@article {3125,
	title = {RADICAL FORMATION DURING THE REACTION OF BIS(FLUOROSULFURYL)PEROXIDE, S2O6F2, WITH TETRASULFUR TETRANITRIDE, S4N4, AND ELEMENTAL SULFUR, S-8},
	journal = {Journal of Fluorine Chemistry},
	volume = {66},
	number = {2},
	year = {1994},
	note = {ISI Document Delivery No.: MX367Times Cited: 1Cited Reference Count: 46},
	month = {Feb},
	pages = {147-152},
	type = {Article},
	abstract = {The radical intermediates formed initially in the reaction of S2O6F2 with S4N4 and S8 have been studied by ESR spectroscopy at X-band level. The transient radical formed in the reaction between S2O6F2 and S4N4 has the spin Hamiltonian parameters g(xx) = 2.0014, g(yy) = 2.0054, g(zz) = 2.0249, A(xx) = 22.5 MHz, A(yy) = 4.5 MHz, A(zz) = 2.0 MHz and Q(zz) = 4 MHz as determined by simulation of ESR lineshapes obtained from polycrystalline samples. The spin Hamiltonian parameters are very similar to those previously reported for [S3N2]+., and the spectra are interpreted as being most likely due to the [S3N2]+. radical. The reaction between S2O6F2 and S8 under similar conditions produces a radical that has a g-tensor of the form g(xx) = 2.0026, g(yy) = 2.0184, g(zz) = 2.0258, as determined by simulation. The transient species generated is postulated to be a similar S5+. radical.},
	keywords = {CRYSTAL-STRUCTURE, ELECTRON-SPIN-RESONANCE, HSO3F, NITROGEN, POLYATOMIC CATIONS, S3N2+, SALTS, SPECTRUM},
	isbn = {0022-1139},
	url = {<Go to ISI>://A1994MX36700011},
	author = {Mistry, F. and Herring, F. G. and Haas, A. and Aubke, F.}
}
