@article {2501,
	title = {Hydrolytic stability of nitrogenous-heteroaryltrifluoroborates under aqueous conditions at near neutral pH},
	journal = {Journal of Fluorine Chemistry},
	volume = {130},
	number = {4},
	year = {2009},
	note = {ISI Document Delivery No.: 434ZRTimes Cited: 4Cited Reference Count: 16Li, Ying Asadi, Ali Perrin, David M.},
	month = {Apr},
	pages = {377-382},
	type = {Article},
	abstract = {The hydrolytic stability of heteroaryltrifluoroborates under physiological conditions has been analyzed by F-19 NMR spectroscopy and is found to be greatly enhanced by the presence of endocyclic ring nitrogens. Stability is further enhanced by the presence of exocyclic electron withdrawing substituents. As with aryltrifluoroborates, NMR analysis suggests that the hydrolysis proceeds via single rate-determining step reflecting loss of the first fluoride atom. The stability of these complexes is significant both in terms of metal catalyzed cross-coupling reactions as well as the potential for generating boronic acid based F-18-PET imaging agents. (C) 2008 Elsevier B.V. All rights reserved.},
	keywords = {aryltrifluoroborate, CROSS-COUPLING REACTIONS, F-19 NMR, Heteroaryltrifluoroborates, Hydrolytic stability, PET, PET imaging, POTASSIUM ARYL, SALTS},
	isbn = {0022-1139},
	url = {<Go to ISI>://000265313400001},
	author = {Li, Y. and Asadi, A. and Perrin,David M.}
}
@article {2289,
	title = {Capturing aqueous [F-18]-fluoride with an arylboronic ester for PET: Synthesis and aqueous stability of a fluorescent [F-18]-labeled aryltrifluoroborate},
	journal = {Journal of Fluorine Chemistry},
	volume = {129},
	number = {5},
	year = {2008},
	note = {ISI Document Delivery No.: 302SWTimes Cited: 5Cited Reference Count: 12Ting, Richard Lo, Justin Adam, Michael J. Ruth, Thomas J. Perrin, David M.},
	month = {May},
	pages = {349-358},
	type = {Article},
	abstract = {The aqueous stability of aryltrifluoroborates is of importance to their use in transition metal mediated coupling reactions as well as their potential use in [F-18]-labeled aryltrifluoroborate PET imaging agents. Nevertheless, few studies have fully characterized the solvolysis of fluoride from an aryltrifluoroborate in water. Using [F-19] NMR, fluorescence and [F-18]-labeling techniques, we disclose the composition of an aryltrifluoroborate of exceptional kinetic stability with respect to solvolytic defluoridation. This work not only highlights the potential of using [F-18]-labeled aryltrifluoroborates for PET tracers, but provides a chemical platform and a general approach for evaluating the stability of other aryltrifluoroborates. (c) 2008 Elsevier B.V. All rights reserved.},
	keywords = {ACIDS, aryltrifluoroborate, CROSS-COUPLING REACTIONS, KINETICS, PET, SYNTHESIS, [F-18]-labeling},
	isbn = {0022-1139},
	url = {<Go to ISI>://000255990600005},
	author = {Ting, R. and Lo, J. and Adam,Michael J. and Ruth, T. J. and Perrin,David M.}
}
@article {2289,
	title = {Capturing aqueous [F-18]-fluoride with an arylboronic ester for PET: Synthesis and aqueous stability of a fluorescent [F-18]-labeled aryltrifluoroborate},
	journal = {Journal of Fluorine Chemistry},
	volume = {129},
	number = {5},
	year = {2008},
	note = {ISI Document Delivery No.: 302SWTimes Cited: 5Cited Reference Count: 12Ting, Richard Lo, Justin Adam, Michael J. Ruth, Thomas J. Perrin, David M.},
	month = {May},
	pages = {349-358},
