@article {35360,
	title = {Early Transition Metal-Catalyzed Hydroaminoalkylation},
	journal = {Trends in Chemistry.},
	volume = {3},
	year = {2021},
	chapter = {428-429},
	abstract = {<p>Hydroaminoalkylation was first reported for homoleptic early transition metal complexes by Clerici and Maspero in 1980. After these observations, hydroaminoalkylation was overlooked for decades due to low catalytic activity. A breakthrough by Herzon and Hartwig in 2007, using Ta(NMe2)5 as a catalyst, showed promising reactivity with N-alkylarylamines and unactivated alkenes. Since 2008, the Doye and Schafer groups and others have improved catalytic activity and expanded the substrate scope of early transition metal-catalyzed hydroaminoalkylation.</p>},
	author = {Man{\ss}en, M. and Schafer, L. L.}
}
