@article {5109,
	title = {Mixing schemes for aqueous dimethyl sulfoxide: Support by X-ray diffraction data},
	journal = {Journal of Solution Chemistry},
	volume = {30},
	number = {10},
	year = {2001},
	note = {ISI Document Delivery No.: 505UTTimes Cited: 19Cited Reference Count: 18},
	month = {Oct},
	pages = {885-893},
	type = {Article},
	abstract = {Aqueous dimethyl sulfoxide (DMSO) was studied by X-ray diffraction at room temperature. The results indicated that there are three distinct composition regions. In the DMSO-rich region, DMSO molecules retain the same molecular arrangement as in the pure, state, while H2O does not show any structural feature. These findings are in the complete agreement with the suggestion by our earlier thermodynamic study on aqueous DMSO.((1)) In the H2O-rich region, there is an indication that DMSO molecules exist as small clusters bound mainly by S=O dipole attraction. Hence, hydrophobic CH3 groups point outward from such a cluster and DMSO acts in effect as a hydrophobic solute. This is also consistent with the findings of our earlier thermodynamic study. In the intermediate region, a gradual change in the radial distribution function with composition was observed.},
	keywords = {aqueous DMSO, DIMETHYLSULFOXIDE, intensity, LIQUID, MIXING SCHEMES, NEUTRON-DIFFRACTION, PARTIAL MOLAR ENTHALPIES, WATER MIXTURES, x-ray diffraction},
	isbn = {0095-9782},
	url = {<Go to ISI>://000172934500003},
	author = {Koga,Yoshikata and Kasahara, Y. and Yoshino, K. and Nishikawa, K.}
}
@article {3038,
	title = {NUCLEAR-MAGNETIC-RESONANCE IMAGING AS A PROBE OF THE FREEZING-THAWING PHENOMENA OF LIQUIDS IN HETEROGENEOUS SYSTEMS},
	journal = {Magnetic Resonance in Chemistry},
	volume = {32},
	number = {5},
	year = {1994},
	note = {ISI Document Delivery No.: NK844Times Cited: 2Cited Reference Count: 18},
	month = {May},
	pages = {276-283},
	type = {Article},
	abstract = {NMR microscopic imaging is shown to be an excellent probe of the freezing and thawing phenomena of liquids in heterogeneous chemical systems, and, in addition, is capable of monitoring the freezing-thawing of mixed solvent systems. In the model mixed solvent system Me(2)SO-water, the chemical shift specific slice selective (C4S) imaging technique is used to obtain the spatial distributions of the concentrations and mobilities of the two individual solvents in test samples. Measurements of relaxation parameters make it possible to choose values of imaging parameters TE and TR to ensure quantitative reliability of the images. Images of test samples generated at various temperatures demonstrate the qualitative relationship between image intensity and the Me(2)SO-water phase diagram. This series of experiments verifies that NMR microscopic imaging will be a powerful tool for the study of liquids within solid matrices, and in particular of cryoprotectant solvents in biological systems.},
	keywords = {CRYOPROTECTANT, DIMETHYLSULFOXIDE, FREEZING, NMR, NMR imaging, RESOLUTION},
	isbn = {0749-1581},
	url = {<Go to ISI>://A1994NK84400003},
	author = {Fyfe, C. A. and Isbell, S. A. and Burlinson, N. E.}
}
@article {2837,
	title = {ROUTES TO RUTHENIUM(II) BROMO(SULFOXIDE) COMPLEXES, INCLUDING THE SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF A NEUTRAL DILITHIUM DIRUTHENIUM(II) COMPLEX CONTAINING TERMINAL AND BRIDGING TETRAMETHYLENE SULFOXIDE LIGANDS},
	journal = {Inorganica Chimica Acta},
	volume = {207},
	number = {1},
	year = {1993},
	note = {ISI Document Delivery No.: LB776Times Cited: 7Cited Reference Count: 36},
	month = {May},
	pages = {97-103},
	type = {Article},
	abstract = {{The dimeric Ru(II) complex [Br6(TMSO)2Ru2(mu2-TMSO)2(mu3-TMSO)2Li2(TMSO)2] (1) has been isolated from solutions containing RuCl3.3H3O, LiBr and TMSO (TMSO = tetramethylene sulfoxide, O and S indicating oxygen- and sulfur-bonding, respectively). Crystals of 1 are monoclinic},
	keywords = {CHELATION, CRYSTAL-STRUCTURE, DIMETHYLSULFOXIDE, OXIDATION, SOLUTION CHEMISTRY, SULFOXIDE)RUTHENIUM(II), SULFOXIDE)TETRACHLORORUTHENATE(III), VERSATILE STARTING MATERIALS},
	isbn = {0020-1693},
	url = {<Go to ISI>://A1993LB77600014},
	author = {Jaswal, J. S. and Yapp, D. T. T. and Rettig, S. J. and James, Brian R. and Skov, K. A.}
}
