@article {32774,
	title = {Chelating N-Heterocyclic Carbene Ligands Enable Tuning of Electrocatalytic CO2 Reduction to Formate and Carbon Monoxide: Surface Organometallic Chemistry},
	journal = {Angewandte Chemie International Edition},
	volume = {57},
	year = {2018},
	pages = {4981-4985},
	abstract = {<p>Abstract Reported here is the chelate effect as a design principle for tuning heterogeneous catalysts for electrochemical CO2 reduction. Palladium functionalized with a chelating tris-N-heterocyclic carbene (NHC) ligand (Pd-timtmbMe) exhibits a 32-fold increase in activity for electrochemical reduction of CO2 to C1 products with high Faradaic efficiency (FEC1=86\&thinsp;\%) compared to the parent unfunctionalized Pd foil (FE=23\&thinsp;\%), and with sustained activity relative to a monodentate NHC-ligated Pd electrode (Pd-mimtmbMe). The results highlight the contributions of the chelate effect for tailoring and maintaining reactivity at molecular-materials interfaces enabled by surface organometallic chemistry.</p>},
	keywords = {CO2 reduction, electrocatalysis, N-heterocyclic carbenes, palladium, surface chemistry},
	doi = {10.1002/anie.201800367},
	url = {https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.201800367},
	author = {Cao, Zhi and Derrick, Jeffrey S. and Xu, Jun and Gao, Rui and Gong, Ming and Nichols, Eva M. and Smith, Peter T. and Liu, Xingwu and Wen, Xiaodong and Cop{\'e}ret, Christophe and Chang, Christopher J.}
}
@article {2627,
	title = {Noninnocent Behavior of Ancillary Ligands: Apparent Trans Coupling of a Saturated N-Heterocyclic Carbene Unit with an Ethyl Ligand Mediated by Nickel},
	journal = {Journal of the American Chemical Society},
	volume = {131},
	number = {30},
	year = {2009},
	note = {ISI Document Delivery No.: 479FFTimes Cited: 6Cited Reference Count: 26Steinke, Tobias Shaw, Bryan K. Jong, Howard Patrick, Brian O. Fryzuk, Michael D. Green, Jennifer C.},
	month = {Aug},
	pages = {10461-10466},
	type = {Article},
	abstract = {Oxidative addition of the tridentate N-heterocyclic carbene (NHC) diphosphine ligand precursor ([PCP]H)PF6 (1) {[PCP] = o-(Pr2PC6H4)-Pr-i(NC3H4N)o-(C6H4PPr2)-Pr-i} to Ni(COD)(2) results in the formation of the nickel(II) hydride complex ([PCP]NiH)PF6 (2). This hydride undergoes a rapid reaction with ethylene to generate a nickel(O) complex in which an ethyl group has been transferred to the carbene carbon of the original NHC-diphosphine ligand. If the first intermediate is the anticipated square-planar nickel(II) ethyl species, then the formation of the product would require a process that involves a trans C-C coupling of the NHC carbon and a presumed Ni-ethyl intermediate. Deuterium-labeling studies provide evidence for migratory insertion of the added ethylene into the Ni-H bond rather than into the Ni-catene linkage; this is based on the observed deuterium scrambling, which requires reversible P-elimination, alkene rotation, and hydride readdition. However, density functional theory studies suggest that a key intermediate is an agostic ethyl species that has the Ni-C bond cis to the NHC unit. A possible transition state containing two cis-disposed carbon moieties was also identified. Such a process represents a new pathway for catalyst deactivation involving NHC-based metal complexes.},
	keywords = {ACTIVATION, CHEMISTRY, COMPLEXES, MECHANISM, MIGRATORY INSERTION, NHC, ORGANOMETALLIC CATALYSIS, palladium, REDUCTIVE ELIMINATION, ruthenium},
	isbn = {0002-7863},
	url = {<Go to ISI>://000268644400040},
	author = {Steinke, T. and Shaw, B. K. and Jong, H. and Patrick, B. O. and Fryzuk,Michael D. and Green, J. C.}
}
@article {1147,
	title = {Calorimetric study on self-assembling of two kinds of monometallic nanoparticles in solution},
	journal = {Journal of Thermal Analysis and Calorimetry},
	volume = {81},
	number = {3},
	year = {2005},
	note = {ISI Document Delivery No.: 962VGTimes Cited: 4Cited Reference Count: 233rd International Symposium on New Frontiers of Thermal Studies of MaterialsNOV 28-30, 2004Tsukuba, JAPANJSCTA, Univ Tsukuba, Grad Sch Pure \& Appl Sci, Soc Promot Calorimetry \& Thermal Anal, Ibaraki, Sci \& Technol Promot Fdn},
	month = {Aug},
	pages = {523-527},
	type = {Proceedings Paper},
