@article {EJIC:EJIC201501305,
	title = {Enhancing Reactivity of Directly {\'\i}Observable B{\textendash}H{\textendash}Pt Interactions through Conformational Rigidity},
	journal = {European Journal of Inorganic Chemistry},
	volume = {2016},
	number = {15-16},
	year = {2016},
	pages = {2403{\textendash}2408},
	abstract = {We report for the first time the direct syntheses of trimethylplatinum(IV) complexes supported by bis(pyrazolyl)dihydridoborate (Bp) and bis(3,5-dimethylpyrazolyl)dihydridoborate (Bp*) ligands from the corresponding dimethylplatinum(II) complexes. X-ray crystallographic and multinuclear NMR characterization of the trimethylplatinum(IV) complexes reveal agostic B{\textendash}H{\textendash}Pt interactions. Solid-state analysis reveals that BpPtIVMe3 adopts a dinuclear structure featuring an intermolecular B{\textendash}H{\textendash}Pt bridge, whereas Bp*PtIVMe3 adopts a mononuclear structure containing an intramolecular B{\textendash}H{\textendash}Pt bridge. Addition of acetonitrile leads to cleavage of the weakly coordinating B{\textendash}H{\textendash}Pt interactions, and in the case of Bp*PtIVMe3, leads to hydroboration of acetonitrile. The B{\textendash}H fragment interacting with the PtIV center in Bp*PtIVMe3 was also found to react with methanol to form a methoxy-bridged complex. DFT calculations were employed to investigate the structural contributions to the difference in the reactivity of the Bp- and Bp*-supported complexes.},
	keywords = {Agostic interactions, B{\textendash}H functionalization, platinum, Scorpionate ligands},
	issn = {1099-0682},
	doi = {10.1002/ejic.201501305},
	url = {http://dx.doi.org/10.1002/ejic.201501305},
	author = {Pal, Shrinwantu and Drover, Marcus W. and Patrick, Brian O. and Love, Jennifer A.}
}
@article {Fan2009Pt,
	title = {$\beta$-NMR of a thin Pt film},
	journal = {Physica B: Condensed Matter},
	volume = {404},
	number = {5{\textendash}7},
	year = {2009},
	note = {Proceedings of the Eleventh International Conference on Muon Spin Rotation, Relaxation and Resonance},
	pages = {906 - 909},
	abstract = {We report beta-detected \{NMR\} ( β -NMR) measurements on a 50 nm thick platinum (Pt) film grown on a magnesium oxide (MgO) substrate. The frequency of the β -NMR resonance in Pt was compared to the MgO reference frequency to estimate the Knight shift at various temperatures (100{\textendash}300\&$\#$xa0;K). The Knight shift was found to be negative and strongly temperature dependent. The implications are discussed and compared to other transition metals that have been studied via β -NMR previously.},
	keywords = {platinum},
	issn = {0921-4526},
	doi = {http://dx.doi.org/10.1016/j.physb.2008.11.139},
	url = {http://www.sciencedirect.com/science/article/pii/S0921452608007035},
	author = {I. Fan and K.H. Chow and T.J. Parolin and M. Egilmez and M.D. Hossain and J. Jung and T.A. Keeler and R.F. Kiefl and S.R. Kreitzman and C.D.P. Levy and R. Ma and G.D. Morris and M.R. Pearson and H. Saadaoui and Z. Salman and M. Smadella and Q. Song and D. Wang and M. Xu and W.A. MacFarlane}
}
@article {2677,
	title = {Chemistry of Single-Walled Carbon Nanotubes},
	journal = {J. Comput. Theor. Nanosci.},
	volume = {6},
	number = {6},
	year = {2009},
	note = {ISI Document Delivery No.: 441BUTimes Cited: 0Cited Reference Count: 146Yeung, Charles See Tian, Wei Quart Liu, Lei Vincent Wang, Yan AlexanderSp. Iss. SI},
	month = {Jun},
	pages = {1213-1235},
	type = {Review},
