@article {2617,
	title = {Observation of coexistence of 1D and 2D nanostructures in cobalt dipyrromethene trimer complexes adsorbed on a graphite surface},
	journal = {Applied Surface Science},
	volume = {256},
	number = {4},
	year = {2009},
	note = {ISI Document Delivery No.: 527BXTimes Cited: 0Cited Reference Count: 24Son, S. B. Lee, S. J. Hahn, J. R. Ma, L. Shin, J-Y. Dolphin, D.4th Vacuum and Surface Science Conference of Asia and AustraliaOCT 28-31, 2008Matsue City, JAPAN},
	month = {Nov},
	pages = {1176-1179},
	type = {Proceedings Paper},
	abstract = {We report the direct observation of 1D and 2D nanostructures of cobalt dipyrromethene trimer complexes adsorbed on a highly oriented pyrolytic graphite surface using scanning tunneling microscopy (STM). STM images showed two types of ordered structures coexisting on the surface: long 1D molecular chains isolated on the terraces, and 2D hexagonal patterns confined by a 1D chain and/or a graphite step edge. These 1D and 2D structures are attributed to {\textquoteright}edge-on{\textquoteright} and {\textquoteright}face-on{\textquoteright} complex alignments on the surface, respectively. In both configurations, substrate-mediated molecule-molecule interactions may play a significant role in stabilizing the nanostructures. (C) 2009 Elsevier B. V. All rights reserved.},
	keywords = {CHEMISTRY, dipyrromethene, Graphite, MANIPULATION, microscopy, MONOLAYER, PHTHALOCYANINES, PORPHYRIN, porphyrins, SCANNING TUNNELING MICROSCOPY, STM, Supramolecules, VACANCY},
	isbn = {0169-4332},
	url = {<Go to ISI>://000272342300062},
	author = {Son, S. B. and Lee, S. J. and Hahn, J. R. and Ma, L. and Shin, J. Y. and Dolphin, D.}
}
@article {1527,
	title = {A simple, catalytic H-2-hydrogenation method for the synthesis of fine chemicals; hydrogenation of protoporphyrin IX dimethyl ester},
	journal = {Tetrahedron Letters},
	volume = {47},
	number = {29},
	year = {2006},
	note = {ISI Document Delivery No.: 058XJTimes Cited: 2Cited Reference Count: 61Reboucas, Julio S. James, Brian R.},
	month = {Jul},
	pages = {5119-5122},
	type = {Article},
	abstract = {A conceptually simple H-2-hydrogenation protocol is introduced for the high-yield preparation of a natural product derivative. Protoporphyrin IX dimethyl ester is hydrogenated to the mesoporphyrin analogue in N,N-dimethylacetamide under H-2 (1 atm) at 80 degrees C within 30 min. The reaction is catalyzed by commercial RUCl3, without the need for the use of phosphine- and/or carbene-based ligands. (c) 2006 Elsevier Ltd. All rights reserved.},
	keywords = {ASYMMETRIC CATALYSIS, CARBON-MONOXIDE, COMPLEXES, HEME OXYGENASE-1, HORSERADISH-PEROXIDASE, MESOPORPHYRIN, METALLOPORPHYRINS, NUCLEAR-MAGNETIC-RESONANCE, PORPHYRIN, RUTHENIUM(II) MYOGLOBIN},
	isbn = {0040-4039},
	url = {<Go to ISI>://000238697600028},
	author = {Reboucas, J. S. and James, Brian R.}
}
@article {753,
	title = {Synthesis of the hemin of beta-tetrakis(trifluoromethyl)-meso-tetraphenylporphyrin and its evaluation as a P-450 mimic},
	journal = {Inorganica Chimica Acta},
	volume = {346},
	year = {2003},
	note = {ISI Document Delivery No.: 660EJTimes Cited: 4Cited Reference Count: 24},
	month = {Mar},
	pages = {261-264},
	type = {Article},
	abstract = {The hemin of beta-tetrakis(trifluoromethyl)-meso-tetraphenylporphyrin has been synthesized. Conventional methods for iron insertion failed; iron in low oxidation states (0 or II) brought about reduction of the macrocycle and Fe(III) failed to insert. Thus, insertion of iron into the macrocycle required the formation of the lithium complex, from lithium bis(trimethylsilyl)amide, followed by ferrous chloride. The novel hemin was tested as a catalyst for oxidations of cyclohexane and cyclohexene using iodosylbenzene as an oxidant and was found to be ineffective. (C) 2002 Elsevier Science B.V. All rights reserved.},
	keywords = {CATALYSIS, CATALYSTS, cytochrome P-450, ELECTROCHEMISTRY, METALLOPORPHYRINS, OXIDATION, PORPHYRIN, porphyrins, POSITIONS, POTENTIALS},
	isbn = {0020-1693},
	url = {<Go to ISI>://000181820600033},
	author = {Terazono, Y. and Dolphin, D.}
