@article {2684, title = {Development of an Oxazole Conjunctive Reagent and Application to the Total Synthesis of Siphonazoles}, journal = {Journal of Organic Chemistry}, volume = {74}, number = {23}, year = {2009}, note = {ISI Document Delivery No.: 523ONTimes Cited: 6Cited Reference Count: 120Zhang, Jianmin Polishchuk, Elena A. Chen, Jie Ciufolini, Marco A.}, month = {Dec}, pages = {9140-9151}, type = {Review}, abstract = {The preparation of 4-carbethoxy-5-methyl-2-(phenylsulfonyl)methyloxizole and Its use in the elaboration of more complex oxazoles are described. A total synthesis of the unique natural products siphonazoles A and B, illustrates an application of this building block. A discussion of the biological activity of the siphonazoles is also presented.}, keywords = {1ST TOTAL-SYNTHESIS, ALLENYL ESTERS, CONJUGATED, CYANOBACTERIUM NOSTOC-MUSCORUM, CYTOTOXIC, DIAZONAMIDE-A, DOUBLE ELIMINATION PROTOCOL, GLYOXYLIC-ACID DERIVATIVES, INTRAMOLECULAR HYDROAMINATION, marine sponge, METABOLITES, NATURAL-PRODUCT HENNOXAZOLE}, isbn = {0022-3263}, url = {://000272083700026}, author = {Zhang, J. M. and Polishchuk, E. A. and Chen, J. and Ciufolini,Marco A.} }