	abstract = {<p>Single-walled carbon nanotubes (SWCNTs) have received significant attention from the scientific community over the past 15 years. Of particular interest is the potential of these macromolecules for use in molecular electronics, chemical sensory technology, nanobiology, and transition metal catalysis, For effective applications, the selective functionalization of the aforementioned all-carbon framework is necessary but has been met with considerable challenges. Herein, we review our approach to the exploration of structural and electronic properties of SWCNTs within density functional theory (DFT). Our investigations include mechanistic studies on chemical reactions of SWCNTs with defect and exploration of transition metal doped variants and their ability to adsorb small gas molecules.</p>},
	keywords = {AB-INITIO, Defect, DOPED CARBON, ELECTRICAL-CONDUCTIVITY, ELECTROCHEMICALLY DEPOSITED FILMS, Electronic Structure, Gas Adsorption, GAUSSIAN-TYPE BASIS, GENERALIZED GRADIENT APPROXIMATION, LASER-ABLATION, MOLECULAR-ORBITAL METHODS, NANORODS, NITRIC-OXIDE, Nitrogen Monoxide, platinum, SIDEWALL FUNCTIONALIZATION, Single-Walled Carbon Nanotubes},
	isbn = {1546-1955},
	url = {<Go to ISI>://000265745100002},
	author = {Yeung, C. S. and Tian, W. Q. and Liu, L. V. and Y. A. Wang*}
}
@article {2499,
	title = {Surface-enhanced IR-visible sum frequency generation vibrational spectroscopy},
	journal = {Physical Chemistry Chemical Physics},
	volume = {11},
	number = {18},
	year = {2009},
	note = {ISI Document Delivery No.: 436KPTimes Cited: 2Cited Reference Count: 79Li, Qifeng Kuo, Chiung Wen Yang, Zheng Chen, Peilin Chou, Keng C.},
	pages = {3436-3442},
	type = {Article},
	abstract = {Surface-enhanced IR-visible sum frequency generation (SFG) was studied using Ag and Au films over nanospheres (AgFON and AuFON), which provided large area of reproducible nanoscale structures with well-defined morphology. SFG vibrational spectra for a self-assembled monolayer of octadecanethiol were investigated on spheres with diameters ranging from 300 nm to 620 nm. With an input wavelength of 532 nm, a sphere diameter near 360 nm produced the maximum enhancement, which was consistent with the localized surface-plasmon resonant wavelength identified by minimum reflectivity. The measured second-order susceptibility for the asymmetric CH3 stretch mode of octadecanethiol was enhanced by up to 27 times on AgFON, which corresponded to an SFG enhancement factor of similar to 730. The SFG enhancement factor for AuFON was a quarter of that from AgFON. The SFG enhancement factor for the symmetric CH3 mode was about 10 times smaller than that for the asymmetric CH3 mode. This difference can be explained by the highly directional electrical-field parallel to the surface, created at the junction between nanospheres. Polarization-dependent studies also indicated that excitations with the electrical field parallel to the surface was the main contribution to the observed surface enhancements, and the electrical field perpendicular to the surface offered little enhancement.},
	keywords = {2ND-HARMONIC GENERATION, METAL NANOPARTICLES, NANOPARTICLES, NANOSPHERE, platinum, RAMAN-SCATTERING SERS, RHODAMINE 6G MOLECULES, SELF-ASSEMBLED MONOLAYERS, SILVER ELECTRODE, SPECTRA, SUPPORTED PD NANOPARTICLES, SURFACES, TOTAL-REFLECTION},
	isbn = {1463-9076},
	url = {<Go to ISI>://000265413300011},
	author = {Li, Q. F. and Kuo, C. W. and Yang, Z. and Chen, P. L. and Chou, K. C.}
}
@article {2130,
	title = {Total synthesis of (+)-fawcettidine},
	journal = {Angewandte Chemie-International Edition},
	volume = {47},
	number = {22},
	year = {2008},
	note = {ISI Document Delivery No.: 306QCTimes Cited: 22Cited Reference Count: 31Kozak, Jennifer A. Dake, Gregory R.},
	pages = {4221-4223},
	type = {Article},
	keywords = {ALKALOIDS, CATALYSIS, FAWCETTIMINE, GOLD, homogeneous catalysis, LYCOPODIUM ALKALOIDS, platinum, total synthesis},
	isbn = {1433-7851},
	url = {<Go to ISI>://000256261900037},
	author = {Kozak, J. A. and Dake, G. R.}
}
@article {1147,
	title = {Calorimetric study on self-assembling of two kinds of monometallic nanoparticles in solution},