	abstract = {Recently, we have reported a noble method of preparing Ag/Rh bimetallic nanoparticles with a pseudo-core/shell structure. We simply mix the dispersions of poly(N-vinyl-2-pyrrolidone)(PVP)-protected Ag and Rh nanoparticles in solution at room temperature. We found that the mixture of dispersions forms bimetallic nanoparticles in a pseudo-core/shell structure on standing. We call this process the {\textquoteright}self-assembling{\textquoteright} or {\textquoteright}self-organizing{\textquoteright}. In this study we seek for a thermodynamic driving force for this process by determining the enthalpy of the interaction among three pairs of nanoparticles by isothermal titration calorimetry (ITC). The results indicate that the interaction between each pair is strongly exothermic, and that among the pairs studied here the strength of the exothermic interaction is in the order of Ag/Pt<Ag/Pd<Ag/Rh.},
	keywords = {bimetallic nanoparticles, calorimetric method, CATALYTIC-ACTIVITY, CLUSTERS, CORE-SHELL NANOPARTICLES, core/shell structure, GROWTH, isothermal titration calorimetry, metal nanoparticle, NUCLEATION, palladium, PD, platinum, REDUCTION, rhodium, self-assembling, SELF-ORGANIZATION, silver, STRUCTURAL-ANALYSIS},
	isbn = {1388-6150},
	url = {<Go to ISI>://000231760500004},
	author = {Kanemaru, M. and Shiraishi, Y. and Koga,Yoshikata and Toshima, N.}
}
@article {1187,
	title = {A new arene-bridged diamidophosphine ligand and its coordination chemistry with zirconium(IV)},
	journal = {Organometallics},
	volume = {24},
	number = {6},
	year = {2005},
	note = {ISI Document Delivery No.: 904YFTimes Cited: 15Cited Reference Count: 48},
	month = {Mar},
	pages = {1112-1118},
	type = {Article},
	abstract = {The arene-bridged dilithium diamidophosphine ligand, [(2,4,6-Me3C6H2)NLi-2-(5-MeC6H3)](2)PPh, [NPN]*Li-2, was prepared from (2,4,6-Me3C6H2)(2-Br-4-MeC6H3)NH, (BuLi)-Bu-n, and PhPCl2 in Et2O and isolated as a dioxane adduct in similar to 85\% yield. The solid-state structure of [NPN]*Li-2(THF)2 as determined by X-ray diffraction shows both lithiums bridged by the amido nitrogens with one Li ion coordinated to the phosphine donor. The reaction of [NPN]*H-2 and Zr(NMe2)(4) in toluene produced [NPN]*Zr(NMe2)(2) in 90\% isolated yield. Addition of excess Me3SiCl to [NPN]*Zr(NMe2)(2) converts it to [NPN]*ZrCl2 in high yield. The solid-state structure of [NPN] *ZrCl2 as determined by X-ray diffraction shows the Zr center is a distorted trigonal bipyramid with the phosphine and the chloride apical. The ortho-Me{\textquoteright}s on the N-mesityl moiety are inequivalent in both the Li and Zr complexes of [NPN]* by NMR spectroscopy, while in [NPN]*H-2 MesN ortho-Me{\textquoteright}s appear as broad singlets. VT-NMR of [NPN]*H-2 indicated that Delta G(rot)(double dagger) of MesC(ipso)-N is approximately 15.5 +/- 0.3 kcal mol(-1). The thermally labile and light-sensitive zirconium dimethyl complex [NPN]*ZrMe2 was prepared from [NPN]*ZrCl2 and MeMgCl in Et2O in 80\% yield.},
	keywords = {CLEAVAGE, COMPLEX, COUPLING REACTIONS, DINITROGEN LIGAND, END-ON, METAL-COMPLEXES, MOLECULAR NITROGEN, N-2 UNIT, palladium, SIDE-ON, tantalum},
	isbn = {0276-7333},
	url = {<Go to ISI>://000227533800014},
	author = {MacLachlan, E. A. and Fryzuk,Michael D.}
}
@article {1142,
	title = {Palladium(II) complexes of bis(phosphine)monooxide and bis(phosphine)monosulphide ligands bearing o-N,N-dimethylanilinyl substituents},
	journal = {Canadian Journal of Chemistry-Revue Canadienne De Chimie},
	volume = {83},
	number = {6-7},
	year = {2005},
	note = {ISI Document Delivery No.: 963UVTimes Cited: 3Cited Reference Count: 49},
	month = {Jun},
	pages = {546-552},
	type = {Article},
	abstract = {{Palladium( II) complexes of bis( phosphine) monooxide and bis( phosphine) monosulphide ligands with the general formula Ar2P( CH2) P-n( E) Ar-2 are described ( n = 1 ( dmapmE)},
	keywords = {ARYL HALIDES, BIPHOSPHINE MONOXIDE LIGANDS, BISPHOSPHINE LIGANDS, CATALYSIS, CHEMISTRY, CHIRAL DIPHOSPHINE, COORDINATION, CROSS-COUPLING REACTIONS, DONOR, OXIDATION, palladium, phosphine, phosphine oxide, phosphine sulphide, PHOSPHINE-LIGANDS},
	isbn = {0008-4042},
	url = {<Go to ISI>://000231832500007},
	author = {Jones, N. D. and James, Brian R.}