	type = {Article},
	abstract = {The aqueous stability of aryltrifluoroborates is of importance to their use in transition metal mediated coupling reactions as well as their potential use in [F-18]-labeled aryltrifluoroborate PET imaging agents. Nevertheless, few studies have fully characterized the solvolysis of fluoride from an aryltrifluoroborate in water. Using [F-19] NMR, fluorescence and [F-18]-labeling techniques, we disclose the composition of an aryltrifluoroborate of exceptional kinetic stability with respect to solvolytic defluoridation. This work not only highlights the potential of using [F-18]-labeled aryltrifluoroborates for PET tracers, but provides a chemical platform and a general approach for evaluating the stability of other aryltrifluoroborates. (c) 2008 Elsevier B.V. All rights reserved.},
	keywords = {ACIDS, aryltrifluoroborate, CROSS-COUPLING REACTIONS, KINETICS, PET, SYNTHESIS, [F-18]-labeling},
	isbn = {0022-1139},
	url = {<Go to ISI>://000255990600005},
	author = {Ting, R. and Lo, J. and Adam,Michael J. and Ruth, T. J. and Perrin,David M.}
}
@article {1289,
	title = {Arylfluoroborates and alkylfluorosilicates as potential PET imaging agents: High-yielding aqueous biomolecular F-18-labeling},
	journal = {Journal of the American Chemical Society},
	volume = {127},
	number = {38},
	year = {2005},
	note = {ISI Document Delivery No.: 968OCTimes Cited: 29Cited Reference Count: 32},
	month = {Sep},
	pages = {13094-13095},
	type = {Article},
	keywords = {AVIDIN, biotin, BORONIC ACIDS, CROSS-COUPLING REACTIONS, F-18, FRAGMENT, MICROPET, MONOCLONAL-ANTIBODY, PROTEIN, STATE},
	isbn = {0002-7863},
	url = {<Go to ISI>://000232170800007},
	author = {Ting, R. and Adam,Michael J. and Ruth, T. J. and Perrin,David M.}
}
@article {1289,
	title = {Arylfluoroborates and alkylfluorosilicates as potential PET imaging agents: High-yielding aqueous biomolecular F-18-labeling},
	journal = {Journal of the American Chemical Society},
	volume = {127},
	number = {38},
	year = {2005},
	note = {ISI Document Delivery No.: 968OCTimes Cited: 29Cited Reference Count: 32},
	month = {Sep},
	pages = {13094-13095},
	type = {Article},
	keywords = {AVIDIN, biotin, BORONIC ACIDS, CROSS-COUPLING REACTIONS, F-18, FRAGMENT, MICROPET, MONOCLONAL-ANTIBODY, PROTEIN, STATE},
	isbn = {0002-7863},
	url = {<Go to ISI>://000232170800007},
	author = {Ting, R. and Adam,Michael J. and Ruth, T. J. and Perrin,David M.}
}
@article {1142,
	title = {Palladium(II) complexes of bis(phosphine)monooxide and bis(phosphine)monosulphide ligands bearing o-N,N-dimethylanilinyl substituents},
	journal = {Canadian Journal of Chemistry-Revue Canadienne De Chimie},
	volume = {83},
	number = {6-7},
	year = {2005},
	note = {ISI Document Delivery No.: 963UVTimes Cited: 3Cited Reference Count: 49},
	month = {Jun},
	pages = {546-552},
	type = {Article},
	abstract = {{Palladium( II) complexes of bis( phosphine) monooxide and bis( phosphine) monosulphide ligands with the general formula Ar2P( CH2) P-n( E) Ar-2 are described ( n = 1 ( dmapmE)},
	keywords = {ARYL HALIDES, BIPHOSPHINE MONOXIDE LIGANDS, BISPHOSPHINE LIGANDS, CATALYSIS, CHEMISTRY, CHIRAL DIPHOSPHINE, COORDINATION, CROSS-COUPLING REACTIONS, DONOR, OXIDATION, palladium, phosphine, phosphine oxide, phosphine sulphide, PHOSPHINE-LIGANDS},
	isbn = {0008-4042},
	url = {<Go to ISI>://000231832500007},
	author = {Jones, N. D. and James, Brian R.}
}
