@article {2629,
	title = {Rhodium(I)-(N-heterocyclic carbene)-diphosphine complexes},
	journal = {Canadian Journal of Chemistry-Revue Canadienne De Chimie},
	volume = {87},
	number = {9},
	year = {2009},
	note = {ISI Document Delivery No.: 493QBTimes Cited: 0Cited Reference Count: 45Sun, Hongsui Yu, Xiao-Yan Marcazzan, Paolo Patrick, Brian O. James, Brian R.},
	month = {Sep},
	pages = {1248-1254},
	type = {Article},
	abstract = {{Les reactions du [RhCl(COE)(IPr)](2) (1) et du [RhCl(COE)(IMes)](2) (2) [COE = cyclooctene; IPr = N,N{\textquoteright}-bis(2,6-diisopropylphenyl)imidazoline-2-ylidene; IMes = N,N{\textquoteright}-bis(2,4,6-trimethylphenyl)imidazoline-2-ylidene] avec les diphosphines Ph2P(CH2)(n)PPh2 et 1,2-bis(diphenylphosphino)benzene (dppbz) conduisent a la formation de complexes carbene N-heterocyclique (NHC) - diphosphine - rhodium(I): RhCl(NHC)[Ph2P(CH2)(n)PPh2] [NHC = IPr},
	keywords = {C-H ACTIVATION, CATALYTIC-ACTIVITY, HETEROCYCLIC CARBENE COMPLEXES, HYDROFORMYLATION, HYDROGENATION REACTIONS, HYDROSILYLATION, iridium complexes, LIGANDS, phosphine, RHODIUM(I) COMPLEXES},
	isbn = {0008-4042},
	url = {<Go to ISI>://000269751100008},
	author = {Sun, H. S. and Yu, X. Y. and Marcazzan, P. and Patrick, B. O. and James, Brian R.}
}
@article {1481,
	title = {Catalyst poisoning in catalyzed imine hydrogenation: A novel zwitterionic Rh(I)/o-hydroxy-substituted imine complex},
	journal = {Journal of Molecular Catalysis a-Chemical},
	volume = {257},
	number = {1-2},
	year = {2006},
	note = {ISI Document Delivery No.: 089DITimes Cited: 3Cited Reference Count: 38Marcazzan, Paolo Patrick, Brian O. James, Brian R.},
	month = {Sep},
	pages = {26-30},
	type = {Article},
	abstract = {During investigation of the homogeneous H-2-hydrogenation of the ketimine (o-HOC6H4)C(Me)=NCH2Ph catalyzed by the [Rh(COD)(PPh3)(2)]PF6 precursor in MeOH at ambient conditions, we have isolated [Rh{eta(4)-(C6H4O)C(-)(Me)=N(+)(H)CHPh}(PPh3)(2)]PF6 (3), an unusual zwitterionic Rh complex in which the imine is coordinated via the C-4 part of the o-hydroxy-arene moiety in a quinoid form; this tautomer is generated via proton transfer from the O-atom to the N-atom within the molecular, benzenoid form. Precipitation of 3 from the MeOH solution, even under H-2, causes sequestration of the Rh and complete suppression of the catalytic activity. (In a previously studied system with the corresponding, non-hydroxy-substituted ketimine, PhC(Me) = NCH2Ph, the Rh was sequestered as an inactive o-metalated species). The solid state structure of 3 is retained in CH2Cl2 solution, but in MeOH and Me2CO reversible loss of the ketimine generates the cis-[Rh(PPh3)(2)(solvent)(2)]PF6 species. (c) 2006 Elsevier B.V. All rights reserved.},
	keywords = {amine, BEHAVIOR, CATALYSIS, CATIONIC RHODIUM COMPLEXES, CHEMICALS, FINE, HYDROGENATION, HYDROLYSIS, imine complex, LIGAND, LIGANDS, OLEFINS, phosphine, RHODIUM COMPLEX, SCHIFF-BASES, SELECTIVE HYDROGENATION, zwitterion},
	isbn = {1381-1169},
	url = {<Go to ISI>://000240860100005},
	author = {Marcazzan, P. and Patrick, B. O. and James, Brian R.}
}
@article {1240,
	title = {Coordination chemistry of P,O-bidentate phosphinophenolates with Ga3+ and In3+},
	journal = {Dalton Transactions},
	number = {13},
	year = {2005},
	note = {ISI Document Delivery No.: 936NJTimes Cited: 4Cited Reference Count: 63},
	pages = {2268-2274},
	type = {Article},