}
@article {876,
	title = {Pt(II) or Ag(I) salt catalyzed cycloisomerizations and tandem cycloadditions forming functionalized azacyclic arrays},
	journal = {Organic Letters},
	volume = {6},
	number = {26},
	year = {2004},
	note = {ISI Document Delivery No.: 880TNTimes Cited: 47Cited Reference Count: 41},
	month = {Dec},
	pages = {5023-5026},
	type = {Article},
	abstract = {Cyclic ene-N-p-toluenesulfonamides tethered to an electron-deficient alkyne undergo cycloisomerizations readily under the influence of catalytic Pt(II) salts (PtCl2 or [dppbPtmu-OH](2)(BF4)(2)) or AgOTf. Yields for this process range from 47\% to 99\%. The resulting functionalized 2-azahydrindans can be reacted further using the Diels-Alder reaction. Tandem cycloisomerization-cycloaddition reactions in one pot generate highly functionalized 1-azadecalin ring systems in a highly stereocontrolled manner.},
	keywords = {COMPLEXES, cyclizations, ENAMIDES, ENANTIOSELECTIVE REACTIONS, ENYNES, ORGANIC-SYNTHESIS, palladium, platinum, REORGANIZATION, SKELETAL, STEREOCONTROLLED TOTAL-SYNTHESIS},
	isbn = {1523-7060},
	url = {<Go to ISI>://000225812300057},
	author = {Harrison, T. J. and Dake, G. R.}
}
@article {613,
	title = {Diastereoselective formation of a dipalladium(I) complex supported by a bridging tetradentate ligand, and oxidative addition of RS-H across a phosphine-bridged Pd-I-Pd-I bond},
	journal = {Chemical Communications},
	number = {8},
	year = {2003},
	note = {ISI Document Delivery No.: 663LZTimes Cited: 7Cited Reference Count: 13},
	pages = {988-989},
	type = {Article},
	abstract = {{The ligand CH2(P(o-C6H4NMe2)(2))(2) (dmapm) gives access to the first example of a dipalladium(I) complex supported by a tetradentate ligand, Pd2Cl2(mu-N,P,P,N-dmapm), which, unlike the well-known Pd2X2(mu-dppm)(2) complexes (X = halide},
	keywords = {BEHAVIOR, H2S, palladium, REACTIVITY},
	isbn = {1359-7345},
	url = {<Go to ISI>://000182008200029},
	author = {Foo, S. J. L. and Jones, N. D. and Patrick, B. O. and James, Brian R.}
}
@article {407,
	title = {Homo- and heterobimetallic precursor catalysts for the Heck reaction, and a proposal for a general catalytic cooperativity index},
	journal = {Advanced Synthesis \& Catalysis},
	volume = {344},
	number = {10},
	year = {2002},
	note = {ISI Document Delivery No.: 629XZTimes Cited: 22Cited Reference Count: 58},
	month = {Dec},
	pages = {1126-1134},
	type = {Article},
	abstract = {Homo- (Pd-2) and heterobimetallic (PtPd) complexes supported by a P,P-bridging, bis(P,N-chelating) coordination mode of the potentially hexadentate ligand 1,1-bis[di(o-N,N-dimethylanilinyl)phosphino] methane (dmapm) are effective catalyst precursors for the aerobic Heck coupling of iodobenzene and styrene at 100degreesC in DMF/H2O solution containing K2CO3. This medium allows for trivial separation of the trans-stilbene product which precipitates after the reaction mixture is cooled. The bimetallic precursors are more active than predicted from the sum of the activities of complexes chosen to mimic their mono-metallic "half units," suggesting some degree of intermetallic cooperativity during the reaction. A non-linear dependence of initial rate on catalyst concentration implies, however, that the complexes do not remain intact, and may be involved in dissociative equilibria with non-dmapm containing monometallic components that are more active species for the Heck coupling. The complexes are slowly degraded by oxidation at a phosphorus centre. A general index for quantifying the degree of intermetallic cooperativity during a catalytic cycle is proposed and its utility and limitations are discussed.},
	keywords = {aerobic), ASYMMETRIC CATALYSIS, bimetallic, CHEMISTRY, cooperativity, COORDINATION, COUPLING, Heck reaction (aqueous, HIGH REGIOSELECTIVITY, homogeneous, HYDROFORMYLATION, HYDROGEN, LIGANDS, NICKEL(II) SITE, palladium, PALLADIUM(II) COMPLEXES, phosphine (anilinyl), platinum, REACTIONS, thermomorphic, VINYLIC SUBSTITUTION-REACTIONS},
	isbn = {1615-4150},
	url = {<Go to ISI>://000180078900015},
	author = {Jones, N. D. and James, Brian R.}
}
@article {539,
	title = {Microwave spectrum, geometry, and hyperfine constants of PdCO},
	journal = {Journal of Physical Chemistry A},