}
@article {4189,
	title = {Synthesis and characterization of homoleptic ruthenium(II) imidazole complexes, and a carbonyl species derived by CO abstraction from DMF},
	journal = {Canadian Journal of Chemistry-Revue Canadienne De Chimie},
	volume = {76},
	number = {10},
	year = {1998},
	note = {ISI Document Delivery No.: 156LMTimes Cited: 15Cited Reference Count: 37},
	month = {Oct},
	pages = {1379-1388},
	type = {Article},
	abstract = {{[Ru(II)(L)(6)](2+) complexes were synthesized from [Ru(DMF)(6)][CF3SO3](3); DMF = dimethylformamide},
	keywords = {ABSTRACTION, AQUATION, CHEMISTRY, CO, COORDINATION, crystal structures, CRYSTAL-STRUCTURES, hexakis(imidazole)ruthenium(II) triflates, PORPHYRIN},
	isbn = {0008-4042},
	url = {<Go to ISI>://000078002800008},
	author = {Baird, I. R. and Rettig, S. J. and James, Brian R. and Skov, K. A.}
}
@article {3912,
	title = {5,10-Diphenyltripyrrane, a useful building block for the synthesis of meso-phenyl substituted expanded macrocycles},
	journal = {Chemical Communications},
	number = {17},
	year = {1997},
	note = {ISI Document Delivery No.: XW022Times Cited: 62Cited Reference Count: 22},
	month = {Sep},
	pages = {1689-1690},
	type = {Article},
	abstract = {Pyrrole and benzaldehyde were condensed under acidic conditions to produce a mixture of 5-phenyldipyrromethane and 5,10-diphenyltripyrrane; the tripyrrane was utilized in syntheses of meso-phenylsapphyrins, meso-diphenylpentaphyrin and meso-hexaphenylhexaphyrin.},
	keywords = {PORPHOCYANINES, PORPHYRIN},
	isbn = {1359-7345},
	url = {<Go to ISI>://A1997XW02200050},
	author = {Bruckner, C. and Sternberg, E. D. and Boyle, R. W. and Dolphin, D.}
}
@article {3909,
	title = {Quantitative description of migration behavior of porphyrins based on the dynamic complexation model in a nonaqueous capillary electrophoresis system},
	journal = {Electrophoresis},
	volume = {18},
	number = {1},
	year = {1997},
	note = {ISI Document Delivery No.: WH231Times Cited: 47Cited Reference Count: 48},
	month = {Jan},
	pages = {82-91},
	type = {Article},
	abstract = {The effect of an additive (Brij 35) on the mobilities of a group of porphyrin acids is quantitatively characterized based on a 1:I dynamic complexation model. Varying additive concentration shifts the equilibrium and changes the viscosity of the background electrolyte. The equilibrium constant, the electrophoretic mobility of the free analyte, and the electrophoretic mobility of the complex are identified as the parameters necessary to describe the analytes{\textquoteright} migration behavior. Several statistical methods for obtaining these parameters are discussed. The equilibrium constants and complex mobilities are calculated using three different linear regression methods. The weighted y-recip-rocal method was preferred because it gives smaller error, and the data points are evenly distributed along the concentration axis. These values are confirmed using a nonlinear regression to ensure that the proper weighting was used in the linear regression plots. The parameters are then used to predict the apparent mobilities of the analytes over the entire additive concentration range, allowing the optimum separation conditions to be identified. For disclike molecules, such as porphyrins, the mobility is determined by the orientation of the molecule in an electric field, in addition to their size and charge. The strength of binding between the porphyrins and Brij 35 depends on the number of binding sites and the solvation shell.},
	keywords = {additives, AFFINITY, ANIONS, BETA-CYCLODEXTRIN, BINDING, CHIRAL SEPARATION, DYNAMIC COMPLEXATION, ENANTIOMERS, nonaqueous capillary electrophoresis, PARAMETERS, PORPHYRIN, SELECTIVITY, SELECTORS, separation theory, TIOCONAZOLE, ZONE ELECTROPHORESIS},
	isbn = {0173-0835},
	url = {<Go to ISI>://A1997WH23100016},
	author = {Bowser, M. T. and Sternberg, E. D. and Chen, D. D. Y.}
}
@article {3261,
	title = {beta,beta{\textquoteright}-Dihydroxylation of meso-tetraphenylchlorins and metallochlorins},
	journal = {Tetrahedron Letters},
	volume = {36},
	number = {52},
	year = {1995},