	journal = {Journal of Thermal Analysis and Calorimetry},
	volume = {81},
	number = {3},
	year = {2005},
	note = {ISI Document Delivery No.: 962VGTimes Cited: 4Cited Reference Count: 233rd International Symposium on New Frontiers of Thermal Studies of MaterialsNOV 28-30, 2004Tsukuba, JAPANJSCTA, Univ Tsukuba, Grad Sch Pure \& Appl Sci, Soc Promot Calorimetry \& Thermal Anal, Ibaraki, Sci \& Technol Promot Fdn},
	month = {Aug},
	pages = {523-527},
	type = {Proceedings Paper},
	abstract = {Recently, we have reported a noble method of preparing Ag/Rh bimetallic nanoparticles with a pseudo-core/shell structure. We simply mix the dispersions of poly(N-vinyl-2-pyrrolidone)(PVP)-protected Ag and Rh nanoparticles in solution at room temperature. We found that the mixture of dispersions forms bimetallic nanoparticles in a pseudo-core/shell structure on standing. We call this process the {\textquoteright}self-assembling{\textquoteright} or {\textquoteright}self-organizing{\textquoteright}. In this study we seek for a thermodynamic driving force for this process by determining the enthalpy of the interaction among three pairs of nanoparticles by isothermal titration calorimetry (ITC). The results indicate that the interaction between each pair is strongly exothermic, and that among the pairs studied here the strength of the exothermic interaction is in the order of Ag/Pt<Ag/Pd<Ag/Rh.},
	keywords = {bimetallic nanoparticles, calorimetric method, CATALYTIC-ACTIVITY, CLUSTERS, CORE-SHELL NANOPARTICLES, core/shell structure, GROWTH, isothermal titration calorimetry, metal nanoparticle, NUCLEATION, palladium, PD, platinum, REDUCTION, rhodium, self-assembling, SELF-ORGANIZATION, silver, STRUCTURAL-ANALYSIS},
	isbn = {1388-6150},
	url = {<Go to ISI>://000231760500004},
	author = {Kanemaru, M. and Shiraishi, Y. and Koga,Yoshikata and Toshima, N.}
}
@article {876,
	title = {Pt(II) or Ag(I) salt catalyzed cycloisomerizations and tandem cycloadditions forming functionalized azacyclic arrays},
	journal = {Organic Letters},
	volume = {6},
	number = {26},
	year = {2004},
	note = {ISI Document Delivery No.: 880TNTimes Cited: 47Cited Reference Count: 41},
	month = {Dec},
	pages = {5023-5026},
	type = {Article},
	abstract = {Cyclic ene-N-p-toluenesulfonamides tethered to an electron-deficient alkyne undergo cycloisomerizations readily under the influence of catalytic Pt(II) salts (PtCl2 or [dppbPtmu-OH](2)(BF4)(2)) or AgOTf. Yields for this process range from 47\% to 99\%. The resulting functionalized 2-azahydrindans can be reacted further using the Diels-Alder reaction. Tandem cycloisomerization-cycloaddition reactions in one pot generate highly functionalized 1-azadecalin ring systems in a highly stereocontrolled manner.},
	keywords = {COMPLEXES, cyclizations, ENAMIDES, ENANTIOSELECTIVE REACTIONS, ENYNES, ORGANIC-SYNTHESIS, palladium, platinum, REORGANIZATION, SKELETAL, STEREOCONTROLLED TOTAL-SYNTHESIS},
	isbn = {1523-7060},
	url = {<Go to ISI>://000225812300057},
	author = {Harrison, T. J. and Dake, G. R.}
}
@article {407,
	title = {Homo- and heterobimetallic precursor catalysts for the Heck reaction, and a proposal for a general catalytic cooperativity index},
	journal = {Advanced Synthesis \& Catalysis},
	volume = {344},
	number = {10},
	year = {2002},
	note = {ISI Document Delivery No.: 629XZTimes Cited: 22Cited Reference Count: 58},
	month = {Dec},
	pages = {1126-1134},
	type = {Article},
