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REGIOSELECTIVE AND STEREOSELECTIVE DIELS-ALDER REACTIONS OF UNSYMMETRICAL 1,2-DISUBSTITUTED VINYL SULFONES WITH A MONOVINYLPORPHYRIN

TitleREGIOSELECTIVE AND STEREOSELECTIVE DIELS-ALDER REACTIONS OF UNSYMMETRICAL 1,2-DISUBSTITUTED VINYL SULFONES WITH A MONOVINYLPORPHYRIN
Publication TypeJournal Article
Year of Publication1992
AuthorsYonhin, P, Wijesekera, TP, Dolphin, D
JournalNew Journal of Chemistry
Volume16
Pagination537-539
Date PublishedMay
Type of ArticleNote
ISBN Number1144-0546
Keywordsbiosynthesis, ROUTE
Abstract

A study of the Diels-Alder reactions of several 1,2-disubstituted vinyl sulfones with a beta-methyl-beta’-monovinylporphyrin shows that the cycloadditions are highly regioselective and that stereochemical control can be manipulated by replacing a carboxyl ester group by a cyano group or by changing the geometry of the dienophile.

URL<Go to ISI>://A1992JK62500003