@article {1433,
	title = {Reaction of H2S with MoRu(CO)(6)(dppm)(2) to give H-2 and a bridged-sulfide product via hydrido-sulfhydryl intermediates (dppm = Ph2PCH2PPh2)},
	journal = {Canadian Journal of Chemistry-Revue Canadienne De Chimie},
	volume = {84},
	number = {2},
	year = {2006},
	note = {ISI Document Delivery No.: 040YKTimes Cited: 2Cited Reference Count: 29},
	month = {Feb},
	pages = {330-336},
	type = {Article},
	abstract = {Oxidative addition of H2S to MoRu(CO)(6)(mu-dppm)(2) (1) at similar to 20 degrees C in toluene yields an isolable complex formulated as Mo(CO)(3)(mu-SH)(mu-CO)(mu-dppm)(2)RuH(CO) (2) via the possible intermediate Mo(CO)(3)(mu-H)(mu-CO)(mu-dppm)(2)Ru(SH)(CO) (4) (dppm = Ph2PCH2PPh2) that is detectable at lower temperatures. Over 2 days, species 2 in toluene loses H-2 (and CO) to yield the bridged-sulfide product, Mo(CO)(2)(mu-CO)(mu-S)(mu-dppm)(2)Ru(CO) (5) that is also formed directly from the reaction of 1 with elemental sulfur. The solid-state molecular structure of 5 is determined by X-ray crystallography. A further hydrido-sulfhydryl species, possibly Mo(CO)(3)(mu-SH)(mu-H)(mu-dppm)(2)Ru(CO)(2) (3), is in equilibrium with 2 at ambient temperature.},
	keywords = {bis(diphenylphosphino) methane, bis(diphenylphosphino)methane, BOND ACTIVATION, bridged-sulfide complex, carbonyl complexes, CHEMISTRY, COMPLEXES, hydrido-sulfhydryl species, HYDROGEN, HYDROGEN-SULFIDE, MECHANISTIC ASPECTS, METAL, MO, MOLYBDENUM, RECOVERY, ruthenium, sulfide, SULFUR-DIOXIDE},
	isbn = {0008-4042},
	url = {<Go to ISI>://000237417600031},
	author = {Khorasani-Motlagh, M. and Safari, N. and Pamplin, C. B. and Patrick, B. O. and James, Brian R.}
}
@article {651,
	title = {Oxidative addition of halogens to MoRu(CO)(6)(dppm)(2)},
	journal = {Inorganic Chemistry Communications},
	volume = {6},
	number = {9},
	year = {2003},
	note = {ISI Document Delivery No.: 720EATimes Cited: 2Cited Reference Count: 27},
	month = {Sep},
	pages = {1175-1179},
	type = {Article},
	abstract = {Halogens oxidatively add to MoRu(CO)(6)(mu-dppm)(2) (1) at ambient temperature to yield [(CO)(2)Mo(mu-X)(mu-CO)(mu-dpmm)(2)Ru(CO)(2)] (divided by)[Mo(CO)(4) X-3](-), where X = Cl (2) or I (3), dppm - Ph2PCH2PPh2, and the mu-CO is semi-bridging. Complexes 2 and 3 have been characterized by elemental analysis, conductivity, and NMR spectroscopy, while the molecular structure of 3 has been determined by X-ray crystallography. Ignoring a weak metal-metal bond interaction, the cation of 3 is most easily described as pseudo-octahedral at Ru(II) and Mo(0) centres; the anion is a monocapped octahedron that has been described previously. (C) 2003 Elsevier B.V. All rights reserved.},
	keywords = {COMPLEX RHRE(CO)4(PH2PCH2PPH2)2, crystal structure, CRYSTAL-STRUCTURE, H2S, halogen reactivity, METAL-CARBONYLS, MO, molybdenum complex, MOLYBDENUM(II), RH, RU, ruthenium complex, semi-bridged carbonyl, SULFUR-DIOXIDE, {bis(diphenylphosphino)methane},
	isbn = {1387-7003},
	url = {<Go to ISI>://000185247500003},
	author = {Khorasani-Motlagh, M. and Safari, N. and Pamplin, C. B. and Patrick, B. O. and James, Brian R.}
}
@article {5095,
	title = {Spectra of jet-cooled (SO2)-S-32 and (SO2)-S-34 in systems (a)over-tilde(3)B(1) and (b)over-tilde(3)A(2)-(X)over-tilde(1)A(1): Rotational structure of perturbed (b)over-tilde(3)A(2)},
	journal = {Journal of Chemical Physics},
	volume = {114},
	number = {3},
	year = {2001},
	note = {ISI Document Delivery No.: 388ZNTimes Cited: 6Cited Reference Count: 20},
	month = {Jan},
	pages = {1187-1193},
	type = {Article},
	abstract = {{Spectra of (a) over tilde B-3(1)(nu (1)nu (2)nu (3))=(110) and (200)-(X) over tilde (1)A(1)(000) of (SO2)-S-32 and (SO2)-S-34 are obtained in a supersonic jet at a resolution 0.015 cm(-1). The rotational structures are analyzed for both isotopic species to obtain precise rotational and spin constants. Two new bands at 27 032.222(1) and 27 515.41(1) cm-1 arising from vibronic interaction separately with vibrational state (110) and (200) of (a) over tilde B-3(1) are assigned to transitions to (b) over tilde (3)A(2)(011) and (101). The rotational structure of (b) over tilde (3)A(2) is observed and analyzed for the first time. The two vibrational states are analyzed to yield effective rotational constants A=1.4348(3), 1.89(3)},