	abstract = {Homo- (Pd-2) and heterobimetallic (PtPd) complexes supported by a P,P-bridging, bis(P,N-chelating) coordination mode of the potentially hexadentate ligand 1,1-bis[di(o-N,N-dimethylanilinyl)phosphino] methane (dmapm) are effective catalyst precursors for the aerobic Heck coupling of iodobenzene and styrene at 100degreesC in DMF/H2O solution containing K2CO3. This medium allows for trivial separation of the trans-stilbene product which precipitates after the reaction mixture is cooled. The bimetallic precursors are more active than predicted from the sum of the activities of complexes chosen to mimic their mono-metallic "half units," suggesting some degree of intermetallic cooperativity during the reaction. A non-linear dependence of initial rate on catalyst concentration implies, however, that the complexes do not remain intact, and may be involved in dissociative equilibria with non-dmapm containing monometallic components that are more active species for the Heck coupling. The complexes are slowly degraded by oxidation at a phosphorus centre. A general index for quantifying the degree of intermetallic cooperativity during a catalytic cycle is proposed and its utility and limitations are discussed.},
	keywords = {aerobic), ASYMMETRIC CATALYSIS, bimetallic, CHEMISTRY, cooperativity, COORDINATION, COUPLING, Heck reaction (aqueous, HIGH REGIOSELECTIVITY, homogeneous, HYDROFORMYLATION, HYDROGEN, LIGANDS, NICKEL(II) SITE, palladium, PALLADIUM(II) COMPLEXES, phosphine (anilinyl), platinum, REACTIONS, thermomorphic, VINYLIC SUBSTITUTION-REACTIONS},
	isbn = {1615-4150},
	url = {<Go to ISI>://000180078900015},
	author = {Jones, N. D. and James, Brian R.}
}
@article {5117,
	title = {Tensor LEED analysis for the electrodeposited Pt(111)-(3x3)-Ag,I surface structure},
	journal = {Surface Science},
	volume = {490},
	number = {3},
	year = {2001},
	note = {ISI Document Delivery No.: 473XWTimes Cited: 5Cited Reference Count: 34},
	month = {Sep},
	pages = {256-264},
	type = {Article},
	abstract = {A crystallographic analysis is reported using low-energy electron diffraction (LEED) in the tensor LEED approach for the electrodeposited coadsorption (3 x 3) structure with 4/9 monolayer (ML) of silver and 4/9 ML of iodine on the Pt(1 1 1) surface. The structure approximates a two-layer slice of bulk AgI cut parallel to its (1 1 1) plane and superimposed on the substrate with the Ag atoms in contact with the topmost Pt(1 1 1) layer, and the I atoms forming an overlayer on the Ag atoms. There are two types of Ag atoms in the (3 x 3) unit mesh; one type bonds to a single Pt atom, while the other type bonds to three Pt atoms. The average Ag-Pt bond distances are close to 2.48 and 2.82 (A) over circle respectively for the one and three-coordinate Ag atoms, but both types of Ag atoms bond to three I atoms with an average Ag-I distance of 2.67 (A) over circle. No significant corrugation is observed for either the I layer or the Ag layer. (C) 2001 Elsevier Science B.V. All rights reserved.},
	keywords = {ADSORBATES, ADSORPTION, AG, chemisorption, ELECTROCHEMISTRY, ENERGY-ELECTRON-DIFFRACTION, IODINE, LOW ENERGY ELECTRON DIFFRACTION (LEED), METAL-SURFACES, platinum, PT(111), SCANNING-TUNNELING-MICROSCOPY, silver},
	isbn = {0039-6028},
	url = {<Go to ISI>://000171075300007},
	author = {Labayen, M. and Harrington, D. A. and Saidy, M. and Mitchell, K. A. R.}
}
@article {4962,
	title = {Bis(carbonyl)platinum(II) derivatives: Molecular structure of cis-Pt(CO)(2)(SO3F)(2), complete vibrational analysis of cis-Pt(CO)(2)Cl-2, and attempted synthesis of cis-Pt(CO)(2)F-2},
	journal = {Inorganic Chemistry},
	volume = {39},
	number = {20},
	year = {2000},
	note = {ISI Document Delivery No.: 361DNTimes Cited: 12Cited Reference Count: 91},
	month = {Oct},
	pages = {4424-4432},
	type = {Article},
	abstract = {{As part of a comprehensive study of square planar palladium(II) and platinum(II) carbonyl derivatives, the molecular structure of cis-Pt(CO)(2)(SO3F)(2), the complete vibrational spectra of cis-Pt(CO)(2)Cl-2 and the attempted synthesis of cis-Pt(CO)(2)F-2 an reported. cis-Pt(CO)(2)(SO3F)(2) is isostructural with cis-Pd(CO) (2)(SO3F)(2) and crystallizes in the monoclinic space group P2(1)/n (no. 14). Crystal data: a = 7.419(1) Angstrom; b = 14.751(2) Angstrom; c 8.634(1) Angstrom; beta = 89.95(1)degrees; V = 934.9(2) Angstrom(3); Z = 4; T = 300 K; R [F-o > 4 sigma(F-o)] = 0.0447 and wR2 = 0.1097. The internal bond parameters of the cis-Pt(CO)(2)(SO3F)(2) are compared to those of cis-Pd(CO)(2)(SO3F)(2), cis-Pt(CO)(2)Cl-2, and [M(CO)(4)](2+)},
