@article {1338,
	title = {Salts of the cobalt(I) complexes [Co(CO)(5)](+) and[Co(CO)(2)(NO)(2)](+) and the Lewis acid-base adduct [CO2(CO)(7)CO-B(CF3)(3)]},
	journal = {Chemistry-a European Journal},
	volume = {12},
	number = {32},
	year = {2006},
	note = {ISI Document Delivery No.: 110YZTimes Cited: 4Cited Reference Count: 60Bernhardt, Eduard Finze, Maik Willner, Helge Lehmann, Christian W. Aubke, Friedhelm},
	month = {Nov},
	pages = {8276-8283},
	type = {Article},
	abstract = {The reaction of [Co-2(CO)(8)] with (CF3)(3)BCO in hexane leads to the Lewis acid-base adduct [CO2(CO)(7)COB(CF3)(3)] in high yield. When the reaction is performed in anhydrous HF solution [Co(CO)(5)][(CF3)(3)BF] is isolated. The product contains the first example of a homoleptic metal pentacarbonyl cation with 18 valence electrons and a trigonal-bipyramidal structure. Treatment of [Co-2(CO)(8)] or [Co(CO)(3)NO] with NO+ salts of weakly coordinating anions results in mixed crystals containing the [Co(CO)(5)](+)/[Co(CO)(2)(NO)(2)](+) ions or pure novel [Co(CO)(2)(NO)(2)](+) salts, respectively. This is a promising route to other new metal carbonyl nitrosyl cations or even homoleptic metal nitrosyl cations. All compounds were characterized by vibrational spectroscopy and by single-crystal X-ray diffraction.},
	keywords = {ALUMINUM HALIDES, ANIONS, carbonyl ligands, cobalt, density, density functional calculations, DICOBALT OCTACARBONYL, EXCHANGE, LIGANDS, METAL-CARBONYL CATIONS, NITRIC-OXIDE, NITROSYL, SOLID-STATE, SPECTROSCOPIC PROPERTIES, vibrational spectroscopy, VIBRATIONAL-SPECTRA},
	isbn = {0947-6539},
	url = {<Go to ISI>://000242418600008},
	author = {Bernhardt, E. and Finze, M. and Willner, H. and Lehmann, C. W. and Aubke, F.}
}
@article {880,
	title = {The solid-state molecular structure of W(NO)(3)Cl-3 and the nature of its W-NO bonding},
	journal = {Canadian Journal of Chemistry-Revue Canadienne De Chimie},
	volume = {82},
	number = {2},
	year = {2004},
	note = {ISI Document Delivery No.: 802BHTimes Cited: 1Cited Reference Count: 46},
	month = {Feb},
	pages = {285-292},
	type = {Article},
	abstract = {{The monomeric trinitrosyl complex, W(NO)(3)Cl-3, can be prepared by the treatment of WCl6 in CH2Cl2 with NO gas, and its identity has been unambiguously confirmed by a single-crystal X-ray diffraction analysis. The complex crystallizes in the space group Pmn2(1) as a three-component twin (a = 10.4280(4) Angstrom},
	keywords = {bonding, CARBONYL, CHEMISTRY, CRYSTAL-STRUCTURE, DERIVATIVES, DICHLORODINITROSYLTUNGSTEN, DICHLOROTRINITROSYLVANADIUM, MOLYBDENUM, MONONUCLEAR, NITROSYL, NITROSYL COMPLEXES, STRUCTURE, TUNGSTEN},
	isbn = {0008-4042},
	url = {<Go to ISI>://000220138500024},
	author = {Hayton, T. W. and Patrick, B. O. and Legzdins,Peter and McNeil, W. S.}
}
@article {706,
	title = {Thermal activation of hydrocarbon C-H bonds by Cp*M(NO) complexes of molybdenum and tungsten},
	journal = {Accounts of Chemical Research},
	volume = {36},
	number = {4},
	year = {2003},
	note = {ISI Document Delivery No.: 669GJTimes Cited: 54Cited Reference Count: 36},
	month = {Apr},
	pages = {223-233},
	type = {Review},
	abstract = {Gentle thermolysis of appropriate Cp*M(NO)(hydrocarbyl)(2) complexes (Cp* = eta(5)-C5Me5) of molybdenum and tungsten results in loss of hydrocarbon and the transient formation of 16-electron Cp*M(NO)-containing complexes such as Cp*M(NO)(alkylidene), Cp*M(NO)(eta(2)-benzyne), Cp*M(NO)(eta(2)-acetylene), and Cp*M(NO)(eta(2)-allene) (M = Mo, W). These intermediates effect the single, double, or triple activation of hydrocarbon C-H bonds intermolecularly, the first step of these activations being the reverse of the transformations by which they were generated. This Account summarizes the various types of C-H activations that have been effected with these nitrosyl complexes and also describes the results of kinetic, mechanistic, and theoretical investigations of these processes.},
	keywords = {ALKANES, ALKYLIDENE COMPLEXES, ARENES, CHEMISTRY, INTERMEDIATE, NITROSYL, REACTIVITY, REDUCTIVE ELIMINATION, THERMOLYSIS, TRANSITION-METAL BONDS},
	isbn = {0001-4842},
	url = {<Go to ISI>://000182343300001},
	author = {Pamplin, C. B. and Legzdins,Peter}
}
@article {3419,
	title = {NITROSYL N-O BOND-CLEAVAGE DURING REACTIONS OF ORGANOMETALLIC NITROSYL COMPLEXES OF THE GROUP-6 ELEMENTS},
	journal = {Comments on Inorganic Chemistry},
	volume = {17},
	number = {4},
	year = {1995},
	note = {ISI Document Delivery No.: RH843Times Cited: 11Cited Reference Count: 44Part A},
	pages = {239-254},
	type = {Article},
	abstract = {The nitrosyl ligands in organotransition-metal nitrosyl complexes usually stay intact during chemical transformations of these complexes. However, our continuing study of the characteristic reactivity of Group 6 organometallic nitrosyl complexes has recently revealed a number of new product complexes which result from N-O bond cleavage of the nitrosyl groups in the reactants. The various reactions and reaction conditions during which these complexes undergo facile nitrosyl N-O bond dissociation are summarized, and mechanistic ideas as to why these bond cleavages occur are also presented.},
	keywords = {(ETA-5-C5ME5)RU(NO), ACTIVATION, COORDINATED NITRIC-OXIDE, COORDINATIVELY UNSATURATED BRIDGING, GAS-PHASE, GROUP 6, LIGANDS, MIGRATORY INSERTION, MOLYBDENUM, NITROSYL, NITROSYL BOND CLEAVAGE, OXIDATIVE ADDITION-REACTIONS, OXO COMPLEXES, TUNGSTEN},
	isbn = {0260-3594},
	url = {<Go to ISI>://A1995RH84300003},
	author = {Legzdins,Peter and Young, M. A.}
}