	volume = {106},
	number = {24},
	year = {2002},
	note = {ISI Document Delivery No.: 563BXTimes Cited: 14Cited Reference Count: 48},
	month = {Jun},
	pages = {5803-5808},
	type = {Article},
	abstract = {The pure rotational spectrum of palladium monocarbonyl. PdCO, has been measured between 6000 and 24 000 MHz using a cavity pulsed jet Fourier transform microwave spectrometer. The molecules were prepared by laser ablation of Pd in the presence of CO contained in an Ar backing gas. The spectra of 15 isotopomers have been used to determine the molecular geometry from the measured rotational constants. Centrifugal distortion constants are in good agreement with those calculated from a literature harmonic force field. A nuclear quadrupole coupling constant and nuclear spin-rotation constant have been determined for Pd-105. Nuclear shielding parameters have been evaluated from the measured spin-rotation constant. The geometry is discussed with reference to theoretical data and to other molecules containing an M-CO bond.},
	keywords = {CL, CLUSTERS, CO, MOLECULAR-STRUCTURE, MONOCARBONYLS, palladium, PURE ROTATIONAL SPECTRUM, SOLID ARGON, {BR},
	isbn = {1089-5639},
	url = {<Go to ISI>://000176235000007},
	author = {Walker, N. R. and Hui, J. K. H. and Gerry, M. C. L.}
}
@article {4929,
	title = {Regioselective halogenation and palladium-catalysed couplings on 5,15-diphenylporphyrin},
	journal = {Journal of Porphyrins and Phthalocyanines},
	volume = {4},
	number = {3},
	year = {2000},
	note = {ISI Document Delivery No.: 302BXTimes Cited: 53Cited Reference Count: 13},
	month = {Apr-May},
	pages = {228-232},
	type = {Article},
	abstract = {5,15-Diphenylporphyrin was regiospecifically halogenated in high yield to give 5-iodo-15-bromo-10.20-diphenylporphyrin, which was then subjected to Heck and Stille-type coupling reactions to form unsymmetrically substituted porphyrins. The regioselectivity of the iodination of diphenylporphyrins and subsequent formation of amphiphilic porphyrins via palladium-based methodology was also studied. The utility of this method for the synthesis of photodynamic sensitisers has been demonstrated on AR4-2J rat pancreatic carcinoma cells. Copyright (C) 2000 John Wiley \& Sons, Ltd.},
	keywords = {ALKYNYLATION, amphiphiles, CROSS-COUPLING, IODINATION, palladium, PHOTODYNAMIC THERAPY, porphyrins},
	isbn = {1088-4246},
	url = {<Go to ISI>://000086346000002},
	author = {Shanmugathasan, S. and Johnson, C. K. and Edwards, C. and Matthews, E. K. and Dolphin, D. and Boyle, R. W.}
}
@article {4579,
	title = {Coordination chemistry of the 2-pyridyldiphosphine ligands, (py)(2)P(CH(CH2)(3)CH)P(py)(2) and (py)(2)P(CH2)(2)P(py)(2) (py=2-pyridyl), with platinum(II) and ruthenium(II). Ruthenium-catalyzed hydrogenation of imines},
	journal = {Inorganic Chemistry},
	volume = {38},
	number = {18},
	year = {1999},
	note = {ISI Document Delivery No.: 235DPTimes Cited: 32Cited Reference Count: 78},
	month = {Sep},
	pages = {3956-3966},
	type = {Article},
	abstract = {{The synthesis and characterization of a range of Pt(II) and Ru(II) complexes containing the new 2-pyridyldi-phosphine ligand, d(py)pcp = (py)(2)P(CH(CH2)(3)CH)P(py)(2) (made as a racemate) and the previously reported d(py)pe = (py)(2)P(CH2)(2)P(py)(2) are given (py =2-pyridyl). The Pt complexes made were cis-PtX2(d(py)pcp) (X = Cl (1), I (2)), cis-PtX2(d(py)pe) (X = Cl (3), I (4)), [Pt(d(py)pcp)(2)][PF6](2) (5), and [Pt(d(py)pe)(2)][PF6](2) (6); these all contain P,P-bonded diphosphine ligand, as evidenced by P-31 NMR data and by crystallographic data in the case of 2 and 3. The X-ray structure of d(py)pe is also reported. The complexes RuX2(P,P,N-d(py)pcp)(PPh3) have cis-halogens and a P,P,N-bonding mode of the pyridyldiphosphine (which incorporates a four-membered P,N-chelate ring) with either a mer-arrangement (in 7a},
	keywords = {ALLYL-ELECTROPHILES, ASYMMETRIC TRANSFER HYDROGENATION, BINUCLEAR COMPLEXES, BRIDGING LIGAND, COMPLEXES, MOLECULAR-STRUCTURE, palladium, PHOSPHINE COMPLEXES, {2-PYRIDYL},
	isbn = {0020-1669},
	url = {<Go to ISI>://000082525000003},
	author = {Jones, N. D. and Macfarlane, K. S. and Smith, M. B. and Schutte, R. P. and Rettig, S. J. and James, Brian R.}
}
@article {4705,
