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PHOSPHINE COMPLEXES OF THE EARLY METALS AND THE IANTHANOIDS

TitlePHOSPHINE COMPLEXES OF THE EARLY METALS AND THE IANTHANOIDS
Publication TypeJournal Article
Year of Publication1991
AuthorsFryzuk, MD, Haddad, TS, Berg, DJ, Rettig, SJ
JournalPure and Applied Chemistry
Volume63
Pagination845-850
Date PublishedJun
Type of ArticleProceedings Paper
ISBN Number0033-4545
KeywordsDERIVATIVES, F-BLOCK METALS, FLUXIONAL BEHAVIOR, GROUP-4, HAFNIUM(IV), LIGANDS, RAY CRYSTAL-STRUCTURE, ZIRCONIUM(IV)
Abstract

The coordination chemistry of the mixed-donor tridentate ligand -N(SiMe2CH2PR2)2 with the early transition metals of groups 3 and 4 and the lanthanide elements will be presented. This ancillary ligand has allowed for the formation of phosphine complexes of these hard elements which has in turn induced new reactivity patterns for hydrocarbyl ligands.

URL<Go to ISI>://A1991FN25500008