@article {7018,
	title = {SYNTHESIS AND REACTIVITY OF RUTHENIUM AMIDE PHOSPHINE COMPLEXES - FACILE CONVERSION OF A RUTHENIUM AMIDE TO A RUTHENIUM AMINE VIA DIHYDROGEN ACTIVATION AND ORTHO METALATION - X-RAY STRUCTURE OF RUCL(C6H4PPH2)[NH(SIME2CH2PPH2)2]},
	journal = {Organometallics},
	volume = {10},
	number = {2},
	year = {1991},
	note = {ISI Document Delivery No.: EY681Times Cited: 68Cited Reference Count: 38},
	month = {Feb},
	pages = {467-473},
	type = {Article},
	abstract = {{The reaction of LiN(SiMe2CH2PPh2)2 with RuCl2(PPh3)3 leads to the formation of the ruthenium amide complex RuCl(PPh3)[N(SiMe2CH2PPh2)2]. This complex reacts with H2 to form two isomeric amine-hydride derivatives of the formula RuCl(PPh3)H[NH(SiMe2CH2PPh2)2]. Reaction of RuCl(PPh3)[N-(SiMe2CH2PPh2)2] with MeLi, Me3SiCH2Li, or H2C = CHCH2MgCl does not lead to the expected hydrocarbyl derivative; rather, ortho metalation occurs to generate Ru(C6H4PPh2)[N(SiMe2CH2PPh2)2]. Attempts to displace the PPh3 ligand of RuCl(PPh3)[N(SiMe2CH2PPh2)2] with PEt3 lead to the formation of RuCl(C6H4PPh2)[NH(SiMe2PPh2)2], having an amine ligand and the ortho-metalated phenyl group. The complex RuCl(C6H4PPh2)[NH(SiMe2CH2PPh2)2] crystallizes in space group P2(1)/n with a = 9.8385 (5) angstrom},
	keywords = {5-COORDINATE D6 COMPLEXES, CARBONYL-COMPLEXES, CRYSTAL, formation, HYDROGEN, IRIDIUM, MOLECULAR-STRUCTURE, STEREOSELECTIVE},
	isbn = {0276-7333},
	url = {<Go to ISI>://A1991EY68100025},
	author = {Fryzuk,Michael D. and Montgomery, C. D. and Rettig, S. J.}
}