	abstract = {Novel complexes of Ga3+ and In3+ were synthesized with two hetero donor phosphinophenolate ligands (PO-, ortho-phenoxydiphenylphosphine; MePO-, 5-methyl-2-phenoxydiphenylphosphine). RPO- (R = H, Me) binds in a bidentate fashion through both the hard O and the soft P donor atoms to In3+, whereas, it only binds Ga3+ through the O donor. Electrochemical synthesis proved to be a practical synthetic approach to In-2(PO)(3)Cl-3, In(PO)(3) and In(MePO)(3). [In(MePO)(H2O)Cl-2](2) and Ga(HPO)Cl-3 were synthesized from MCl3 (M = In and Ga, respectively). Both dimetallic indium complexes, [In(MePO)(H2O)Cl-2](2) and In-2(PO)(3)Cl-3, incorporate phenolate oxygen atoms bridging the two metal ions. Each pair of In atoms are in a distorted octahedral geometry in each complex, with the former complex having a coordination sphere of PO3Cl2 for both indium metal ions and the latter showing a coordination sphere of PO3Cl2 for one indium and P2O3Cl for the other. Ga(HPO)Cl-3 is a zwitterionic complex, with Ga having a OCl3 coordination core. All these complexes were fully characterized by a variety of techniques including X-ray crystallography.},
	keywords = {aluminum, CRYSTAL, DERIVATIVES, gallium, INDIUM TRICHLORIDE, LIGANDS, METAL CHELATE COMPLEXES, MOLECULAR-STRUCTURE, phosphine, THALLIUM},
	isbn = {1477-9226},
	url = {<Go to ISI>://000229862400008},
	author = {Saatchi, K. and Patrick, B. O. and Orvig, Chris}
}
@article {1142,
	title = {Palladium(II) complexes of bis(phosphine)monooxide and bis(phosphine)monosulphide ligands bearing o-N,N-dimethylanilinyl substituents},
	journal = {Canadian Journal of Chemistry-Revue Canadienne De Chimie},
	volume = {83},
	number = {6-7},
	year = {2005},
	note = {ISI Document Delivery No.: 963UVTimes Cited: 3Cited Reference Count: 49},
	month = {Jun},
	pages = {546-552},
	type = {Article},
	abstract = {{Palladium( II) complexes of bis( phosphine) monooxide and bis( phosphine) monosulphide ligands with the general formula Ar2P( CH2) P-n( E) Ar-2 are described ( n = 1 ( dmapmE)},
	keywords = {ARYL HALIDES, BIPHOSPHINE MONOXIDE LIGANDS, BISPHOSPHINE LIGANDS, CATALYSIS, CHEMISTRY, CHIRAL DIPHOSPHINE, COORDINATION, CROSS-COUPLING REACTIONS, DONOR, OXIDATION, palladium, phosphine, phosphine oxide, phosphine sulphide, PHOSPHINE-LIGANDS},
	isbn = {0008-4042},
	url = {<Go to ISI>://000231832500007},
	author = {Jones, N. D. and James, Brian R.}
}
@article {677,
	title = {The analysis of volatile trace compounds in landfill gases, compost heaps and forest air},
	journal = {Applied Organometallic Chemistry},
	volume = {17},
	number = {3},
	year = {2003},
	note = {ISI Document Delivery No.: 651ZYTimes Cited: 7Cited Reference Count: 28},
	month = {Mar},
	pages = {154-160},
	type = {Article},
	abstract = {Landfill gas, cryotrapped on a loop fashioned from a length of a capillary gas chromatography (GC) column, was examined for volatile organometallic compounds (VOMCs) and for volatile organic compounds (VOCs) by using GC-mass spectrometry (MS). A large number of organic components were present and many were identified, but the only VOMCs present in high enough concentrations to be detected were trimethylstibine and tetramethyltin. The use of inductively coupled plasma (ICP)-MS as an element-specific detector allowed the identification of a number of other organometallic species in the landfill gas, including trimethylarsine and trimethylbismuth, and, for the first time, butyltrimethyltin and dibutyldimethyltin. The presence of molybdenum hexacarbonyl was confirmed. Gas from a large-scale compost heap and from compost incubated in the laboratory contained iodomethane but no common VOMCs (GC-ICP-MS). Only VOCs were present in forest air (GC-MS). Copyright (C) 2003 John Wiley Sons, Ltd.},
