@article {WANG20198, title = {Solvent-free high-throughput analysis of herbicides in environmental water}, journal = {Analytica Chimica Acta}, volume = {1071}, year = {2019}, month = {04/2019}, pages = {8 - 16}, abstract = {

A high throughput, and eco-friendly method based on solid-phase microextraction (SPME) combined with direct analysis in real time mass spectrometry (DART-MS) was established for the determination of trace pollutants in water. A laboratory-made SPME device coated with a metal organic framework (MIL-100 (M)) was fabricated for the on-site enrichment of triazine herbicides in environmental water, and the device was directly subjected to DART ionization (\<20 s) for high resolution MS. The interactions between the target analytes and sorbents were investigated to improve the SPME device targeting specific pollutants, as well as to improve the desorption and ionization processes with DART-MS. Other factors were also systematically studied to obtain the optimal conditions, including pH, salinity, extraction temperature, pressure at the Vapur\® interface, linear rail moving speed, gas temperature, extraction time, and sample volume. The limit of detection of target compounds were 5.0\–50.0 ng L\−1 and the recoveries ranged from of 92.4\%\–125.7\%.

}, keywords = {direct analysis in real time mass spectrometry, Metal-organic frameworks, SOLID-PHASE MICROEXTRACTION, Sustainable analytical method, Triazine herbicides}, issn = {0003-2670}, doi = {https://doi.org/10.1016/j.aca.2019.04.024}, url = {http://www.sciencedirect.com/science/article/pii/S0003267019304453}, author = {Jiaqin Wang and Qi Du and Xinrui You and Youqi Lv and Wentao Bi and Hongli Li and David D. Y. Chen} } @article {1491, title = {Analysis of amphetamine, methamphetamine and methylenedioxy-methamphetamine by micellar capillary electrophoresis using cation-selective exhaustive injection}, journal = {Electrophoresis}, volume = {27}, number = {16}, year = {2006}, note = {ISI Document Delivery No.: 081RBTimes Cited: 18Cited Reference Count: 40Meng, Pinjia Fang, Ning Wang, Meng Liu, Huwei Chen, David D. Y.}, month = {Aug}, pages = {3210-3217}, type = {Article}, abstract = {Cation-selective exhaustive injection (CSEI) is used as an on-line concentration method for the high-sensitivity analysis of illicit amphetamines using CE. Optimum conditions for the determination of amphetamine, methamphetamine and methylenedioxy-methamphetamine were investigated. Sodium dodecyl sulfate (25 mM) in 100 mM phosphate buffer (pH 2.9) with 20\% methanol as organic additive was used as the background electrolyte for CE separation. The LOD, based on an S/N of 3:1, was about 0.01 mu g/mL using normal capillary micellar electrokinetic chromatography, while by using CSEI in combination with micellar sweeping the sensitivity increased up to 1000-fold with the LOD lower than 50 pg/mL. The reproducibility of CSEI combined with micellar sweeping for analyzing amphetamines was satisfactory (relative standard deviation around 10\% by using area ratios against an internal standard). This method is highly sensitive and can be used to analyze trace amount amphetamines in human hair.}, keywords = {amphetamine, AMPLIFIED SAMPLE STACKING, analysis, cation-selective exhaustive injection, CHROMATOGRAPHY, CHROMATOGRAPHY-MASS SPECTROMETRY, ELECTROKINETIC, FLUORESCENCE DETECTION, illicit drug, LIQUID-CHROMATOGRAPHY, methamphetamine, methylenedioxy-methamphetamine, NEUTRAL ANALYTES, ONLINE CONCENTRATION, REVERSE MIGRATING MICELLES, SOLID-PHASE MICROEXTRACTION, ZONE-ELECTROPHORESIS}, isbn = {0173-0835}, url = {://000240333600007}, author = {Meng, P. J. and Fang, N. and Wang, M. and Liu, H. W. and Chen, D. D. Y.} }