@article {2169,
	title = {Serendipitous syntheses of Rh(H)(2)Cl(PRPh2)(3) complexes, and their crystal structures, where R = Me, Cy (cyclohexyl)},
	journal = {Inorganica Chimica Acta},
	volume = {361},
	number = {7},
	year = {2008},
	note = {ISI Document Delivery No.: 304ETTimes Cited: 4Cited Reference Count: 40Lorenzini, Fabio Patrick, Brian O. James, Brian R.},
	month = {May},
	pages = {2123-2130},
	type = {Article},
	abstract = {Reactions of RhCl(cod)(THP) (cod = 1,5-cyclooctadiene; THP = P(CH2OH)(3)) with PMePh2 or PCyPh2 (Cy = cyclohexyl) in acetone/MeOH solution under H-2 surprisingly form the complexes cis,mer-Rh(H)Cl-2(PRPh2)(3) (R = Me or Cy); both complexes are characterized by crystallography (the first structures in which the hydride ligands of such dihydrido-chloro-trisphosphine complexes have been located), and by detailed H-1 and P-31 NMR spectroscopy. The key role of the THP in the observed chemistry is discussed. (C) 2007 Elsevier B.V. All rights reserved.},
	keywords = {CRYSTALLOGRAPHY, ETHYLENE, EXCHANGE, HOMOGENEOUS CATALYTIC HYDROGENATION, hydride, hydride complexes, NMR, PARAHYDROGEN-INDUCED POLARIZATION, PHOSPHINE COMPLEXES, rhodium, RHODIUM(I), SPECTROSCOPY, TERTIARY PHOSPHINES, WATER, WILKINSONS CATALYST},
	isbn = {0020-1693},
	url = {<Go to ISI>://000256093500040},
	author = {Lorenzini, F. and Patrick, B. O. and James, Brian R.}
}