	title = {Kinetic and mechanistic aspects of sulfur recovery from Pd2I2(mu-S)(mu-dpm)(2) using I-2 and structures of Pd(II) complexes with the chelated monosulfide of dpm},
	journal = {Inorganic Chemistry},
	volume = {38},
	number = {9},
	year = {1999},
	note = {ISI Document Delivery No.: 194LGTimes Cited: 21Cited Reference Count: 46},
	month = {May},
	pages = {2143-2149},
	type = {Article},
	abstract = {The Pd2X2(mu-S)(dpm)(2) complexes (2) (X = I, Br) react with halogens to yield PdX2(dpm) (3) and elemental sulfur. Kinetic and mechanistic studies on the X = I system in CHCl3 reveal that the reaction proceeds via addition of I-2 to give Pd2I4(dpm)(2) (4c), which then undergoes unimolecular decomposition to generate PdI2(dpm) (3c); the liberated sulfur concatenates to form elemental Ss The addition reaction is in the stopped-flow time regime and is first-order in both 2c and I-2, with Delta H-double dagger = 32 +/- 1 kJ mol-l and Delta S-double dagger = -91 +/- 3 J K-1 mol(-1). The slower decomposition reaction of 4c is first order in 4c, with Delta H-double dagger. = 80 +/- kJ mol(-1) and Delta S-double dagger = -26 +/- 3 J K-1 mol(-1). Byproduct PdX2(dpm(S)) (5) [dpm(S) = Ph2PCH2P(S)Ph-2] also forms under some conditions via reaction of 3 with an S, species (n < 8). Complexes 5 (X = Cl (a), Br (b), I(c)) were also synthesized directly, and the structure of the 5c species, as well as of [Pd(dpm(S))(2)]Cl-2, were determined by X-ray analyses that reveal the envelope configuration of the five-membered Pd-PPh2CH2P(S)Ph-2 chelate ring.},
	keywords = {bis(diphenylphosphino)methane, CONVERSION, COORDINATION CHEMISTRY, HYDROGEN-SULFIDE, LIGANDS, MAGNETIC-RESONANCE, MOLECULAR-STRUCTURES, palladium, RAY CRYSTAL-STRUCTURE, SE},
	isbn = {0020-1669},
	url = {<Go to ISI>://000080194500029},
	author = {Wong, T. Y. H. and Rettig, S. J. and James, Brian R.}
}
@article {4302,
	title = {Platinum(II)-silver(I) polymers bearing platinum(II) clusters containing chelated P,P- and bridged P, N-2-pyridylphosphine ligands},
	journal = {Journal of Cluster Science},
	volume = {9},
	number = {3},
	year = {1998},
	note = {ISI Document Delivery No.: 168QATimes Cited: 6Cited Reference Count: 32},
	month = {Sep},
	pages = {243-258},
	type = {Article},
	abstract = {Reactions of PtI2L (L = P,P-bonded 1,2-bis(2-pyridyl )phosphino)ethane, d(py)pe, or 1,2-bis((2-pyridyl)phosphino)cyclopentane, d(py)pcp) with excess AgNO3 in acetic acid/ethanol afford the polymers [Pt-2(d(py)pe)(2)Ag-4(NO3)(8) (H2O)(2)](n) (1) and [Pt-2(d(py)pcp)(2) Ag-6(NO3)(10)](n) (2), respectively, which contain Pt2L24+ cores with each L ligand now P,N-bridging two Pt-atoms; these Pt-2 cores are connected via bridging AgNO3 clusters, the Ag being bound to the pyridyl-N or nitrate-O atoms. X-ray crystallographic data reveal Pt-Pt contacts of similar to 2.76 Angstrom indicative of bonding.},
	keywords = {2-PYRIDYL, 2-PYRIDYLPHOSPHINE LIGANDS, =, cation, COMPLEXES, CRYSTAL-STRUCTURE, DIMER, METAL-METAL BOND, OXIDATION, palladium, platinum, pyridylphosphine, silver, SPECTROSCOPY, TETRAKIS(DITHIOACETATO)DIPLATINUM(II)},
	isbn = {1040-7278},
	url = {<Go to ISI>://000078702700004},
	author = {Jones, N. D. and Rettig, S. J. and James, Brian R.}
}
@article {4061,
	title = {The structure of the Pd(111)-(root 7x root 7)R19.1 degrees-S surface: comparison with the corresponding P/Rh(111) surface},
	journal = {Surface Science},
	volume = {393},
	number = {1-3},
	year = {1997},
	note = {ISI Document Delivery No.: YP959Times Cited: 15Cited Reference Count: 35},
	month = {Dec},
	pages = {L119-L125},
	type = {Letter},
	abstract = {The structure of the Pd(lll)-(root 7 x root 7)R19.1<degrees-S surface has been determined by low-energy electron diffraction and has been shown to involve a reconstructed topmost metal layer based on a packed arrangement of Pd pentagons and triangles, with S atoms at 3/7 monolayer coverage occupying eight-coordinate sites at the centre of each Pd pentagon. Comparisons are made with the structure recently determined for the corresponding P/Rh(lll) system. In both cases, the atomic density in the reconstructed layer increases to five metal atoms and three chemisorbed atoms for every seven atoms in the regular metal surface. Some details are closely similar between the two systems, but an intriguing difference is also indicated. In S/Pd(lll), four metal atoms in each pentagonal ring appear close to hcp-type three-fold sites, while the other is close to a fee-type three-fold site. This contrasts with the situation for the topmost layer of the P/Rh(lll) system, for which the reversed lateral registry has been reported (i.e. the atoms of each pentagonal ring occupy three-fold sites where four are of the fee type and one of the hcp type). (C) 1997 Elsevier Science B.V.},