	keywords = {AMPLIFIED SPONTANEOUS EMISSION, BAND SYSTEM, NM, SO2, STATE, STIMULATED BRILLOUIN-SCATTERING, SULFUR-DIOXIDE},
	isbn = {0021-9606},
	url = {<Go to ISI>://000166213100015},
	author = {Huang, C. L. and Chen, I. C. and Merer, A. J. and Ni, C. K. and Kung, A. H.}
}
@article {4834,
	title = {High-resolution spectroscopy of jet-cooled (SO2)-S-32 and (SO2)-S-34: The (a)over-tilde(3)B(1)-(X)over-tilde(1)A(1), 2(0)(1) and 1(0)(1) bands},
	journal = {Journal of Molecular Spectroscopy},
	volume = {203},
	number = {1},
	year = {2000},
	note = {ISI Document Delivery No.: 347WMTimes Cited: 5Cited Reference Count: 20},
	month = {Sep},
	pages = {151-157},
	type = {Article},
	abstract = {Laser-induced excitation spectra of the two bands (a) over tilde(3)B(1)-(X) over tilde(1)A(1), 2(0)(1) and 1(0)(1) of (SO2)-S-32 and (SO2)-S-34 have been recorded in a supersonic jet at a resolution of 0.015 cm(-1). The rotational and electron-spin fine structure has been analyzed for both isotopic species. Analysis of the rotational and electron-spin fine structure yields precise values of the rotational constants A, B, and C and the spin constants alpha and beta for both (SO2)-S-32 and (SO2)-S-34 in the states (a) over tilde(3)B(1) (010) and (100). No interaction between these two vibrational States with any nearby triplet state is observed for rotational levels with J less than or equal to 8 and K less than or equal to 2. (C) 2000 Academic Press.},
	keywords = {ABSORPTION, AMPLIFIED SPONTANEOUS EMISSION, ROTATIONAL STRUCTURE, SO2, SPECTRUM, STATE, STIMULATED BRILLOUIN-SCATTERING, sulfur dioxide, SULFUR-DIOXIDE, SYSTEM},
	isbn = {0022-2852},
	url = {<Go to ISI>://000088952200018},
	author = {Huang, C. L. and Ju, S. S. and Chen, I. C. and Merer, A. J. and Ni, C. K. and Kung, A. H.}
}
@article {4991,
	title = {Laser-induced phosphorescence of SO2 in solid neon: Direct observation of the (b)over-tilde(3)A(2) state in the (OSO)-O-16-O-18 molecule},
	journal = {Journal of Physical Chemistry A},
	volume = {104},
	number = {4},
	year = {2000},
	note = {ISI Document Delivery No.: 280WFTimes Cited: 13Cited Reference Count: 41},
	month = {Feb},
	pages = {771-776},
	type = {Article},
	abstract = {Laser excitation of isotopically labeled SO2 molecules in a neon matrix has allowed the measurement of dispersed phosphorescence spectra ((a) over tilde(3)B(1)-(X) over tilde(1)A(1)) in the wavelength region 387.5-526.3 nm (19 000-25 800 cm(-1)). The origin of the (a) over tilde-(X) over tilde transition lies at 25 747 cm(-1) in (OSO)-O-16-O-16, shifted 18 cm(-1) to the red from the gas phase; the three vibrational frequencies of the (X) over tilde state are nearly unperturbed in the neon matrix (1149, 520, and 1362 cm(-1)). As the zero-phonon lines are sharp and well resolved, it has been possible to monitor emission from a specific isotopomer to obtain its excitation spectrum. The excitation spectra of matrix-isolated (OSO)-O-16-O-16 and (OSO)-O-18-O-18 in the region 350.9-388.5 nm (25 740-28 500 cm(-1)) are similar to those previously observed in the gas phase, with strong perturbations affecting all vibrational levels above a(3)B(1)(110) at 27 005 cm(-1) (370 nm). Two additional groups of bands are observed for the unsymmetrical isotopomer (OSO)-O-18-O-16; they are identified as transitions to levels of the (a) over tilde(3)B(1) state with v(3) = 1 and as direct transitions to the (b) over tilde(3)A(2) state, which both become allowed in the lower symmetry. The v(3) frequency of the (a) over tilde(3)B(1) state of (OSO)-O-18-O-16 is 922 cm(-1); for the (b) over tilde(3)A(2) state, v(1) similar or equal to 791 cm(-1) and v(2) similar or equal to 315 cm(-1), while the (b) over tilde (001) level lies 26 653 cm(-1) above the (X) over tilde (000) level.},
	keywords = {ABSORPTION, BAND SYSTEM, FLUORESCENCE, INDUCED EMISSION, MATRICES, REGION, ROTATIONAL, SPECTRA, STRUCTURE, SULFUR-DIOXIDE, VIBRATIONAL STRUCTURE},
	isbn = {1089-5639},
	url = {<Go to ISI>://000085126200014},
	author = {Zen, C. C. and Chen, I. C. and Lee, Y. P. and Merer, A. J.}
}
