@article {1402,
	title = {The first report of a muoniated free radical formed from reaction of Mu with Br-2},
	journal = {Physica B-Condensed Matter},
	volume = {374},
	year = {2006},
	note = {ISI Document Delivery No.: 027BNTimes Cited: 2Cited Reference Count: 1410th International Conference on Muon Spin Rotation, Relaxation and ResonanceAUG 08-12, 2005Oxford, ENGLANDHamamatsi Photon, ISIS Fac, Triumf Fac},
	month = {Mar},
	pages = {303-306},
	type = {Proceedings Paper},
	abstract = {In this paper, we report preliminary data for the first direct evidence of a free radical formed from Mu reactivity with Br-2 ill the gas phase, in N-2 moderator at a total pressure of 3 bar. A new experimental setup and target vessel for mu SR studies of reactive Compounds, such as the halogens and hydrogen halides, suitable as well for RF measurements, is described. The experimental data, obtained from a longitudinal field repolarization curve, yields a hfc of 1770 MHz. We tentatively identify this as the [BrMuBr] radical, a non-conventional bond system, arising from the combination of a van der Waals interaction and dynamics on a repulsive surface. Studies of the dynamics and hfcs of possible radicals, which in principal could form, are also outlined here. (c) 2005 Elsevier B.V. All rights reserved.},
	keywords = {chemical dynamics, ENERGY, GASES, halogen, IHI, isotope effect, muonium, STATE},
	isbn = {0921-4526},
	url = {<Go to ISI>://000236388800078},
	author = {Ghandi, K. and Cottrell, S. P. and Fleming, Donald G. and Johnson, C.}
}
@article {7380,
	title = {SELECTED REACTIONS OF FLUORINE-FLUOROSULFATE, FOSO2F},
	journal = {Journal of Fluorine Chemistry},
	volume = {59},
	number = {3},
	year = {1992},
	note = {ISI Document Delivery No.: KF321Times Cited: 8Cited Reference Count: 36},
	month = {Dec},
	pages = {333-349},
	type = {Article},
	abstract = {The reactions of fluorine-fluorosulfate, FOSO2F, with SSF2, SeF4, AsF3 and MoF5 have been studied, and its previously reported reactions with SF4, Br2 and I2 re-investigated in order to test its suitability as a synthetic reagent. All substrates reacted exothermically, and sometimes explosively, between 80-298 K. The presence of the byproducts obtained may be rationalized by the thermal decomposition of some of the FOSO2F, which proceeds along two pathways, i.e. FOSO2F {\textendash}> 1/2O2 + SO2F2 and FOSO2F {\textendash}> 1/2F2 + 1/2S2O6F2, during the extremely exothermic reactions via radical intermediates. The fluorine formed gives rise to fully fluorinated products, and the SO3F. radicals, initially formed, either dimerize to give S2O6F2 or decompose to O2 and S2O5F2. Element fluoride-fluorosulfates, when formed at all, were obtained in low yields only when SO2F2 or SO2FCl were used as suitable moderators. The complete vibrational spectra of EF5OSO2F (E = S, Se or Te) have been studied and assigned. The reactions of I2, Br2 and AsF3 with FOSO2F yielded viscous liquids of the approximate, non-stoichiometric composition EFn(SO5F)5-n (E = As or I) and EFn(SO3F)3-n (E = Br), with n = non-integral number. All compounds were characterized by their vibrational and F-19 NMR spectra, and in the case of SeF5OSO2F by Se-77 NMR methods.},
	keywords = {DERIVATIVES, GOLD(III) FLUOROSULFATE, halogen, ION, SPECTRA, TRIS(FLUOROSULFATE)},
	isbn = {0022-1139},
	url = {<Go to ISI>://A1992KF32100004},
	author = {Willner, H. and Mistry, F. and Aubke, F.}
}