	keywords = {ADSORBATE STRUCTURE, ARRANGEMENT, chemisorption, CRYSTAL SURFACES, CRYSTALLOGRAPHY, ENERGY-ELECTRON-DIFFRACTION, LEED INTENSITY ANALYSIS, low energy electron diffraction crystallography, LOW INDEX SINGLE, METAL-SURFACES, palladium, PD(111) SURFACE, RECONSTRUCTION, SULFUR, sulphur, surface structure},
	isbn = {0039-6028},
	url = {<Go to ISI>://000071333200009},
	author = {Liu, W. and Mitchell, K. A. R. and Berndt, W.}
}
@article {3843,
	title = {Synthesis, molecular structure, and vibrational spectra of mer-tris(carbonyl)iridium(III)fluorosulfate, mer-Ir(CO)(3)(SO3F)(3)},
	journal = {Inorganic Chemistry},
	volume = {35},
	number = {5},
	year = {1996},
	note = {ISI Document Delivery No.: TY260Times Cited: 21Cited Reference Count: 36},
	month = {Feb},
	pages = {1279-1285},
	type = {Article},
	abstract = {{Addition of carbon monoxide (0.5-2 atm) to iridium(III) fluorosulfate, Ir(SO3F)(3), dissolved in HSO3F over 4 days and at 60 degrees C, results in the quantitative formation of tris(carbonyl)iridium(III) fluorosulfate Ir(CO)(3)(SO3F)(3) Slow evaporation of the solvent produces single crystals of mer-Ir(CO)(3)(SO3F)(3). Crystal structure data for mer-Ir(CO)(3)(SO3F)(3): monoclinic, space group P2(1)/c},
	keywords = {DERIVATIVES, FLUOROSULFATES, GOLD, palladium, SYSTEM, UNDECAFLUORODIANTIMONATE(V)},
	isbn = {0020-1669},
	url = {<Go to ISI>://A1996TY26000029},
	author = {Wang, C. Q. and Lewis, A. R. and Batchelor, R. J. and Einstein, F. W. B. and Willner, H. and Aubke, F.}
}
@article {3235,
	title = {NICKEL(II) AND NICKEL(0) COMPLEXES CONTAINING 2-PYRIDYLPHOSPHINE LIGANDS, INCLUDING WATER-SOLUBLE SPECIES},
	journal = {Inorganica Chimica Acta},
	volume = {235},
	number = {1-2},
	year = {1995},
	note = {ISI Document Delivery No.: RP069Times Cited: 27Cited Reference Count: 33},
	month = {Jul},
	pages = {291-297},
	type = {Article},
	abstract = {{The paramagnetic},
	keywords = {2-PYRIDYLPHOSPHINE COMPLEXES, ANTITUMOR-ACTIVITY, MONONUCLEAR, NICKEL(0) COMPLEXES, NICKEL(II) COMPLEXES, palladium, phosphine, RHODIUM(I)},
	isbn = {0020-1693},
	url = {<Go to ISI>://A1995RP06900034},
	author = {Baird, I. R. and Smith, M. B. and James, Brian R.}
}
@article {3430,
	title = {A NOVEL SURFACE-STRUCTURE - RH(111)-(ROOT-7X-ROOT-7)R19.1-DEGREES-P},
	journal = {Journal of the American Chemical Society},
	volume = {117},
	number = {49},
	year = {1995},
	note = {ISI Document Delivery No.: TK382Times Cited: 7Cited Reference Count: 26},
	month = {Dec},
	pages = {12344-12345},
	type = {Note},
	keywords = {acetylene, chemisorption, CYCLOTRIMERIZATION, ENERGY-ELECTRON-DIFFRACTION, HETEROCYCLIZATION SITES, INTERMEDIATE, MOLECULAR PATHWAYS, palladium, SUBSTRATE, SULFIDED PD(111) SURFACE},
	isbn = {0002-7863},
	url = {<Go to ISI>://A1995TK38200041},
	author = {Liu, W. and Wong, K. C. and Mitchell, K. A. R.}
}
@article {3264,
	title = {THE ONE-STEP SYNTHESIS OF CHIRAL AMINO PHOSPHINO FERROCENES},
	journal = {Journal of Organometallic Chemistry},
	volume = {492},
	number = {2},
	year = {1995},
	note = {ISI Document Delivery No.: QV350Times Cited: 10Cited Reference Count: 24},
	month = {May},
	pages = {157-164},
	type = {Article},
	abstract = {Reaction of the chiral lithium reagent-2-lithio-(alpha-N,N-dimethyl)aminoethylbenzene with 1,1{\textquoteright}-ferrocenediylphenylphosphine gives chiral aminophosphinoferrocenes that contain both chiral carbon and phosphorus centres. Treatment of the ferroceno-phane with 2-lithio-N,N-dimethylaminomethylferrocene followed by hydrolysis gives the product ferrocenyl 2-(dimethylaminomethylferrocenyl) phenylphosphine as a pair of diastereomers. The single crystal structures of compound 3a PdCl2 and compound 4. PdCl2.2CH(2)Cl(2) have been determined. The compounds, 2-(ferrocenylphenylphosphino)-1-(alpha-N, N{\textquoteright}-dimethylaminoethylbenzene)ferrocene, 5 and 1-[2-(alpha-N,N{\textquoteright}-dimethyraminoethylbenzene)phenylphospphino]-1{\textquoteright}-diphenyl phosphinoferrocene, 6a, have also been prepared by minor modifications of the methodology developed.},