	keywords = {(VOCs), BISMUTH, CHROMATOGRAPHY, EMISSIONS, ENVIRONMENT, GC-ICP-MS, GC-MS, METAL-COMPOUNDS, ORGANIC-COMPOUNDS, organotin speciation, phosphine, SITE, volatile organic compounds, volatile organometallic compounds (VONICs), WASTE},
	isbn = {0268-2605},
	url = {<Go to ISI>://000181355200002},
	author = {Maillefer, S. and Lehr, C. R. and Cullen, W. R.}
}
@article {408,
	title = {Bisphosphine ligands containing two o-N,N-dimethylanilinyl substituents at each phosphorus atom},
	journal = {Canadian Journal of Chemistry-Revue Canadienne De Chimie},
	volume = {80},
	number = {11},
	year = {2002},
	note = {ISI Document Delivery No.: 623LDTimes Cited: 11Cited Reference Count: 35},
	month = {Nov},
	pages = {1600-1606},
	type = {Article},
	abstract = {The synthesis and complete characterization of the family of tetra(amine)bisphosphine ligands (o-NMe2C6H4)(2)P-(X)-P(o-NMe2C6H4)(2), where X = CH2 (dmapm), (CH2)(2) (dmape), and CH(CH2)(3)CH (dmapcp), are described. Crystal structure data are compared with known, analogous bisphosphines containing o-pyridyl or phenyl substituents in place of the o-dimethylanilinyl groups. Several short, intramolecular C-H...N distances in the anilinyl derivatives may represent the presence of weak hydrogen bonds.},
	keywords = {ACID, amine, AMPHIPHILIC DIPHOSPHINES, CATALYTIC-HYDROGENATION, CHEMISTRY, DERIVATIVES, HYDROFORMYLATION, hydrogen-bonding to N atoms, phosphine, polydentate, RESOLUTION, RHODIUM COMPLEXES, RUTHENIUM(II), WATER-SOLUBLE PHOSPHINES},
	isbn = {0008-4042},
	url = {<Go to ISI>://000179703800030},
	author = {Jones, N. D. and Meessen, P. and Smith, M. B. and Losehand, U. and Rettig, S. J. and Patrick, B. O. and James, Brian R.}
}
@article {3806,
	title = {Synthesis, characterization, and reactivity of a ruthenium(II) N,N{\textquoteright},N{\textquoteright}{\textquoteright}-tris(2-pyridyl)phosphine complex. X-ray analysis of RuCl2(PPh(3))(Ppy(3)) (py equals 2-pyridyl)},
	journal = {Canadian Journal of Chemistry-Revue Canadienne De Chimie},
	volume = {74},
	number = {11},
	year = {1996},
	note = {ISI Document Delivery No.: WC124Times Cited: 10Cited Reference Count: 32},
	month = {Nov},
	pages = {2064-2072},
	type = {Article},
	abstract = {{Reaction of RuCl2(PPh(3))(3) with Ppy(3) (py = 2-pyridyl) in benzene produced the N,N{\textquoteright},N {\textquoteright}{\textquoteright}-Ppy(3) complex RuCl2(PPh(3))(Ppy(3)) 1. Crystals of RuCl2(PPh(3))(Ppy(3)). 2CH(2)Cl(2)(C35H31Cl6N3P2Ru) are monoclinic},
	keywords = {COORDINATION, crystal structure, CRYSTAL-STRUCTURE, LIGANDS, MOLECULAR-STRUCTURES, phosphine, pyridylphosphines, ruthenium},
	isbn = {0008-4042},
	url = {<Go to ISI>://A1996WC12400022},
	author = {Schutte, R. P. and Rettig, S. J. and James, Brian R.}
}
@article {3392,
	title = {KINETICS AND MECHANISM OF H-2-HYDROGENATION OF STYRENE CATALYZED BY [RUCL(DPPB)(MU-CL)](2) (DPPB=1,4-BIS(DIPHENYLPHOSPHINO)BUTANE) - EVIDENCE FOR HYDROGEN-TRANSFER FROM A DINUCLEAR MOLECULAR-HYDROGEN SPECIES},
	journal = {Journal of Organometallic Chemistry},
	volume = {488},
	number = {1-2},
	year = {1995},
	note = {ISI Document Delivery No.: QG254Times Cited: 32Cited Reference Count: 31},
	month = {Feb},
	pages = {161-167},
	type = {Article},
