@article {ANIE:ANIE201511448, title = {Capturing HBCy2: Using N,O-Chelated Complexes of Rhodium(I) and Iridium(I) for Chemoselective Hydroboration}, journal = {Angewandte Chemie International Edition}, volume = {55}, number = {9}, year = {2016}, pages = {3181{\textendash}3186}, abstract = {1,3-N,O-chelated complexes of RhI and IrI cooperatively and reversibly stabilized the B-H bond of HBCy2 to afford six-membered metallaheterocycles (M=Rh (7) or Ir (8)) having a δ-[M]...H-B agostic interaction. Treatment of these Shimoi-type borane adducts 7 or 8 with both an aldehyde and an alkene resulted in chemoselective aldehyde hydroboration and reformation of the 1,3-N,O-chelated starting material. The observed chemoselectivity is inverted from that of free HBCy2, which is selective for alkene hydroboration.}, keywords = {boranes, hemilability, hydroboration, IRIDIUM, rhodium}, issn = {1521-3773}, doi = {10.1002/anie.201511448}, url = {http://dx.doi.org/10.1002/anie.201511448}, author = {Drover, Marcus W. and Schafer, Laurel L. and Love, Jennifer A.} } @article {ANIE:ANIE201511448, title = {Capturing HBCy2: Using N,O-Chelated Complexes of Rhodium(I) and Iridium(I) for Chemoselective Hydroboration}, journal = {Angewandte Chemie International Edition}, volume = {55}, number = {9}, year = {2016}, pages = {3181{\textendash}3186}, keywords = {boranes, hemilability, hydroboration, IRIDIUM, rhodium}, issn = {1521-3773}, doi = {10.1002/anie.201511448}, url = {http://dx.doi.org/10.1002/anie.201511448}, author = {Drover, Marcus W. and Schafer, Laurel L. and Love, Jennifer A.} }