@article {3352,
	title = {CATALYSIS OF HYDROSILYLATION .28. THE ROLE OF DIOXYGEN IN HYDROSILYLATION OF ALKENES CATALYZED BY RUTHENIUM PHOSPHINE COMPLEXES},
	journal = {Journal of Organometallic Chemistry},
	volume = {499},
	number = {1-2},
	year = {1995},
	note = {ISI Document Delivery No.: RR624Times Cited: 3Cited Reference Count: 24},
	month = {Sep},
	pages = {173-179},
	type = {Article},
	abstract = {Catalytic hydrosilylation of C=C bonds in alkenes in the presence of Ru(II)-phosphine complexes takes place only for alkoxy-substituted silanes in the absence of solvent and in the presence of small amounts of O-2. The activation effect of {\textquoteright}{\textquoteright}trace{\textquoteright}{\textquoteright} O-2, noted previously for rhodium and other transition metal phosphine complex catalysts for several catalytic processes, has been little studied to date. In this work, oxygen is considered to cause removal of phosphine as its oxide, formation of intermediate dioxygen complexes (followed by oxygenation of Ru-Si= to an Ru-O-Si= moiety with elimination of disiloxane) and possible formation of Ru(IV) species. The studies include the characterization of isolated intermediates (well defined complexes or their mixtures) from an RuCl2(PPh(3))(3)-HSi(OC2H5)(3) system and general mechanisms for the hydrosilylation of alkenes in the presence of Ru(II) precursors are discussed.},
	keywords = {ALKENES, CATALYSIS, CHEMISTRY, DIOXYGEN, HYDROSILYLATION, rhodium, ruthenium, SILANE},
	isbn = {0022-328X},
	url = {<Go to ISI>://A1995RR62400025},
	author = {Gulinski, J. and James, Brian R. and Marciniec, B.}
}
@article {6784,
	title = {SYNTHESIS, CHARACTERIZATION, AND REACTIVITY OF TRANS-RU(X)(CL)(NBD)(DPPB) (X = H, CL - NBD = 2,5-NORBORNADIENE - DPPB = 1,4-BIS(DIPHENYLPHOSPHINO)BUTANE), INCLUDING THE X-RAY CRYSTAL-STRUCTURE OF THE DICHLORIDE},
	journal = {Israel Journal of Chemistry},
	volume = {30},
	number = {4},
	year = {1990},
	note = {ISI Document Delivery No.: FD556Times Cited: 5Cited Reference Count: 32},
	pages = {343-350},
	type = {Article},
	abstract = {{The ruthenium (II) diene complexes [Ru(X)(Cl)(nbd)(dppb)] (X = Cl, H; nbd = 2,5-norbornadiene; dppb = PPh2(CH2)4PPh2) have been prepared and characterized spectroscopically. The X-ray crystal structure of RuCl2(nbd)(dppb) (crystal data at 22-degrees-C: space group PlBAR},
	keywords = {ASYMMETRIC HYDROGENATION, CARBON-MONOXIDE, CATALYSIS, COMPLEXES, DIHYDROGEN, DIOXYGEN, rhodium},
	isbn = {0021-2148},
	url = {<Go to ISI>://A1990FD55600007},
	author = {Dekleva, T. W. and Joshi, A. M. and Thorburn, I. S. and James, Brian R. and Evans, S. V. and Trotter, J.}
}
@article {6784,
	title = {SYNTHESIS, CHARACTERIZATION, AND REACTIVITY OF TRANS-RU(X)(CL)(NBD)(DPPB) (X = H, CL - NBD = 2,5-NORBORNADIENE - DPPB = 1,4-BIS(DIPHENYLPHOSPHINO)BUTANE), INCLUDING THE X-RAY CRYSTAL-STRUCTURE OF THE DICHLORIDE},
	journal = {Israel Journal of Chemistry},
	volume = {30},
	number = {4},
	year = {1990},
	note = {ISI Document Delivery No.: FD556Times Cited: 5Cited Reference Count: 32},
	pages = {343-350},
	type = {Article},
	abstract = {{The ruthenium (II) diene complexes [Ru(X)(Cl)(nbd)(dppb)] (X = Cl, H; nbd = 2,5-norbornadiene; dppb = PPh2(CH2)4PPh2) have been prepared and characterized spectroscopically. The X-ray crystal structure of RuCl2(nbd)(dppb) (crystal data at 22-degrees-C: space group PlBAR},
	keywords = {ASYMMETRIC HYDROGENATION, CARBON-MONOXIDE, CATALYSIS, COMPLEXES, DIHYDROGEN, DIOXYGEN, rhodium},
	isbn = {0021-2148},
	url = {<Go to ISI>://A1990FD55600007},
	author = {Dekleva, T. W. and Joshi, A. M. and Thorburn, I. S. and James, Brian R. and Evans, S. V. and Trotter, J.}
}
