@article {1834,
	title = {Formation of a phosphine-phosphinite ligand in RhCl(PRR {\textquoteright}(2))[P,P-R {\textquoteright}(R)POCH2P(CH2OH)(2)] and R {\textquoteright} H from cis-RhCl(PRR {\textquoteright}(2))(2)[P(CH2OH)(3)] via P-C bond cleavage},
	journal = {Inorganic Chemistry},
	volume = {46},
	number = {21},
	year = {2007},
	note = {Lorenzini, Fabio Patrick, Brian O. James, Brian R.},
	month = {Oct},
	pages = {8998-9002},
	abstract = {Reaction of RhCl(1,5-cod)(THP), where THP = P(CH2OH)(3), with several PRR{\textquoteright}(2) phosphines (R = or not equal R{\textquoteright}) generates, concomitantly with R{\textquoteright}H, the derivatives RhCl(PRR{\textquoteright}(2))[PP-R{\textquoteright}(R)POCH2P(CH2OH)(2)] in two isomeric forms. The hydrogen of the hydrocarbon co-product derives from, a THP hydroxyl group which becomes an {\textquoteright}alkoxy{\textquoteright} group at the residual PRR{\textquoteright} moiety, this resulting in the P,P-chelated R{\textquoteright}(R)POCH2P(CH2OH)2 ligand. One of the isomers of the PPh3 system, cis-RhCl (PPh3)[P, P-P(Ph)(2)OCH2P(CH2OH)(2)], was structurally characterized (cis refers to the disposition of the P atoms with Ph substituents).},
	isbn = {0020-1669},
	url = {<Go to ISI>://000250009600077},
	author = {Lorenzini, F. and Patrick, B. O. and James, Brian R.}
}
