@article {753,
	title = {Synthesis of the hemin of beta-tetrakis(trifluoromethyl)-meso-tetraphenylporphyrin and its evaluation as a P-450 mimic},
	journal = {Inorganica Chimica Acta},
	volume = {346},
	year = {2003},
	note = {ISI Document Delivery No.: 660EJTimes Cited: 4Cited Reference Count: 24},
	month = {Mar},
	pages = {261-264},
	type = {Article},
	abstract = {The hemin of beta-tetrakis(trifluoromethyl)-meso-tetraphenylporphyrin has been synthesized. Conventional methods for iron insertion failed; iron in low oxidation states (0 or II) brought about reduction of the macrocycle and Fe(III) failed to insert. Thus, insertion of iron into the macrocycle required the formation of the lithium complex, from lithium bis(trimethylsilyl)amide, followed by ferrous chloride. The novel hemin was tested as a catalyst for oxidations of cyclohexane and cyclohexene using iodosylbenzene as an oxidant and was found to be ineffective. (C) 2002 Elsevier Science B.V. All rights reserved.},
	keywords = {CATALYSIS, CATALYSTS, cytochrome P-450, ELECTROCHEMISTRY, METALLOPORPHYRINS, OXIDATION, PORPHYRIN, porphyrins, POSITIONS, POTENTIALS},
	isbn = {0020-1693},
	url = {<Go to ISI>://000181820600033},
	author = {Terazono, Y. and Dolphin, D.}
}
