@article {2961,
	title = {HIGH-PRESSURE NMR-STUDY OF IMINE HYDROGENATION CATALYZED BY RHODIUM(I) PHOSPHINE COMPLEXES - CHARACTERIZATION OF SPECIES PRESENT UNDER CATALYTIC CONDITIONS},
	journal = {Inorganic Chemistry},
	volume = {33},
	number = {7},
	year = {1994},
	note = {ISI Document Delivery No.: NE102Times Cited: 19Cited Reference Count: 21},
	month = {Mar},
	pages = {1464-1468},
	type = {Article},
	abstract = {A high-pressure NMR cell based upon the use of a sapphire NMR tube and simple valve design was constructed. The use of the cell to study the hydrogenation of imines under 1000-2000 psi of hydrogen mediated by [tertiary bis(phosphine)]rhodium(I) catalysts is described. Complexes of the type [{Rh(diphos)}2(mu-H)(mu-X)] (X = Cl, I, OMe), which are formed at these elevated hydrogen pressures, were characterized in situ, and the possible significance of these complexes in the catalysis is discussed. The dihydride cis-[RhH2(diphos)2]Cl, produced in a side reaction, was spectroscopically characterized at low temperature under 1200 psi of H-2.},
	keywords = {LIGAND, SYSTEMS},
	isbn = {0020-1669},
	url = {<Go to ISI>://A1994NE10200040},
	author = {Ball, G. E. and Cullen, W. R. and Fryzuk,Michael D. and Henderson, W. J. and James, Brian R. and Macfarlane, K. S.}
}
