@article {1513,
	title = {The interaction of patterned solutes in binary solvent mixtures},
	journal = {Journal of Chemical Physics},
	volume = {124},
	number = {9},
	year = {2006},
	note = {ISI Document Delivery No.: 019IHTimes Cited: 1Cited Reference Count: 44},
	month = {Mar},
	pages = {11},
	type = {Article},
	abstract = {Mean solute-solute forces and solute-induced solvent structure are investigated for pairs of chemically patterned (patched) solutes in binary mixtures near demixing coexistence. The isotropic and anisotropic hypernetted-chain integral equation theories as well as a superposition approximation are solved and compared. The patched solutes consist of one end that favors the majority species in the mixture while the other end favors the minority species. A wide range of patch sizes is considered. The isotropic and anisotropic theories are found to be in good agreement for most orientations, including the most attractive and most repulsive configurations. However, some differences arise for asymmetrical orientations where unlike ends of the solute particles face each other. In contrast, superposition often gives a rather poor approximation to the mean force, even though the results obtained for the solvent densities agree qualitatively with the anisotropic theory. The mean force is sensitive to small differences in the densities particularly near demixing. For patched solutes the influence of demixinglike behavior is evident both in the orientational dependence and in the range of the mean force acting between solutes. (c) 2006 American Institute of Physics.},
	keywords = {BRIDGE DIAGRAM SERIES, FLUID, HARD-SPHERES, HYDROPHOBIC SURFACES, LENNARD-JONES, LIQUID MIXTURES, MACROPARTICLES, PHASE-TRANSITION, RANGE, SPHERICALLY INHOMOGENEOUS FLUIDS, WATER},
	isbn = {0021-9606},
	url = {<Go to ISI>://000235828300034},
	author = {Overduin, S. D. and Patey, G. N.}
}
@article {1224,
	title = {Solvent phase behavior and the interaction of uniform and patterned solutes},
	journal = {Journal of Chemical Physics},
	volume = {123},
	number = {19},
	year = {2005},
	note = {ISI Document Delivery No.: 985CHTimes Cited: 2Cited Reference Count: 42},
	month = {Nov},
	pages = {10},
	type = {Article},
	abstract = {Isotropic and anisotropic hypernetted-chain (HNC) integral equation theories are used to obtain the interaction of solutes both near and far from the solvent liquid-vapor coexistence. Spherically symmetrical and chemically patterned (patched) solutes are considered, and the influences of particle and patch sizes are investigated. Solvophilic and solvophobic solutes (or patches) are examined. Near coexistence, in the solvophobic case drying like behavior occurs for solutes (patches) of sufficient size. This gives rise to relatively long ranged attractive forces that are strongly orientation dependent for the patched solute particles. We also report grand canonical Monte Carlo results for a pair of spherically symmetric solutes. This demonstrates that the anisotropic HNC theory gives qualitatively correct solvent structure in the vicinity of the solutes. Comparison with previous simulations also shows that the solute-solute potentials of mean force given by the anisotropic theory are more accurate (particularly at small separations) than those obtained using the isotropic method. (c) 2005 American Institute of Physics.},
	keywords = {BINARY-FLUID MIXTURE, BRIDGE DIAGRAM SERIES, HYDROPHOBIC SURFACES, INTEGRAL-EQUATION, LENNARD-JONES FLUIDS, MACROPARTICLES, MEAN FORCE, RANGE, SPHERICALLY INHOMOGENEOUS FLUIDS, TRANSITION},
	isbn = {0021-9606},
	url = {<Go to ISI>://000233353200029},
	author = {Overduin, S. D. and Patey, G. N.}
}
@article {911,
	title = {"Icebergs" or no "Icebergs" in aqueous alcohols?: Composition-dependent mixing schemes},
	journal = {Journal of Physical Chemistry A},
	volume = {108},
	number = {17},
	year = {2004},
	note = {ISI Document Delivery No.: 814TNTimes Cited: 22Cited Reference Count: 38},
	month = {Apr},
	pages = {3873-3877},
	type = {Article},
	abstract = {The classical concept of "iceberg formation" is modified by our recent thermodynamic studies. The local enhancement of the hydrogen-bond network of H2O in the immediate vicinity of small nonelectrolyte solutes (i.e., the "iceberg formation") is still correct. However, the hydrogen-bond probability of bulk H2O away from solutes is reduced progressively, as the solute composition increases. When the hydrogen-bond probability of bulk H2O is reduced to the bond percolation threshold of the hexagonal ice connectivity, the hydrogen-bond percolation is lost and a qualitatively different mixing scheme sets in, whereby the solution consists of two kinds of clusters. In the solute-rich region, solute molecules form Clusters of its own kind. Thus, the "iceberg, formation" is basically correct within a narrow range in the H2O-rich region for small nonelectrolyte solutes. Thus, reference made to the "iceberg" concept in recent literatures should be clarified in terms of the concentration range and the size of solute in question.},
	keywords = {2-BUTOXYETHANOL, BUTANOL, fluctuations, hydration, HYDROPHOBIC SURFACES, MIXTURES, PARTIAL MOLAR VOLUMES, TERT-BUTYL ALCOHOL, WATER-RICH REGION, X-RAY-SCATTERING},
	isbn = {1089-5639},
	url = {<Go to ISI>://000220997100023},
	author = {Koga,Yoshikata and Nishikawa, K. and Westh, P.}
}
@article {704,
	title = {Surfactant-stabilized structures in confined liquids},
	journal = {Journal of Chemical Physics},