	note = {ISI Document Delivery No.: TM148Times Cited: 29Cited Reference Count: 19},
	month = {Dec},
	pages = {9425-9428},
	type = {Article},
	abstract = {meso-Tetraphenylchlorin and 2,3-vic-dihydroxy-meso-tetraphenylchlorin and their zinc complexes were dihydroxylated by stoichiometric amounts of OsO4. The chlorins gave specifically 2,3-vic-dihydroxy-meso-tetraphenylbacteriochlorins or 2,3, 12,13-bis-(vic-dihydroxy)bacteriochlorins while the Zn(II)-chlorins gave (2,3-vic-dihydroxy-meso-tetraphenylisobacteriochlorinato) Zn(II) or [2,3,7,8-bis-(vic-dihydroxy)-meso-tetraphenylisobacteriochlorinato]Zn(II ).},
	keywords = {PORPHYRIN},
	isbn = {0040-4039},
	url = {<Go to ISI>://A1995TM14800002},
	author = {Bruckner, C. and Dolphin, D.}
}
@article {3320,
	title = {NET AMINE DEALKYLATION AT A DIRUTHENIUM CENTER - DEHYDROGENATION OF A SECONDARY AMINE AND HYDROLYSIS OF A COORDINATED IMINE},
	journal = {Inorganic Chemistry},
	volume = {34},
	number = {10},
	year = {1995},
	note = {ISI Document Delivery No.: QX706Times Cited: 26Cited Reference Count: 36},
	month = {May},
	pages = {2557-2561},
	type = {Article},
	abstract = {Reaction of excess benzylamine with Ru2Cl4(dppb)(2) (1) or RuCl2(dppb)(PPh(3)) (2) under Ar or with Ru2Cl5(dppb)(2) (3) under H-2 or in air generates RuCl2(dppb)(NH(2)CH(2)Ph)(2) [dppb = 1,4-bis(diphenylphosphino)butane, Ph(2)P(CH2)(4)PPh(2)]. Use of 1 equiv of amine per [Ru(II)](2) gives dinuclear Ru2Cl4(dppb)(2)(NH(2)CH(2)Ph) (4a) as a mixture of isomers. The corresponding reactions with dibenzylamine yield only dinuclear products: either Ru2Cl4(dppb)(2)[NH(CH(2)Ph)(2)] (4b), for reactions under H-2, or a mixture of this species and the dealkylation product 4a. The mechanism proposed for formation of the latter involves dehydrogenation of the secondary amine adduct to Ru2Cl4(dppb)(2)[PhCH(2)N=C(H)Ph], followed by hydrolysis of the coordinated imine. Direct reaction of PhCH(2)N=C(H)Ph with 3 under H-2 permits isolation of solely 4b. The findings are of interest also in context of thermal degradation of tertiary amines and hydrogenation of imines catalyzed by Ru ditertiary phosphine complexes.},
	keywords = {ACTIVATION, CATALYSTS, COMPLEXES, CONVERSION, CRYSTAL-STRUCTURE, DIHYDROGEN, PHOSPHINE COMPLEXES, PORPHYRIN, REACTIVITY, ruthenium complexes, TERTIARY-AMINES},
	isbn = {0020-1669},
	url = {<Go to ISI>://A1995QX70600012},
	author = {Fogg, D. E. and James, Brian R.}
}
@article {2784,
	title = {PORPHOCYANINE - AN EXPANDED TETRAPYRROLIC MACROCYCLE},
	journal = {Journal of the American Chemical Society},
	volume = {115},
	number = {20},
	year = {1993},
	note = {ISI Document Delivery No.: MC277Times Cited: 25Cited Reference Count: 14},
	month = {Oct},
	pages = {9301-9302},
	type = {Note},
	keywords = {PORPHYRIN},
	isbn = {0002-7863},
	url = {<Go to ISI>://A1993MC27700061},
	author = {Dolphin, D. and Rettig, S. J. and Tang, H. and Wijesekera, T. and Xie, L. Y.}
}
@article {6996,
	title = {VERATRYL ALCOHOL AS A MEDIATOR IN LIGNIN MODEL-COMPOUND BIODEGRADATION},
	journal = {Holzforschung},
	volume = {45},
	number = {1},
	year = {1991},
	note = {ISI Document Delivery No.: FC210Times Cited: 7Cited Reference Count: 22},
	month = {Feb},
	pages = {31-35},
	type = {Article},
	abstract = {Veratryl alcohol and 1,4-dimethoxybenzene were found to be ineffective mediators for the oxidation of anisyl alcohol by the lignin peroxidase model, iron meso-tetra(2,6-dichloro-3-sulfonatophenyl)porphyrin chloride (TDCSPPFeCl). However, veratryl alcohol can mediate the electrochemical oxidation of the polymeric dye Poly B-411. The TDCSPPFeCl catalyzed reactions of lignin model compounds were found to be dependent on pH and the solvent being used. The importance of the mediating role of veratryl alcohol in lignin degradation is discussed.},
	keywords = {APPROACH, BASIDIOMYCETE PHANEROCHAETE-CHRYSOSPORIUM, BIOMIMETIC, BURDS, C BOND-CLEAVAGE, DEGRADATION, ENZYME, IRON PORPHYRINS, LIGNIN, MECHANISM, MEDIATOR, OXIDATION, PEROXIDASE, PORPHYRIN, SYSTEM, VERATRYL ALCOHOL},
	isbn = {0018-3830},
	url = {<Go to ISI>://A1991FC21000006},
	author = {Cui, F. T. and Dolphin, D.}
}
