@article {1105,
	title = {Characterization of a rhodium(III)-imine-orthometalated imine complex: Reversible C-H activation of a coordinated imine},
	journal = {Organometallics},
	volume = {24},
	number = {15},
	year = {2005},
	note = {ISI Document Delivery No.: 945IGTimes Cited: 13Cited Reference Count: 40},
	month = {Jul},
	pages = {3753-3757},
	type = {Article},
	abstract = {Solutions of cis-[Rh(PPh3)(2)(solv)(2)]PF6 (solv = acetone or MeOH) react at room temperature under Ar with benzophenone imine to yield cis- [Rh(PPh3)(2)(eta(1)-NH=CPh2)(2)]PF6 (3), but depending on reaction conditions, one of the imine ligands undergoes orthometalation to give [RhH{NH=C(Ph)(o-C6H4)}(HN=CPh2)(PPh3)(2)]PF6 (2) with trans-phosphines; this is the first recorded complex containing an imine in its eta(1)-form and as an eta(2)-moiety formed via orthometalation. Complexes 2 and 3 are characterized by elemental analysis, H-1 and P-31-{H-1} NMR spectroscopy, and, in the case of 2, an X-ray crystal structure.},
	keywords = {BEHAVIOR, BONDS, CATIONIC COMPLEXES, COMPLEXES, HYDROGENATION, METAL-COMPLEXES, OXIDATIVE ADDITION, RHODIUM(III), semicarbazones, TERDENTATE NITROGEN LIGANDS, UNIT},
	isbn = {0276-7333},
	url = {<Go to ISI>://000230495600021},
	author = {Ezhova, M. B. and Patrick, B. O. and James, Brian R.}
}