	volume = {119},
	number = {16},
	year = {2003},
	note = {ISI Document Delivery No.: 731BWTimes Cited: 5Cited Reference Count: 48},
	month = {Oct},
	pages = {8676-8685},
	type = {Article},
	abstract = {Grand canonical Monte Carlo simulations are used to investigate the effect of surfactant on binary Lennard-Jones mixtures confined between planar, chemically patterned surfaces. Near bulk demixing coexistence, confined binary mixtures form liquid "bridges" joining specifically patterned surface areas. The length of these bridges is restricted by the unfavorable liquid-liquid interfacial tension, and in the present paper we show that this constraint can be significantly reduced by adding surfactant to the system. This leads to very extended liquid bridges and to other structures not found in the simple two-component case. We give a qualitative discussion of the surface-surfactant -induced liquid structures and examine in detail the associated forces acting between the plates. (C) 2003 American Institute of Physics.},
	keywords = {CAPILLARY CONDENSATION, DENSITY-FUNCTIONAL METHOD, HYDROPHILIC SURFACES, HYDROPHOBIC SURFACES, INTERACTION FORCES, LAMELLAR PHASES, LENNARD-JONES FLUID, MORPHOLOGICAL WETTING TRANSITIONS, PHASE-TRANSITIONS, SLIT-LIKE PORES},
	isbn = {0021-9606},
	url = {<Go to ISI>://000185865500048},
	author = {Overduin, S. D. and Patey, G. N.}
}
@article {472,
	title = {Forces between chemically patterned plates immersed in binary liquid mixtures},
	journal = {Journal of Chemical Physics},
	volume = {117},
	number = {7},
	year = {2002},
	note = {ISI Document Delivery No.: 579WWTimes Cited: 9Cited Reference Count: 31},
	month = {Aug},
	pages = {3391-3397},
	type = {Article},
	abstract = {Grand canonical Monte Carlo calculations are used to investigate the phase behavior of a binary mixture of Lennard-Jones particles confined between planar, parallel, chemically patterned plates. Attention is focused on the influence of surface-induced transitions on the net force acting between the plates. In addition to the stable and metastable bulk states that play a crucial role for homogeneous surfaces, for certain patterns and surface separations a bridge phase analogous to that recently reported for one-component systems is observed. It is found that bridge phase formation leads to strongly attractive plate-plate forces that are equal in magnitude to those observed for homogeneous surfaces. The significance of our results for the interaction and behavior of nonuniform macroparticles in solution is discussed. (C) 2002 American Institute of Physics.},
	keywords = {CHARGED HARD-SPHERES, HYDROPHOBIC SURFACES, LENNARD-JONES FLUID, MACROPARTICLES, MONTE-CARLO, PHASE-TRANSITION, STATISTICAL-MECHANICS, WALLS, WATER},
	isbn = {0021-9606},
	url = {<Go to ISI>://000177202300048},
	author = {Overduin, S. D. and Patey, G. N.}
}
@article {5086,
	title = {Demixing and the force between parallel plates immersed in binary liquid mixtures},
	journal = {Journal of Chemical Physics},
	volume = {114},
	number = {16},
	year = {2001},
	note = {ISI Document Delivery No.: 420ZQTimes Cited: 16Cited Reference Count: 23},
	month = {Apr},
	pages = {7182-7188},
	type = {Article},
	abstract = {Grand Canonical Monte Carlo calculations are used to examine the phase behavior of model binary liquid mixtures confined between parallel plates. The stable and metastable states are identified by direct evaluation of the grand potential. It is shown that demixing transitions can lead to long-range attractive forces acting between the plates, verifying earlier predictions based on approximate integral equation theories. The nature of these transitions and the physical origin of the accompanying attractive forces are discussed. (C) 2001 American Institute of Physics.},
	keywords = {CHARGED HARD-SPHERES, HYDROPHOBIC SURFACES, LENNARD-JONES FLUID, MACROPARTICLES, MONTE-CARLO, PHASE-TRANSITION, STATISTICAL-MECHANICS, WALLS},
	isbn = {0021-9606},
	url = {<Go to ISI>://000168036900026},
	author = {Greberg, H. and Patey, G. N.}
}
@article {3786,
	title = {Remarks on the forces between macroscopic particles in solution},
	journal = {Berichte Der Bunsen-Gesellschaft-Physical Chemistry Chemical Physics},
	volume = {100},
	number = {6},
	year = {1996},
	note = {ISI Document Delivery No.: UW575Times Cited: 21Cited Reference Count: 221st International Symposium on Polyelectrolytes/Discussion Meeting of Deutsche-Bunsen-Gesellschaft-fur-Physikalische-Chemie on Polyelectrolytes in Solution and at InterfacesSEP 18-22, 1995POTSDAM, GERMANYDeut Bunsen Gesell Phys chem},
	month = {Jun},
	pages = {885-888},
	type = {Proceedings Paper},
	abstract = {Some interesting aspects of the forces acting between macroscopic objects (spheres and plates) immersed in solution are discussed. These include attractive forces between like-charged objects in primitive model electrolyte solutions, van der Waals forces in molecular solvents, and strong attractive interactions related to cavitation or separation-induced evaporation of liquids between inert or {\textquoteright}{\textquoteright}solvophobic{\textquoteright}{\textquoteright} walls.},
	keywords = {ATTRACTION, COLLOIDAL PARTICLES, ELECTRICAL DOUBLE-LAYER, ELECTROLYTE SOLUTION, FLUIDS, HYDROPHOBIC SURFACES, HYPERNETTED-CHAIN APPROXIMATION, LENNARD-JONES, molecular interactions, MONTE-CARLO, solutions, SYMMETRICAL POISSON-BOLTZMANN},
	isbn = {0005-9021},
	url = {<Go to ISI>://A1996UW57500032},
	author = {Patey, G. N.}
}