	keywords = {<1>FERROCENOPHANES, ASYMMETRIC-SYNTHESIS, CATALYST, chirality, crystal structure, FERROCENE, GRIGNARD, HALIDES, HYDROGENATION, iron, METAL-COMPLEXES, ORGANIC, palladium, PHOSPHORUS, PLANAR CHIRALITY, REAGENTS, SECONDARY},
	isbn = {0022-328X},
	url = {<Go to ISI>://A1995QV35000005},
	author = {Butler, I. R. and Cullen, W. R. and Rettig, S. J. and White, A. S. C.}
}
@article {3188,
	title = {SYNTHESIS, MOLECULAR-STRUCTURE, AND VIBRATIONAL-SPECTRA OF CYCLO-BIS(MU-CARBONYL)DIPALLADIUM(I) FLUOROSULFATE, [C-PD2(MU-CO)2](SO3F)2},
	journal = {Inorganic Chemistry},
	volume = {33},
	number = {4},
	year = {1994},
	note = {ISI Document Delivery No.: MX860Times Cited: 32Cited Reference Count: 55},
	month = {Feb},
	pages = {779-786},
	type = {Article},
	abstract = {{The synthesis, molecular structure, and complete vibrational spectrum of cyclo-bis(mu-carbonyl)dipalladium(I) fluorosulfate, [c-Pd2(mu-CO)2] (SO3F)2, are reported. The synthesis is achieved by reductive decomposition of Pd-(CO)2(SO3F)2 in fluorosulfuric acid, HSO3F; at 25-degrees-C, long orange-red needles form over a period of about 3 weeks. The compound is stable up to 157-degrees-C (the decomposition point). The molecular structure is solved by single-crystal X-ray diffraction. Crystals of [Pd2(mu-CO)2](SO3F)2 are monoclinic, C2/c; a = 11.495(1)},
	keywords = {CARBONYL HALIDES, COMPLEXES, CRYSTAL-STRUCTURE, palladium},
	isbn = {0020-1669},
	url = {<Go to ISI>://A1994MX86000026},
	author = {Wang, C. Q. and Bodenbinder, M. and Willner, H. and Rettig, S. and Trotter, J. and Aubke, F.}
}
@article {3188,
	title = {SYNTHESIS, MOLECULAR-STRUCTURE, AND VIBRATIONAL-SPECTRA OF CYCLO-BIS(MU-CARBONYL)DIPALLADIUM(I) FLUOROSULFATE, [C-PD2(MU-CO)2](SO3F)2},
	journal = {Inorganic Chemistry},
	volume = {33},
	number = {4},
	year = {1994},
	note = {ISI Document Delivery No.: MX860Times Cited: 32Cited Reference Count: 55},
	month = {Feb},
	pages = {779-786},
	type = {Article},
	abstract = {{The synthesis, molecular structure, and complete vibrational spectrum of cyclo-bis(mu-carbonyl)dipalladium(I) fluorosulfate, [c-Pd2(mu-CO)2] (SO3F)2, are reported. The synthesis is achieved by reductive decomposition of Pd-(CO)2(SO3F)2 in fluorosulfuric acid, HSO3F; at 25-degrees-C, long orange-red needles form over a period of about 3 weeks. The compound is stable up to 157-degrees-C (the decomposition point). The molecular structure is solved by single-crystal X-ray diffraction. Crystals of [Pd2(mu-CO)2](SO3F)2 are monoclinic, C2/c; a = 11.495(1)},
	keywords = {CARBONYL HALIDES, COMPLEXES, CRYSTAL-STRUCTURE, palladium},
	isbn = {0020-1669},
	url = {<Go to ISI>://A1994MX86000026},
	author = {Wang, C. Q. and Bodenbinder, M. and Willner, H. and Rettig, S. and Trotter, J. and Aubke, F.}
}
@article {7258,
	title = {GENERATION OF AU2+ IONS IN THE SOLID-STATE OR IN FLUOROSULFURIC ACID-SOLUTION AND THEIR IDENTIFICATION BY ESR},
	journal = {Journal of the American Chemical Society},
	volume = {114},
	number = {4},
	year = {1992},
	note = {ISI Document Delivery No.: HD978Times Cited: 25Cited Reference Count: 64},
	month = {Feb},
	pages = {1271-1277},
	type = {Article},
	abstract = {{The partial pyrolysis of gold(III) fluorosulfate, Au(SO3F)3, at temperatures below 145-degrees-C allows the generation of Au2+ defects in the solid residue by reductive elimination of SO3F. radicals. Solvated Au2+ is obtained by the reduction of Au(SO3F)3 in HSO3F solution by gold powder at 65-degrees-C. Both systems are studied by ESR and identical high g(iso) values of g = 2.360 are found. Hyperfine splitting due to Au-197},
	keywords = {BR2+, bromine, CATIONS, COMPLEX, GOLD(III) FLUOROSULFATE, HSO3F, I2+, palladium, SILVER(II)},
	isbn = {0002-7863},
	url = {<Go to ISI>://A1992HD97800024},
	author = {Herring, F. G. and Hwang, G. and Lee, K. C. and Mistry, F. and Phillips, P. S. and Willner, H. and Aubke, F.}
