@article {3007, title = {EXCESS PARTIAL MOLAR VOLUMES AND THERMAL EXPANSIVITIES IN THE WATER-RICH REGION OF AQUEOUS 2-BUTANONE}, journal = {Journal of Solution Chemistry}, volume = {23}, number = {2}, year = {1994}, note = {ISI Document Delivery No.: NB508Times Cited: 8Cited Reference Count: 22Symposium in Honor of Donald Patterson on His 65th Birthday, at the 76th Congress of the Canadian-Society-for-ChemistryMAY 31-JUN 03, 1993SHERBROOKE, CANADACANADIAN SOC CHEM}, month = {Feb}, pages = {339-349}, type = {Proceedings Paper}, abstract = {Excess partial molar volumes of 2-butanone V(m)E(B) and thermal expansivities alpha(p) were measured in the water-rich region of aqueous 2-butanone. The composition derivatives of both quantities showed anomalies at about X(B) = 0.033 (x(B) is the mole fraction of B). (partial derivative V(m)E(B)/partial derivative n(B))p,T,nW showed a step anomaly, while (partial derivative alpha(p)/partial derivatives n(B))p,T,nw exhibited a peak anomaly. The compositions at which these anomalies occurred match those of the step anomalies observed earlier in (partial derivative H(m)E(B)/partial derivative n(B))p,T,nW and (partial derivative S(m)E(B)/partial derivative n(B))p,T,nW in aqueous 2-butanone. These results are discussed in comparison with those obtained previously for aqueous 2-butoxyethanol.}, keywords = {2-BUTANONE, 2-BUTOXYETHANOL, 25-DEGREES-C, ANOMALIES IN 3RD DERIVATIVES, AQUEOUS, DERIVATIVES, ENTHALPIES, EXCESS PARTIAL MOLAR VOLUMES, fluctuations, FREE-ENERGIES, HEAT-CAPACITIES, MIXING SCHEME, OF GIBBS FREE ENERGY, TERT-BUTANOL MIXTURES, THERMAL EXPANSIVITIES, TRANSITION, TRANSITION OF MIXING SCHEME}, isbn = {0095-9782}, url = {://A1994NB50800016}, author = {Davies, J. V. and Fooks, R. and Koga,Yoshikata} }