@article {35336,
	title = {N-Silylamines in catalysts: synthesis and reactivity},
	journal = {Chemical Communications.},
	volume = {58},
	year = {2022},
	chapter = {9174-9189},
	abstract = {<p>A summary of the catalytic synthesis and reactivity of N-silylated amines is presented. Dehydrocoupling of amines with silanes, hydrosilylation of imines and dealkenylative coupling of amines with vinylsilanes are three ways to achieve their catalytic syntheses. The resultant N-silylamines serve as substrates in a variety of reactions, including C\&ndash;N and C\&ndash;C bond forming reactions, and are preferred in transformations because of the facile Si\&ndash;N hydrolytic cleavage to reveal free amine products upon reaction completion. This review highlights the distinct electronic properties of N-silyl amines, N-silyl imines and N-silyl enamines that result in complementary reactivity to that of parent non-silyl variants.</p>},
	author = {Verma, Vani and Koperniku, Ana; and Edwards, Peter M. and Schafer, L. L.}
}