}
@article {7253,
	title = {MOLECULAR DIHYDROGEN AND HYDRIDO DERIVATIVES OF RUTHENIUM(II) COMPLEXES CONTAINING CHELATING FERROCENYL-BASED TERTIARY PHOSPHINE AMINE LIGANDS AND OR MONODENTATE TERTIARY PHOSPHINE-LIGANDS},
	journal = {Inorganic Chemistry},
	volume = {31},
	number = {26},
	year = {1992},
	note = {ISI Document Delivery No.: KE754Times Cited: 34Cited Reference Count: 60},
	month = {Dec},
	pages = {5509-5520},
	type = {Article},
	abstract = {{Reactions of complexes of the type RuCl2(PPh3)(P-N) with H2 are reported, where P-N represents the chelating ferrocene-based ligands (eta-C5H5)Fe(etaC5H3(CHMeNMe2)PR2-1,2) with R = i-Pr (the isoPFA ligand) or Ph (the PPFA ligand). Depending on the solvent(s) used, and absence or presence of added base, RuCl2(PPh3)(isoPFA) (2b) generates the dinuclear eta2-H2 complexes L2(eta2-H2)Ru(eta-Cl)2(eta-H)Ru(H)(PPh3)2 where L2 = isoPFA (complex 3) or L2 = (PPh3)2 (complex 4). n-Butanol solutions of RuCl2(PPh3)(PPFA) (2a) under H-2 also yield 4, as well as Ru(H)Cl2(PPh3)(PPFA.H)(BuOH), a zwitterionic species containing a protonated amine moiety stabilized by coordinated n-BuOH, which is a likely intermediate in heterolytic cleavage of the H-2: the complex RuH(Cl)-PPh3)(isoPFA) (5), together with a hydrido carbonyl species, is isolated from methanol solutions of 2b. Complexes 2b, 3, 4, and 5 are characterized by X-ray crystallography; the mononuclear complexes 2b and 5 are orthorhombic with space groups F2dd and P2(2)2(1)2(1), respectively. For 2b},
	keywords = {BOND, CARBONYL, D6 COMPLEXES, ETA-2-DIHYDROGEN, EXCHANGE, H-H, HYDROGEN COMPLEXES, palladium, REACTIVITY, TRANSITION-METALS},
	isbn = {0020-1669},
	url = {<Go to ISI>://A1992KE75400029},
	author = {Hampton, Crsm and Butler, I. R. and Cullen, W. R. and James, Brian R. and Charland, J. P. and Simpson, J.}
}
@article {7147,
	title = {FLUOROSULFATE DERIVATIVES OF DIVALENT GOLD},
	journal = {Journal of Fluorine Chemistry},
	volume = {52},
	number = {1},
	year = {1991},
	note = {ISI Document Delivery No.: FL539Times Cited: 8Cited Reference Count: 34},
	month = {Apr},
	pages = {13-27},
	type = {Article},
	abstract = {The reduction of gold(III) fluorosulfate, Au(SO3F)3 with either gold powder or carbon monoxide, in fluorosulfuric acid, HSO3F, yields gold(II) fluorosulfate as a yellow-red solid in high yield. Based on magnetic measurements and vibrational spectra, formulation as mixed valency Au(I) Au(III)-(SO3F)4 is suggested. Evidence from ESR measurements for a solvated, paramagnetic Au(II)-species in the supernatant solution is obtained and discussed.},
	keywords = {GOLD(III) FLUOROSULFATE, ION, palladium, SILVER(II), SPECTRA},
	isbn = {0022-1139},
	url = {<Go to ISI>://A1991FL53900003},
	author = {Willner, H. and Mistry, F. and Hwang, G. and Herring, F. G. and Cader, M. S. R. and Aubke, F.}
}
@article {7152,
	title = {SYNTHESIS AND CHEMISTRY OF 2-PYRIDYL(PHOSPHINE) COMPLEXES OF PLATINUM(0)},
	journal = {Journal of Organometallic Chemistry},
	volume = {417},
	number = {1-2},
	year = {1991},
	note = {ISI Document Delivery No.: GL228Times Cited: 23Cited Reference Count: 39},
	month = {Oct},
	pages = {277-288},
	type = {Article},
	abstract = {The complexes tetrakis[tri(2-pyridyl)phosphine]platinum(0), 1, and tris[2-(diphenylphosphino)pyridine]platinum(0), 2, are synthesized, and characterized by P-31{H-1} and Pt-195{H-1} NMR spectroscopy. The reactions of 1 and 2 with olefins (ethylene, maleic anhydride, diethyl maleate, and olefinic nitriles) are studied and some square-planar Pt(PR3)2(eta-2-olefin) species isolated (PR3 = the pyridylphosphine). No olefin hydration products are observed on heating the olefin complexes in aqueous solution. Oxidative addition of MeI to 1 and to 2 gives the trans-PtI(Me)(PR3)2 species. However, the trans-Pt(H)Cl(PR3)2 species is isolated only from reaction of 2 with gaseous HCl; the hydride reacts with acrylonitrile to form cis-PtCl(CH2CH2CN)(PR3)2.},
	keywords = {2-(DIPHENYLPHOSPHINO)PYRIDINE, BINUCLEAR COMPLEXES, BRIDGING, CATALYSIS, hydration, LIGAND, MOLECULAR-STRUCTURE, palladium, PHOSPHINE COMPLEXES, RHODIUM(I), RUTHENIUM(II)},
	isbn = {0022-328X},
	url = {<Go to ISI>://A1991GL22800024},
	author = {Xie, Y. and James, Brian R.}
}
