@article {939,
	title = {Rhodium-hydrido-benzylamine-triphenylphosphine complexes: Solid-state and solution structures and implications in catalyzed imine hydrogenation},
	journal = {Inorganic Chemistry},
	volume = {43},
	number = {21},
	year = {2004},
	note = {ISI Document Delivery No.: 862KITimes Cited: 10Cited Reference Count: 26},
	month = {Oct},
	pages = {6838-6841},
	type = {Article},
	abstract = {The complexes cis, trans, cis-[Rh(H)(2)(PPh3)(2)(NH2CH2Ph)(2)]PF6 (1) and cis-[Rh(PPh3)(2)(NH2CH2Ph)(2)]PF6 (2) are characterized by X-ray crystallography; the structures are maintained in CH2Cl2 where the species are in equilibrium under H-2. In MeOH and in acetone, loss of amine and/or H-2 can occur. Traces of 1 and 2 are present after a Rh-catalyzed H-2-hydrogenation of PhCH=NCH2Ph in MeOH, where the amine is generated by hydrolysis of the imine substrate through adventitious water. The findings are relevant to catalyst poisoning in the catalytic process.},
	keywords = {CATIONIC COMPLEXES, CRYSTAL, DIHYDRIDO COMPLEXES, LIGANDS, metals, X-RAY},
	isbn = {0020-1669},
	url = {<Go to ISI>://000224489100049},
	author = {Marcazzan, P. and Patrick, B. O. and James, Brian R.}
}
