@article {7230,
	title = {THE 1992 ALCAN AWARD LECTURE EXCURSIONS AROUND THE PERIODIC-TABLE - LIGAND DESIGN IN INORGANIC-CHEMISTRY},
	journal = {Canadian Journal of Chemistry-Revue Canadienne De Chimie},
	volume = {70},
	number = {12},
	year = {1992},
	note = {ISI Document Delivery No.: KL565Times Cited: 56Cited Reference Count: 38},
	month = {Dec},
	pages = {2839-2845},
	type = {Article},
	abstract = {An overview is given on the strategy used to come up with the design of a new type of ligand that is appropriate for coordination to both the late metals and the early metals. The coordination chemistry of the potentially tridentate ligand -N(SiMe2CH2PR2)2 is developed starting with the Ni triad and then the heavier members of group 9, namely rhodium and iridium. It is with iridium that reactive fragments such as methylene and vinylidene have been stabilized and their chemistry examined. Extension to groups 3, 4, and the lanthanides is also discussed. With these elements, phosphine coordination imparts new reactivity patterns such as alkane elimination with group 3 and dinitrogen activation with group 4. In addition, the side-on binding mode for N2 attached to a dinuclear zirconium system is also presented.},
	keywords = {asymmetric synthesis, CARBON BOND FORMATION, DERIVATIVES, DINITROGEN, FLUXIONAL BEHAVIOR, HAFNIUM(IV), hydride, MULTI-DENTATE LIGANDS, PHOSPHINE COMPLEXES, RAY CRYSTAL-STRUCTURE},
	isbn = {0008-4042},
	url = {<Go to ISI>://A1992KL56500001},
	author = {Fryzuk,Michael D.}
}
@article {7013,
	title = {PHOSPHINE COMPLEXES OF THE EARLY METALS AND THE IANTHANOIDS},
	journal = {Pure and Applied Chemistry},
	volume = {63},
	number = {6},
	year = {1991},
	note = {ISI Document Delivery No.: FN255Times Cited: 21Cited Reference Count: 2314TH INTERNATIONAL CONF ON ORGANOMETALLIC CHEMISTRYAUG 19-24, 1990DETROIT, MIINT UNION PURE \& APPL CHEM, DIV INORGAN CHEM, WAYNE STATE UNIV},
	month = {Jun},
	pages = {845-850},
	type = {Proceedings Paper},
	abstract = {The coordination chemistry of the mixed-donor tridentate ligand -N(SiMe2CH2PR2)2 with the early transition metals of groups 3 and 4 and the lanthanide elements will be presented. This ancillary ligand has allowed for the formation of phosphine complexes of these hard elements which has in turn induced new reactivity patterns for hydrocarbyl ligands.},
	keywords = {DERIVATIVES, F-BLOCK METALS, FLUXIONAL BEHAVIOR, GROUP-4, HAFNIUM(IV), LIGANDS, RAY CRYSTAL-STRUCTURE, ZIRCONIUM(IV)},
	isbn = {0033-4545},
	url = {<Go to ISI>://A1991FN25500008},
	author = {Fryzuk,Michael D. and Haddad, T. S. and Berg, D. J. and Rettig, S. J.}
}
@article {7014,
	title = {PHOSPHINE COMPLEXES OF YTTRIUM, LANTHANUM, AND LUTETIUM - SYNTHESIS, THERMOLYSIS, AND FLUXIONAL BEHAVIOR OF THE HYDROCARBYL DERIVATIVES MR{\textquoteright}[N(SIME2CH2PME2)2]2 - X-RAY CRYSTAL-STRUCTURE OF Y[N(SIME2CHPME2)(SIME2CH2PME2)][N(SIME2CH2PME2)2]},
	journal = {Organometallics},
	volume = {10},
	number = {6},
	year = {1991},
	note = {ISI Document Delivery No.: FQ933Times Cited: 61Cited Reference Count: 41},
	month = {Jun},
	pages = {2026-2036},
	type = {Article},
	abstract = {{The preparation of phosphine complexes of the group 3 elements yttrium and lanthanum and the lanthanide metal lutetium is described. The reaction of 2 equiv of lithium salt of the mixed-donor ligand LiN(SiMe2CH2PR2)2 (R = Me, Ph, Pr(i)) with YCl3 or LuCl3 (R = Me only) leads to the formation of the bis(ligand) complexes MCl[N(SiMe2CH2PR2)2]2. The analogous lanthanum derivative requires the use of the corresponding potassium salt KN(SiMe2CH2PR2)2 (R = Me, Ph) with anhydrous LaCl3 to generate good yields of LaCl(N(SiMe2CH2PR2)2]2. Replacement of the remaining chloride with a hydrocarbyl ligand can be achieved for M = Y and Lu to generate MR[N(SiMe2CH2PMe2)2]2 (M = Y},
	keywords = {ALKYL, BOND ACTIVATION, CHEMISTRY, CRYSTALLOGRAPHIC CHARACTERIZATION, ELIMINATION, F-BLOCK METALS, HAFNIUM(IV), hydride, LIGAND, ORGANOLANTHANIDES},
	isbn = {0276-7333},
	url = {<Go to ISI>://A1991FQ93300059},
	author = {Fryzuk,Michael D. and Haddad, T. S. and Rettig, S. J.}
}