	abstract = {Kinetic studies on the H-2-hydrogenation of styrene catalyzed by [RuCl(dppb)(mu-Cl)](2) (dppb = Ph(2)P(CH2)(4)PPh(2)) in N,N-dimethylacetamide solution, near ambient conditions have revealed a first-order dependence on Ru, and dependences on H-2 and on styrene that are first-order at lower concentrations and decrease with increasing concentration. Considered along with NMR and tensiometric data, the findings are interpreted in terms of a basic hydride route in which an initially formed, dinuclear, molecular hydrogen complex (eta(2)-H-2)Ru(dppb)(mu-Cl)(3)RuCl(dppb) transfers both hydrogens to the styrene.},
	keywords = {ASYMMETRIC HYDROGENATION, BINAP, CATALYSIS, COMPLEXES, DIHYDROGEN, dihydrogen complexes, HYDROGENATION, KINETICS, LIGANDS, phosphine, ruthenium, RUTHENIUM(II) COMPLEXES, SELECTIVE, STYRENE, UNSATURATED CARBOXYLIC-ACIDS},
	isbn = {0022-328X},
	url = {<Go to ISI>://A1995QG25400022},
	author = {Joshi, A. M. and Macfarlane, K. S. and James, Brian R.}
}
@article {3235,
	title = {NICKEL(II) AND NICKEL(0) COMPLEXES CONTAINING 2-PYRIDYLPHOSPHINE LIGANDS, INCLUDING WATER-SOLUBLE SPECIES},
	journal = {Inorganica Chimica Acta},
	volume = {235},
	number = {1-2},
	year = {1995},
	note = {ISI Document Delivery No.: RP069Times Cited: 27Cited Reference Count: 33},
	month = {Jul},
	pages = {291-297},
	type = {Article},
	abstract = {{The paramagnetic},
	keywords = {2-PYRIDYLPHOSPHINE COMPLEXES, ANTITUMOR-ACTIVITY, MONONUCLEAR, NICKEL(0) COMPLEXES, NICKEL(II) COMPLEXES, palladium, phosphine, RHODIUM(I)},
	isbn = {0020-1693},
	url = {<Go to ISI>://A1995RP06900034},
	author = {Baird, I. R. and Smith, M. B. and James, Brian R.}
}
@article {3099,
	title = {SYNTHESIS, CHARACTERIZATION, AND REDOX PROPERTIES OF THE 17-VALENCE-ELECTRON COMPLEXES CP{\textquoteright}CR(NO)(L)X},
	journal = {Organometallics},
	volume = {13},
	number = {2},
	year = {1994},
	note = {ISI Document Delivery No.: MX338Times Cited: 8Cited Reference Count: 35},
	month = {Feb},
	pages = {562-568},
	type = {Article},
	abstract = {Treatment of CH2Cl2 solutions of [Cp{\textquoteright}Cr(NO)I]2 [CP{\textquoteright}= Cp (eta5-C5H5) or Cp* (eta5-C5Me5)] with various P- and N-containing Lewis bases, L, affords good yields of Cp{\textquoteright}Cr(NO)(L)I complexes [L = PPh3, P(OMe)3, P(OPh)3, py, or C5H11N (pip)]. Photolysis of toluene solutions of CpCr(NO)(CO)2 in the presence of PPh3 and a source of halogen such as CH2Cl2 results in a 63\% isolated yield of CpCr(NO)(PPh3)Cl. In donor solvents, S, the ESR-active CpCr(NO)(L)X (X = Cl, I) compounds undergo either L or X substitution to form the 17-valence-electron CpCr-(NO)(S)X and [CpCr(NO)(L)(S)+ species, respectively. A kinetic analysis of the reaction of CpCr(NO)(THF)I with PPh3 shows the process to be second-order overall (first-order in each reactant) and associative in nature. The reduction potentials for the various CpCr(NO)(L)X complexes in THF vary from -1.05 to -1.65 V. These reductions are irreversible and are followed by loss of X-. Consistently, reduction of CpCr(NO)(PPh3)I in THF by Zn in the presence of P(OPh)3 affords the 18-valence-electron mixed phosphine-phosphite complex, CpCr(NO)(PPh3)[P(OPh)3]. The redox chemistry of the CpCr(NO)(L)X complexes is thus unusual in that the odd-electron species are substitutionally less labile than are, their 18-electron reduction products.},
	keywords = {19-ELECTRON, carbonyl ligands, COMPLEXES, COMPOUNDS, ME, METAL-CENTERED RADICALS, ORGANOMETALLIC NITROSYL CHEMISTRY, phosphine, {17-ELECTRON},
	isbn = {0276-7333},
	url = {<Go to ISI>://A1994MX33800030},
	author = {Legzdins,Peter and McNeil, W. S. and Shaw, M. J.}
}
