@article {1202,
	title = {Effect of an "ionic liquid" cation, 1-butyl-3-methylimidazolium, on the molecular organization of H2O},
	journal = {Journal of Physical Chemistry B},
	volume = {109},
	number = {18},
	year = {2005},
	note = {ISI Document Delivery No.: 924MMTimes Cited: 46Cited Reference Count: 46},
	month = {May},
	pages = {9014-9019},
	type = {Article},
	abstract = {The excess partial molar enthalpy of 1-propanol (1P), H-1P(E), was measured at 28 \&DEG; C in the ternary mixture of 1P-1-butyl-3-methylimidazolium chloride ([bmim]Cl)-H2O in the H2O-rich composition range. From these data we evaluated what we call the 1P-1P enthalpic interaction function, H-1P-1P(E). Its changes induced by addition of (bmim]Cl of the pattern of H-1P-1P(E) were used as a probe to elucidate the effect of [bmim]Cl on the molecular organization of H2O. It was found that the effect of Cl- was not conspicuous within this methodology, and the observed dependence is predominantly due to the hydration of [bmim](+). The changes in the \&chi;(1P)-dependence of H-1P-1P(E) were compared with those brought about by temperature increase, or by the addition of fructose or glycerol. It was found that the effect of [bmim](+) is similar to that of fructose or increased temperature. We speculate that in the H2O-rich composition region a number of H2O molecules are attracted to the delocalized positive charge of the imidazolium ring and the bulk of H2O is influenced in such a manner that the global hydrogen bond probability is reduced.},
	keywords = {25-DEGREES-C, ALKANE-MONO-OLS, AQUEOUS-SOLUTIONS, fluctuations, HEXAFLUOROPHOSPHATE, MIXING SCHEMES, PARTIAL MOLAR ENTHALPIES, SOLVENTS, TERT-BUTANOL MIXTURES, WATER SOLUTIONS},
	isbn = {1520-6106},
	url = {<Go to ISI>://000228982900071},
	author = {Miki, K. and Westh, P. and Nishikawa, K. and Koga,Yoshikata}
}
@article {7196,
	title = {ORGANOMETALLIC NITROSYL CHEMISTRY .51. NEW ORGANOMETALLIC NITROSYL CATIONS CONTAINING THE GROUP-6 ELEMENTS},
	journal = {Organometallics},
	volume = {11},
	number = {2},
	year = {1992},
	note = {ISI Document Delivery No.: HE298Times Cited: 14Cited Reference Count: 39},
	month = {Feb},
	pages = {913-922},
	type = {Article},
	abstract = {{Treatment of the dihalo nitrosyl complexes of molybdenum and tungsten, Cp{\textquoteright}M(NO)X2 (Cp{\textquoteright} = Cp (eta(5)-C5H5), Cp* (eta(5)-C5Me5); M = Mo, W;X = Cl, Br, I), in CH3CN with NO+ or Ag+ salts affords a series of new diamagnetic cationic nitrosyl complexes, [Cp*Mo(NO)(NCCH3)3]2+ and [Cp{\textquoteright}M(NO)X(NCCH3)2]+. Eight such complexes have been isolated analytically pure as either their PF6- or BF4- salts by crystallization from CH3CN/Et2O. The physical and spectroscopic properties of these organometallic cations are consistent with their possessing four-legged piano stool molecular structures. This conclusion has been confirmed by single-crystal X-ray crystallographic analyses of [Cp*Mo(NO)(NCCH3)3][PF6]2 and [CpMo(NO)Cl-(NCCH3)2]BF4 which also establish that the acetonitrile ligands are coordinated linearly through their N atoms to the metal centers. Crystal data for [Cp*Mo(NO)(NCCH3)3][PF6]2: monoclinic},
	keywords = {COMPLEXES, HEXAFLUOROPHOSPHATE, MO, MOLYBDENUM, REDUCTION},
	isbn = {0276-7333},
	url = {<Go to ISI>://A1992HE29800062},
	author = {Chin, T. T. and Legzdins,Peter and Trotter, J. and Yee, V. C.}
}
@article {7196,
	title = {ORGANOMETALLIC NITROSYL CHEMISTRY .51. NEW ORGANOMETALLIC NITROSYL CATIONS CONTAINING THE GROUP-6 ELEMENTS},
	journal = {Organometallics},
	volume = {11},
	number = {2},
	year = {1992},
	note = {ISI Document Delivery No.: HE298Times Cited: 14Cited Reference Count: 39},
	month = {Feb},
	pages = {913-922},
	type = {Article},
	abstract = {{Treatment of the dihalo nitrosyl complexes of molybdenum and tungsten, Cp{\textquoteright}M(NO)X2 (Cp{\textquoteright} = Cp (eta(5)-C5H5), Cp* (eta(5)-C5Me5); M = Mo, W;X = Cl, Br, I), in CH3CN with NO+ or Ag+ salts affords a series of new diamagnetic cationic nitrosyl complexes, [Cp*Mo(NO)(NCCH3)3]2+ and [Cp{\textquoteright}M(NO)X(NCCH3)2]+. Eight such complexes have been isolated analytically pure as either their PF6- or BF4- salts by crystallization from CH3CN/Et2O. The physical and spectroscopic properties of these organometallic cations are consistent with their possessing four-legged piano stool molecular structures. This conclusion has been confirmed by single-crystal X-ray crystallographic analyses of [Cp*Mo(NO)(NCCH3)3][PF6]2 and [CpMo(NO)Cl-(NCCH3)2]BF4 which also establish that the acetonitrile ligands are coordinated linearly through their N atoms to the metal centers. Crystal data for [Cp*Mo(NO)(NCCH3)3][PF6]2: monoclinic},
	keywords = {COMPLEXES, HEXAFLUOROPHOSPHATE, MO, MOLYBDENUM, REDUCTION},
	isbn = {0276-7333},
	url = {<Go to ISI>://A1992HE29800062},
	author = {Chin, T. T. and Legzdins,Peter and Trotter, J. and Yee, V. C.}
}