	keywords = {CARBONYL-COMPLEXES, CRYSTAL-STRUCTURE, FLUOROSULFATE, HALIDE LIGANDS, INORGANIC, LATE TRANSITION-ELEMENTS, NOBLE-METALS, OLIGOMERS, platinum, SPECTRA, UNDECAFLUORODIANTIMONATE(V)},
	isbn = {0020-1669},
	url = {<Go to ISI>://000089707500008},
	author = {von Ahsen, B. and Wartchow, R. and Willner, H. and Jonas, V. and Aubke, F.}
}
@article {4961,
	title = {{The reactions of the third transition series metal hexafluorides, MF6},
	journal = {Journal of Fluorine Chemistry},
	volume = {102},
	number = {1-2},
	year = {2000},
	note = {ISI Document Delivery No.: 302YMTimes Cited: 8Cited Reference Count: 77},
	month = {Mar},
	pages = {243-252},
	type = {Article},
	abstract = {{The reactions of the third transition (5d) series metal hexafluorides PtF6, IrF6, OsF6, ReF6 and WF6 with CO are studied in the Lewis superacid SbF5, the Bronsted superacid HF and the conjugate Bronsted-Lewis superacid HF-SbF5, in order to evaluate their potential as reactants in reductive carbonylations. These reactions are aimed at the generation of homoleptic metal carbonyl cations of the type [M(CO)(n)](m+)},
	keywords = {<IR(CO)(6)>(3+), carbonyl fluoride, CO, FLUOROSULFATES, HEXACARBONYLS, homoleptic carbonyl complexes, INCLUDING STEREOISOMERS, metal hexafluorides, MOLECULAR-STRUCTURE, NOBLE-METALS, PALLADIUM(II), platinum, superacid, UNDECAFLUORODIANTIMONATE(V), VIBRATIONAL-SPECTRA},
	isbn = {0022-1139},
	url = {<Go to ISI>://000086394100033},
	author = {von Ahsen, B. and Bach, C. and Pernice, H. and Willner, H. and Aubke, F.}
}
@article {4302,
	title = {Platinum(II)-silver(I) polymers bearing platinum(II) clusters containing chelated P,P- and bridged P, N-2-pyridylphosphine ligands},
	journal = {Journal of Cluster Science},
	volume = {9},
	number = {3},
	year = {1998},
	note = {ISI Document Delivery No.: 168QATimes Cited: 6Cited Reference Count: 32},
	month = {Sep},
	pages = {243-258},
	type = {Article},
	abstract = {Reactions of PtI2L (L = P,P-bonded 1,2-bis(2-pyridyl )phosphino)ethane, d(py)pe, or 1,2-bis((2-pyridyl)phosphino)cyclopentane, d(py)pcp) with excess AgNO3 in acetic acid/ethanol afford the polymers [Pt-2(d(py)pe)(2)Ag-4(NO3)(8) (H2O)(2)](n) (1) and [Pt-2(d(py)pcp)(2) Ag-6(NO3)(10)](n) (2), respectively, which contain Pt2L24+ cores with each L ligand now P,N-bridging two Pt-atoms; these Pt-2 cores are connected via bridging AgNO3 clusters, the Ag being bound to the pyridyl-N or nitrate-O atoms. X-ray crystallographic data reveal Pt-Pt contacts of similar to 2.76 Angstrom indicative of bonding.},
	keywords = {2-PYRIDYL, 2-PYRIDYLPHOSPHINE LIGANDS, =, cation, COMPLEXES, CRYSTAL-STRUCTURE, DIMER, METAL-METAL BOND, OXIDATION, palladium, platinum, pyridylphosphine, silver, SPECTROSCOPY, TETRAKIS(DITHIOACETATO)DIPLATINUM(II)},
	isbn = {1040-7278},
	url = {<Go to ISI>://000078702700004},
	author = {Jones, N. D. and Rettig, S. J. and James, Brian R.}
}
@article {7017,
	title = {BINUCLEAR PALLADIUM COMPLEXES WITH BRIDGING HYDRIDES - UNUSUAL COORDINATION BEHAVIOR OF LIBET4},
	journal = {Journal of the American Chemical Society},
	volume = {113},
	number = {11},
	year = {1991},
	note = {ISI Document Delivery No.: FN005Times Cited: 29Cited Reference Count: 22},
	month = {May},
	pages = {4332-4334},
	type = {Note},
	keywords = {BONDS, CENTERS, NICKEL, platinum, RHODIUM HYDRIDES},
	isbn = {0002-7863},
	url = {<Go to ISI>://A1991FN00500047},
	author = {Fryzuk,Michael D. and Lloyd, B. R. and Clentsmith, G. K. B. and Rettig, S. J.}
}
