@article {1270, title = {Lewis adducts of the side-on end-on dinitrogen-bridged complex [{(NPN)Ta}(2)(mu-H)(2)(mu-eta(1):eta(2)-N-2)] with AlMe3, GaMe3, and B(C6F5)(3): Synthesis, structure, and spectroscopic properties}, journal = {Chemistry-a European Journal}, volume = {11}, number = {2}, year = {2005}, note = {ISI Document Delivery No.: 887VLTimes Cited: 12Cited Reference Count: 49}, month = {Jan}, pages = {604-618}, type = {Article}, abstract = {{Reaction of the side-on end-on dinitrogen complex [{(NPN)Ta}(2)(mu- H)(2)(mu-eta(1):eta(2)-N-2)] (1; in which NPN= (PhNSiMe2CH2)(2)PPh), with the Lewis acids XR3 results in the adducts [{(NPN)Ta}(2)(mu-H)(2)(mu-eta(1):eta(2)-NNXR3)]}, keywords = {CHEMISTRY, CLEAVAGE, COORDINATED, density functional calculations, DINITROGEN, DINITROGEN COMPLEXES, DINUCLEAR TANTALUM COMPLEX, EFFECTIVE CORE POTENTIALS, FIXATION, MOLECULAR CALCULATIONS, MOLYBDENUM CENTER, N-2 LIGAND, NITROGEN, Raman spectroscopy, REACTIVITY, tantalum, TRIS(PENTAFLUOROPHENYL)BORANE}, isbn = {0947-6539}, url = {://000226333500014}, author = {Studt, F. and MacKay, B. A. and Johnson, S. A. and Patrick, B. O. and Fryzuk,Michael D. and Tuczek, F.} }