@article {3752, title = {trans-Tetrachlorobis(triphenylphosphine-P)-rhenium(IV)-mer-trans-trichlo rooxobis(triphenylphosphine-P)rhenium(V) (0.86/0.14)}, journal = {Acta Crystallographica Section C-Crystal Structure Communications}, volume = {52}, year = {1996}, note = {ISI Document Delivery No.: UX298Times Cited: 5Cited Reference Count: 9Part 6}, month = {Jun}, pages = {1377-1380}, type = {Article}, abstract = {trans-Tetrachlorobis (triphenylphosphine)rhenium(rv), (1), is isomorphous with the triclinic polymorph of mer-trans-trichlorooxobis (triphenylphosphine)rhenium(v), (2) [Lebuis \& Beauchamp (1993). Cart. J. Chem. 71, 441-449]. The sample of (1) has been partially oxidized (14-25\%) to (2) by aerial oxidation, resulting in the title compound, [ReCl4(C18H15P)(2)](0.86)-[ReCl3O(C18H15P)(2)](0.14). In the crystal lattice, the oxo ligand is located primarily at one of six possible sites. The molecules have tuans-octahedral coordination geometry, with Re-P distances in the range 2.564(1)-2.580 (1) Angstrom, having a mean value of 2.571(7) Angstrom, and Re-Cl distances in the range 2.291(3)-2.339 (1)Angstrom.}, isbn = {0108-2701}, url = {://A1996UX29800026}, author = {Luo, H. Y. and Orvig, Chris and Rettig, S. J.} }