-27) and single-crystal X-ray diffraction. The M(OZ)3-CH3OH complexes (M = Al, Ga, In) are isomorphous and isostructural. Crystallographic data for C28H28MN3O7: monoclinic},
	keywords = {CHIRAL, CRYSTAL-STRUCTURE, ENTEROBACTIN, INTRAMOLECULAR REARRANGEMENT REACTIONS, ISOMERIZATION, KINETICS, LIGANDS, MICROBIAL IRON TRANSPORT, PROBABLE MECHANISM, SIDEROPHORES, TRIS-CHELATE COMPLEXES},
	isbn = {0020-1669},
	url = {<Go to ISI>://A1992KE75400016},
	author = {Hoveyda, H. R. and Karunaratne, V. and Rettig, S. J. and Orvig, Chris}
}
@article {6889,
	title = {QUANTUM PHENOMENA AND SOLVENT EFFECTS ON ADDITION OF HYDROGEN ISOTOPES TO BENZENE AND TO DIMETHYLBUTADIENE},
	journal = {Berichte Der Bunsen-Gesellschaft-Physical Chemistry Chemical Physics},
	volume = {94},
	number = {11},
	year = {1990},
	note = {ISI Document Delivery No.: EU906Times Cited: 18Cited Reference Count: 4189TH GENERAL ASSEMBLY OF THE DEUTSCHE-BUNSEN-GESELLSCHAFT-FUR-PHYSIKALISCHE-CHEMIE ( ON THE 65TH BIRTHDAY OF THEODOR ACKERMANN ) : CHEMICAL ELEMENTAL REACTIONSMAY 24-26, 1990TUBINGEN, FED REP GERDEUT BUNSEN GESELL PHYS CHEM},
	month = {Nov},
	pages = {1224-1230},
	type = {Proceedings Paper},
	abstract = {Rate constants have been measured for the reaction of the light hydrogen isotope muonium with benzene and 2,3-dimethylbutadiene-1,3 in the gas phase and in several solvents. Comparison with H atom data reveals (1) appreciable kinetic isotope effects, (2) a strong contribution of tunnelling for the activated reaction with benzene, (3) encounter controlled reaction for Mu addition to the diene, (4) a mass dependence of the diffusion constant of hydrogen isotopes in solution, and (5) an enhancement of the rate constant in solution over that in the gas phase by a factor, except for water, of the inverse Ostwald solubility coefficient for hydrogen. The isotope-dependent reduction of the solvent effect in water is tentatively ascribed to the dynamics of the clathrate-like structure when the hydrogen atom reacts.},
	keywords = {ATOM, DIFFUSION, electron, ELEMENTARY REACTIONS, GASES, ISOTOPE EFFECTS, KINETICS, LIQUIDS, muonium, radicals, RATE CONSTANTS, solutions, WATER},
	isbn = {0005-9021},
	url = {<Go to ISI>://A1990EU90600008},
	author = {Roduner, E. and Louwrier, P. W. F. and Brinkman, G. A. and Garner, D. M. and Reid, I. D. and Arseneau, D. J. and Senba, M. and Fleming, Donald G.}
}
