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On the Viability of Cyclometalated Ru(II) Complexes for Light-Harvesting Applications

TitleOn the Viability of Cyclometalated Ru(II) Complexes for Light-Harvesting Applications
Publication TypeJournal Article
Year of Publication2009
AuthorsBomben, PG, Robson, KCD, Sedach, PA, Berlinguette, CP
JournalINORGANIC CHEMISTRY
Volume48
Pagination9631-9643
Date PublishedOCT 19
ISSN0020-1669
Abstract

{The effects of replacing a single polypyridyl ligand with an analogous anionic cyclometalating ligand were investigated for a set of three structurally related series of Ru(II) compounds formulated as {[}Ru(bpy)(2)(L)](z), {[}Ru(tpy)(L)](z), and {[}Ru(tpy)(L)Cl](z) where z = 0, +1, or +2, and L = polypyridyl (e.g.

DOI10.1021/ic900653q