@article {615,
	title = {Activation and functionalization of molecular nitrogen by metal complexes},
	journal = {Chemical Record},
	volume = {3},
	number = {1},
	year = {2003},
	note = {ISI Document Delivery No.: 669WPTimes Cited: 48Cited Reference Count: 52},
	pages = {2-11},
	type = {Article},
	abstract = {Molecular nitrogen is intrinsically unreactive, so much so that it has confounded chemists for decades in attempts to functionalize this abundant diatomic molecule. While biological systems and industrial processes can fix nitrogen to form ammonia, the challenge is to discover a process that involves a homogeneous catalyst that can utilize N-2 as a feedstock to generate higher value organonitrogen materials. In this review, the activation of molecular nitrogen by transition metal complexes is reviewed with the view to present new kinds of transformations for coordinated dinitrogen. Moreover, some reaction types that are as yet unknown are outlined to try and stimulate further research in this area. (C) 2003 The Japan Chemical Journal Forum and Wiley Periodicals, Inc.},
	keywords = {BRIDGING N-2 UNIT, CHEMISTRY, COORDINATED, COORDINATION CHEMISTRY, CRYSTAL-STRUCTURE, DINITROGEN, DINITROGEN COMPLEXES, END-ON, FIXATION, nitrogen fixation, nitrogenase, REDUCTION, SIDE-ON, transition metal complexes, ZIRCONIUM},
	isbn = {1527-8999},
	url = {<Go to ISI>://000182373700001},
	author = {Fryzuk,Michael D.}
}
@article {4809,
	title = {The continuing story of dinitrogen activation},
	journal = {Coordination Chemistry Reviews},
	volume = {200},
	year = {2000},
	note = {ISI Document Delivery No.: 345HCTimes Cited: 235Cited Reference Count: 121},
	month = {May},
	pages = {379-409},
	type = {Review},
	abstract = {This review attempts to survey the recent literature concerning the coordination chemistry and the reactivity patterns of metal-dinitrogen complexes. In order that this work may stand alone, a certain amount of background information is included; however, the emphasis is on synthesis and reactivity patterns of recently discovered dinitrogen complexes. In addition, some effort is made to discuss new trends in dinitrogen chemistry as well as to point out underdeveloped topics in this area. (C) 2000 Elsevier Science S.A. All rights reserved.},
	keywords = {(1-PYRIDINIO)IMIDO, 3-COORDINATE MOLYBDENUM(III) COMPLEXES, BRIDGING N-2 UNIT, COMPLEXES, COORDINATED DINITROGEN, DINITROGEN, metal complexes, MOLECULAR, N BOND-CLEAVAGE, NITROGEN, nitrogen fixation, nitrogenase, RAY CRYSTAL-STRUCTURES, SIDE-ON, TO-END ROTATION, TRIAMIDOAMINE COMPLEXES},
	isbn = {0010-8545},
	url = {<Go to ISI>://000088809700013},
	author = {Fryzuk,Michael D. and Johnson, S. A.}
}
@article {4297,
	title = {Intramolecular protonation and other mechanisms for substitution reactions of hydrido(thiolato)- and di(thiolato)-ruthenium(II) phosphine complexes},
	journal = {Inorganica Chimica Acta},
	volume = {280},
	number = {1-2},
	year = {1998},
	note = {ISI Document Delivery No.: 124VGTimes Cited: 3Cited Reference Count: 28},
	month = {Oct},
	pages = {75-86},
	type = {Article},
	abstract = {Reactions of cct-RuH(SR) (CO)(2)(PPh3)(2) (1) (cct = cis, cis, traits) with R{\textquoteright}SH provide cct-RuH(SR{\textquoteright}) (CO)(2)(PPh3)(2) (R = alkyl, aryl); based on described kinetic data, the proposed mechanism involves PPh3 loss, coordination of R{\textquoteright}SH, intramolecular protonation of RS- by R{\textquoteright}SH, and RSH elimination. The intramolecular protonation step circumvents a potentially slow RSH reductive elimination step. A similar mechanism is proposed for the thiol exchange reactions of cct-Ru(SR)(2)(CO)(2)(PPh3)(2) (2). A corresponding dissociative mechanism is also proposed for the reaction of 1 with P(p-tolyl)(3), which gives cct-RuH(SR) (CO)(2)(PPh3) (P(p-tolyl)(3)) and cct-RuH(SR) (CO)(2)(P(p-tolyl)(3))(2). Other reactions described include the reactions of 1 with H-2, CO, HCl and PPh3, and the reactions of 2 with P(p-tolyl)(3) and H-2. Exposure to light causes 2 to dimerize in solution. (C) 1998 Elsevier Science S.A. All rights reserved.},
	keywords = {ACTIVE-SITES, EXCHANGE, hydride complexes, IRON-SULFUR PROTEINS, kinetics and mechanism, LIGANDS, MOLECULAR-HYDROGEN, nitrogenase, ruthenium complexes, SYNTHETIC ANALOGS, TETRANUCLEAR CLUSTERS <FE4S4(SR)4>2, thiolate complexes, THIOLATO, TRANSITION-METAL COMPLEXES},
	isbn = {0020-1693},
	url = {<Go to ISI>://000076202900012},
	author = {Jessop, P. G. and James, Brian R.}
}
@article {3627,
	title = {Synthesis, structure and magnetic properties of an asymmetric dinuclear oxocitratovanadate(IV) complex},
	journal = {Inorganica Chimica Acta},
	volume = {251},
	number = {1-2},
	year = {1996},
	note = {ISI Document Delivery No.: VX967Times Cited: 32Cited Reference Count: 19},
	month = {Oct},
	pages = {75-79},
	type = {Article},
	abstract = {{Evaporation of an aqueous solution containing VO2+, citric acid and neocuproine (2},
	keywords = {asymmetric, citrate complexes, COMPLEXES, crystal structures, CRYSTAL-STRUCTURE, DIMER, DINUCLEAR COMPLEXES, nitrogenase, VANADYL COMPLEXES},
	isbn = {0020-1693},
	url = {<Go to ISI>://A1996VX96700011},
	author = {Burojevic, S. and Shweky, I. and Bino, A. and Summers, D. A. and Thompson, R. C.}
}
