@article {2408,
	title = {Tantalum-Amidate Complexes for the Hydroaminoalkylation of Secondary Amines: Enhanced Substrate Scope and Enantioselective Chiral Amine Synthesis},
	journal = {Angewandte Chemie-International Edition},
	volume = {48},
	number = {44},
	year = {2009},
	note = {ISI Document Delivery No.: 513DPTimes Cited: 9Cited Reference Count: 25Eisenberger, Patrick Ayinla, Rashidat O. Lauzon, Jean Michel P. Schafer, Latcrel L.},
	pages = {8361-8365},
	type = {Article},
	keywords = {ALKENES, ALKYLATION, alpha, amidates, BOND, C-H ACTIVATION, CATALYSIS, CATALYTIC HYDROAMINOALKYLATION, enantioselectivity, homogeneous, HYDROAMINATION, HYDROAMINOALKYLATION, IMINE, LIGANDS, tantalum, UNACTIVATED OLEFINS},
	isbn = {1433-7851},
	url = {<Go to ISI>://000271302900038},
	author = {Eisenberger, P. and Ayinla, R. O. and Lauzon, J. M. P. and Schafer, L. L.}
}
@article {407,
	title = {Homo- and heterobimetallic precursor catalysts for the Heck reaction, and a proposal for a general catalytic cooperativity index},
	journal = {Advanced Synthesis \& Catalysis},
	volume = {344},
	number = {10},
	year = {2002},
	note = {ISI Document Delivery No.: 629XZTimes Cited: 22Cited Reference Count: 58},
	month = {Dec},
	pages = {1126-1134},
	type = {Article},
	abstract = {Homo- (Pd-2) and heterobimetallic (PtPd) complexes supported by a P,P-bridging, bis(P,N-chelating) coordination mode of the potentially hexadentate ligand 1,1-bis[di(o-N,N-dimethylanilinyl)phosphino] methane (dmapm) are effective catalyst precursors for the aerobic Heck coupling of iodobenzene and styrene at 100degreesC in DMF/H2O solution containing K2CO3. This medium allows for trivial separation of the trans-stilbene product which precipitates after the reaction mixture is cooled. The bimetallic precursors are more active than predicted from the sum of the activities of complexes chosen to mimic their mono-metallic "half units," suggesting some degree of intermetallic cooperativity during the reaction. A non-linear dependence of initial rate on catalyst concentration implies, however, that the complexes do not remain intact, and may be involved in dissociative equilibria with non-dmapm containing monometallic components that are more active species for the Heck coupling. The complexes are slowly degraded by oxidation at a phosphorus centre. A general index for quantifying the degree of intermetallic cooperativity during a catalytic cycle is proposed and its utility and limitations are discussed.},
	keywords = {aerobic), ASYMMETRIC CATALYSIS, bimetallic, CHEMISTRY, cooperativity, COORDINATION, COUPLING, Heck reaction (aqueous, HIGH REGIOSELECTIVITY, homogeneous, HYDROFORMYLATION, HYDROGEN, LIGANDS, NICKEL(II) SITE, palladium, PALLADIUM(II) COMPLEXES, phosphine (anilinyl), platinum, REACTIONS, thermomorphic, VINYLIC SUBSTITUTION-REACTIONS},
	isbn = {1615-4150},
	url = {<Go to ISI>://000180078900015},
	author = {Jones, N. D. and James, Brian R.}
}
@article {7235,
	title = {MONONUCLEAR AND DINUCLEAR RHODIUM CARBONYL SPECIES CONTAINING MONODENTATE OR BRIDGING 1,3-BIS(DIPHENYLPHOSPHINO)PROPANE},
	journal = {Gazzetta Chimica Italiana},
	volume = {122},
	number = {8},
	year = {1992},
	note = {ISI Document Delivery No.: JW695Times Cited: 2Cited Reference Count: 50},
	month = {Aug},
	pages = {329-334},
	type = {Article},
	abstract = {The interaction of [Rh(CO)(dpp)]2(mu-CO)2 with H-2 in CH2Cl2 in the presence of varying amounts of dpp leads mainly to catalytically important species which include Rh(H)(CO)(dpp)(dpp*) and [RhH(CO)(dpp)]2(mu-dpp), these being formed also by treating RhH(dpp)2 with about 2 equivalents of CO; dpp and dpp* = bidentate and monodentate 1,3-bis(diphenylphosphino)propane, respectively. Mechanistic pathways involving a detected RhH(CO)2(dpp) and non-detected <<RhH(CO)(dpp)>> species are suggested.},
	keywords = {ASYMMETRIC HYDROGENATION, CATALYSIS, CATALYTIC-HYDROGENATION, COMPLEXES, DIHYDROGEN, homogeneous, HYDROACYLATION, HYDROFORMYLATION, INSERTION, MONOXIDE, REACTIVITY},
	isbn = {0016-5603},
	url = {<Go to ISI>://A1992JW69500009},
	author = {Fung, D. C. M. and James, Brian R.}
}
