@article {1574,
	title = {High resolution laser induced fluorescence spectroscopy of the [18.8] (3)Phi(i)-X (3)Phi(i) (0,0) band of cobalt monofluoride},
	journal = {Journal of Chemical Physics},
	volume = {125},
	number = {6},
	year = {2006},
	note = {ISI Document Delivery No.: 073TITimes Cited: 5Cited Reference Count: 33Steimle, Timothy C. Ma, Tongmei Adam, Allan G. Hamilton, William D. Merer, Anthony J.},
	month = {Aug},
	pages = {9},
	type = {Article},
	abstract = {The fine and hyperfine interaction parameters in the [18.8] (3)Phi (upsilon=0) and X (3)Phi (upsilon=0) states of cobalt monofluoride, CoF, have been determined from an analysis of high-resolution laser induced fluorescence spectra of the [18.8] (3)Phi(3)-X (3)Phi(3) and [18.8] (3)Phi(4)-X (3)Phi(4) band systems. The previously reported pure rotational transitions of the X (3)Phi(4)(upsilon=0) state [T. Okabayashi and M. Tanimoto, J. Mol. Spectrosc. 221, 149 (2003)] were included in the data set. The hyperfine parameters for Co-59 (I=7/2) and F-19 (I=1/2) have been interpreted using atomic data together with a proposed molecular orbital description for the [18.8](3)Phi(i) and X (3)Phi(i) states. A comparison of the hyperfine parameters in the X (3)Phi state of cobalt monohydride, CoH, with those of the X (3)Phi state of CoF reveals that the bonding in the two molecules is significantly different. It is shown that, in a situation where the Omega substates of a multiplet degenerate electronic state are analyzed separately, the Fermi contact parameter b can be determined with fair accuracy from the apparent centrifugal distortion of the hyperfine structure. (c) 2006 American Institute of Physics.},
	keywords = {ALTERNATING COPOLYMERIZATION, CARBON-DIOXIDE, COF, COMPLEXES, ELECTRONIC-SPECTRUM, GROUND-STATE, HYPERFINE-STRUCTURE, PARAMETERS, PROPYLENE-OXIDE, TRANSITION-METAL},
	isbn = {0021-9606},
	url = {<Go to ISI>://000239765100017},
	author = {Steimle, T. C. and Ma, T. M. and Adam, A. G. and Hamilton, W. D. and Merer, A. J.}
}
